Equilibrium in Protic Ionic Liquids: The Degree of Proton Transfer and Thermodynamic Properties

2017 ◽  
Vol 122 (1) ◽  
pp. 309-315 ◽  
Author(s):  
Kaizhou Chen ◽  
Yongtao Wang ◽  
Jia Yao ◽  
Haoran Li
Keyword(s):  
Ionic Liquids ◽  
Thermodynamic Properties ◽  
Proton Transfer ◽  
Protic Ionic Liquids

Key factor governing the physicochemical properties and extent of proton transfer in protic ionic liquids: ΔpKa or chemical structure?

2019 ◽  
Vol 21 (1) ◽  
pp. 418-426 ◽  
Author(s):  
Muhammed Shah Miran ◽  
Mahfuzul Hoque ◽  
Tomohiro Yasuda ◽  
Seiji Tsuzuki ◽  
Kazuhide Ueno ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Ionic Liquids ◽  
Proton Transfer ◽  
Physicochemical Properties ◽  
Chemical Structure ◽  
Protic Ionic Liquids ◽  
Key Factor ◽  
Factor Governing

A series of protic ionic liquids (PILs) are prepared by neutralisation of bis(trifluoromethanesulfonyl)amide acid (H[NTf2]) with various amines, and the properties (especially thermal stability and ionicity) are compared with those of PILs from 1,8-diazabicyclo[5.4.0]-7-undecene (DBU) and various acids.

Ionicity and proton transfer in protic ionic liquids

2010 ◽  
Vol 12 (35) ◽  
pp. 10341 ◽  
Author(s):  
Jelena Stoimenovski ◽  
Ekaterina I. Izgorodina ◽  
Douglas R. MacFarlane
Keyword(s):  
Ionic Liquids ◽  
Proton Transfer ◽  
Protic Ionic Liquids

Ionicity of acetate-based protic ionic liquids: evidence for both liquid and gaseous phases

2014 ◽  
Vol 38 (8) ◽  
pp. 3449-3456 ◽  
Author(s):  
Xiaofu Sun ◽  
Shuangyue Liu ◽  
Asim Khan ◽  
Chuan Zhao ◽  
Chuanyu Yan ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Proton Transfer ◽  
High Temperatures ◽  
Protic Ionic Liquids ◽  
Equilibrium Shift

Low ionicity at high temperatures has been detected for a series of acetate-based protic ionic liquids (PILs), which form neutral components as a result of back proton transfer through an equilibrium shift.

Proton Transfer in Phosphoric Acid-Based Protic Ionic Liquids: Effects of the Base

2020 ◽  
Vol 124 (20) ◽  
pp. 4141-4149 ◽  
Author(s):  
Zhenghao Zhu ◽  
Xubo Luo ◽  
Alexei P. Sokolov ◽  
Stephen J. Paddison
Keyword(s):  
Ionic Liquids ◽  
Phosphoric Acid ◽  
Proton Transfer ◽  
Protic Ionic Liquids

Preparation of protic ionic liquids with minimal water content and 15N NMR study of proton transfer

2010 ◽  
Vol 12 (7) ◽  
pp. 1571 ◽  
Author(s):  
Geoffrey L. Burrell ◽  
Iko M. Burgar ◽  
Frances Separovic ◽  
Noel F. Dunlop
Keyword(s):  
Ionic Liquids ◽  
Proton Transfer ◽  
Water Content ◽  
15N Nmr ◽  
Protic Ionic Liquids ◽  
Nmr Study

Thermodynamic properties of aqueous solutions of two ammonium-based protic ionic liquids at 298.15K

2013 ◽  
Vol 178 ◽  
pp. 149-155 ◽  
Author(s):  
Mengyin Hou ◽  
Yingjie Xu ◽  
Yajuan Han ◽  
Bin Chen ◽  
Wenxia Zhang ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Thermodynamic Properties ◽  
Aqueous Solutions ◽  
Protic Ionic Liquids

Theoretical and experimental studies on proton transfer in acetate-based protic ionic liquids

2016 ◽  
Vol 221 ◽  
pp. 254-261 ◽  
Author(s):  
Xuejun Sun ◽  
Bobo Cao ◽  
Xinming Zhou ◽  
Shuangyue Liu ◽  
Xiao Zhu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Proton Transfer ◽  
Experimental Studies ◽  
Protic Ionic Liquids
Sign in / Sign up

Export Citation Format

Share Document