Infrared Spectroscopy of Ionic Liquids Consisting of Imidazolium Cations with Different Alkyl Chain Lengths and Various Halogen or Molecular Anions with and without a Small Amount of Water

2017 ◽  
Vol 121 (14) ◽  
pp. 3121-3129 ◽  
Author(s):  
Toshiki Yamada ◽  
Yukihiro Tominari ◽  
Shukichi Tanaka ◽  
Maya Mizuno
2015 ◽  
Vol 44 (33) ◽  
pp. 14666-14672 ◽  
Author(s):  
Bing An ◽  
Jun-Li Wang ◽  
Yan Bai ◽  
Dong-Bin Dang

A cobalt-1,4-naphthalenedicarboxylic acid system in a systematic series of ionic liquids with different alkyl chain lengths of imidazolium cations governed the construction of four MOFs with regular changes of secondary building units (SBUs).


2018 ◽  
Vol 2018 ◽  
pp. 1-5
Author(s):  
Cheng Cheng ◽  
Chenglong Zhang ◽  
Jiachao Jiang ◽  
En Ma ◽  
Jianfeng Bai ◽  
...  

Silicon tetrachloride (SiCl4) is the main byproducts of the polysilicon industries. The dissolution behaviors of SiCl4 in imidazolium ionic liquid, including [Bmim]OTf, [Bmim]NTf2, [Hmim]NTf2, and [Omim]NTf2, were investigated for recycling Si from SiCl4. Raman spectroscopy was used to understand the combination between the ionic liquid and SiCl4, and the conductivity of ionic liquids in different conditions was determined. The results indicated that [Bmim]NTf2 exhibited a better SiCl4 dissolving capacity compared to [Bmim]OTf, longer alkyl chain lengths in the imidazolium cations of the ionic liquids exhibited a better performance in dissolving SiCl4, and [Bmim]NTf2 : PC = 1 : 2 exhibited the best conductivity. In addition, molecular bondings between C-Cl, Si-O-Si, and C-Si were formed between the ionic liquids and SiCl4.


2014 ◽  
Vol 161 (4) ◽  
pp. H161-H165 ◽  
Author(s):  
Bruno Gélinas ◽  
John C. Forgie ◽  
Dominic Rochefort

2020 ◽  
Vol 22 (30) ◽  
pp. 17394-17400
Author(s):  
Shuang Men ◽  
Yujuan Jin ◽  
Peter Licence

XPS is used to probe the impact of the N3-substituted alkyl chain on the electronic environment of the cation and the anion by comparing two types of imidazolium cations, 1-alkyl-3-butylimidazolium and 1-alkyl-3-methylimidazolium.


2021 ◽  
pp. 127868
Author(s):  
Xiaohong Chen ◽  
Huanxuan Sun ◽  
Tianyue Zhang ◽  
Hongyue Shang ◽  
Zhaoxue Han ◽  
...  

2017 ◽  
Vol 140 ◽  
pp. 235-240 ◽  
Author(s):  
Cheng Zhang ◽  
Lusheng Zhu ◽  
Jinhua Wang ◽  
Jun Wang ◽  
Tongtong Zhou ◽  
...  

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