scholarly journals Contribution of Different Molecules and Moieties to the Surface Tension in Aqueous Surfactant Solutions. II: Role of the Size and Charge Sign of the Counterions

2021 ◽  
Author(s):  
György Hantal ◽  
Marcello Sega ◽  
George Horvai ◽  
Pál Jedlovszky
Keyword(s):  
Surface Tension ◽  
Surfactant Solutions ◽  
Charge Sign

On the Role of Marangoni Effects on the Critical Heat Flux for Pool Boiling of Binary Mixtures

1996 ◽  
Vol 118 (1) ◽  
pp. 103-109 ◽  
Author(s):  
W. R. McGillis ◽  
V. P. Carey
Keyword(s):  
Surface Tension ◽  
Heat Flux ◽  
Binary Mixtures ◽  
Critical Heat Flux ◽  
Full Range ◽  
Pool Boiling ◽  
Marangoni Effect ◽  
Restoring Force ◽  
Marangoni Effects

The Marangoni effect on the critical heat flux (CHF) condition in pool boiling of binary mixtures has been identified and its effect has been quantitatively estimated with a modified model derived from hydrodynamics. The physical process of CHF in binary mixtures, and models used to describe it, are examined in the light of recent experimental evidence, accurate mixture properties, and phase equilibrium revealing a correlation to surface tension gradients and volatility. A correlation is developed from a heuristic model including the additional liquid restoring force caused by surface tension gradients. The CHF condition was determined experimentally for saturated methanol/water, 2-propanol/water, and ethylene glycol/water mixtures, over the full range of concentrations, and compared to the model. The evidence in this study demonstrates that in a mixture with large differences in surface tension, there is an additional hydrodynamic restoring force affecting the CHF condition.

scholarly journals Influence of moisture content on the contact angle and surface tension measured on birch wood surfaces

2021 ◽  
Author(s):  
Rami Benkreif ◽  
Fatima Zohra Brahmia ◽  
Csilla Csiha
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Moisture Content ◽  
Solid Wood ◽  
Contact Angles ◽  
Surface Moisture ◽  
Wood Coatings ◽  
The Relationship ◽  
Wood Surfaces

AbstractSurface tension of solid wood surfaces affects the wettability and thus the adhesion of various adhesives and wood coatings. By measuring the contact angle of the wood, the surface tension can be calculated based on the Young-Dupré equation. Several publications have reported on contact angle measured with different test liquids, under different conditions. Results can only be compared if the test conditions are similar. While the roles of the drop volume, image shooting time etc., are widely recognized, the role of the wood surface moisture content (MC) is not evaluated in detail. In this study, the effect of wood moisture content on contact angle values, measured with distilled water and diiodomethane, on sanded birch (Betula pendula) surfaces was investigated, in order to find the relationship between them. With increasing MC from approximately 6% to 30%, increasing contact angle (decreasing surface tension) values were measured according to a logarithmic function. The function makes possible the calculation of contact angles that correspond to different MCs.

scholarly journals Interactions between an Associative Amphiphilic Block Polyelectrolyte and Surfactants in Water: Effect of Charge Type on Solution Properties and Aggregation

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1729
Author(s):  
Patrizio Raffa
Keyword(s):  
Surface Tension ◽  
Self Assembly ◽  
Interaction Model ◽  
Industrial Applications ◽  
Molecular Organization ◽  
Different Types ◽  
Solution Rheology ◽  
Interesting Class ◽  
First Time

The study of interactions between polyelectrolytes (PE) and surfactants is of great interest for both fundamental and applied research. These mixtures can represent, for example, models of self-assembly and molecular organization in biological systems, but they are also relevant in industrial applications. Amphiphilic block polyelectrolytes represent an interesting class of PE, but their interactions with surfactants have not been extensively explored so far, most studies being restricted to non-associating PE. In this work, interactions between an anionic amphiphilic triblock polyelectrolyte and different types of surfactants bearing respectively negative, positive and no charge, are investigated via surface tension and solution rheology measurements for the first time. It is evidenced that the surfactants have different effects on viscosity and surface tension, depending on their charge type. Micellization of the surfactant is affected by the presence of the polymer in all cases; shear viscosity of polymer solutions decreases in presence of the same charge or nonionic surfactants, while the opposite charge surfactant causes precipitation. This study highlights the importance of the charge type, and the role of the associating hydrophobic block in the PE structure, on the solution behavior of the mixtures. Moreover, a possible interaction model is proposed, based on the obtained data.

The kinetics of the surface tension of micellar surfactant solutions

1991 ◽  
Vol 60 ◽  
pp. 235-261 ◽  
Author(s):  
C.D. Dushkin ◽  
I.B. Ivanov ◽  
P.A. Kralchevsky
Keyword(s):  
Surface Tension ◽  
Surfactant Solutions ◽  
Micellar Surfactant Solutions ◽  
Kinetics Of

Study of Surface Tension and Natural Evaporation of Aqueous Surfactant Solutions

2018 ◽  
Author(s):  
Birce Dikici ◽  
Matthew J. Lehman
Keyword(s):  
Surface Tension ◽  
Natural Convection ◽  
Water Loss ◽  
Heat Dissipation ◽  
Eastern Africa ◽  
Working Fluid ◽  
Lauryl Sulfate ◽  
Surfactant Solutions ◽  
Eastern Australia ◽  
Wilhelmy Plate Method

Surface tension and solution evaporation of aqueous solutions of sodium lauryl sulfate (SLS), ECOSURF™ EH-14, and ECOSURF™ SA-9 under natural convection is examined through experimental methods. SLS is an anionic surfactant while EH-14 and SA-9 are environmentally-friendly nonionic surfactants. Surfactants are known to affect evaporation performance of solutions and are studied in relation to water loss prevention and heat dissipation. Surfactants could be useful under drought conditions which present challenges to water management on a yearly basis in arid areas of the world. Recent water scarcity in the greater Los Angeles area, south eastern Africa nations, eastern Australia and eastern Mediterranean countries has high cost of water loss by evaporation. Surfactants are studied as a potential method of suppressing evaporation in water reservoirs. Surfactants are also studied as performance enhancers for the working fluid of heat dissipation devices, such as pulsating heat pipes used for electronics cooling. Some surfactants have been shown to lower thermal resistances and friction pressure in such devices and thereby increase their efficiency. The static surface tensions of the aqueous-surfactant solutions are measured with surface tensiometer using Wilhelmy plate method. The surfactants are shown to lower surface tension significantly from pure water. The surface tension values found at the Critical Micelle Concentration are 33.8 mN/m for SLS, 30.3 mN/m for EH-14, and 30.0 mN/m for SA-9. All three surfactants reduced natural convection water loss over 5 days with SLS showing the greatest effect on evaporation rates. The maximum evaporation reduction by each surfactant from distilled water with no surfactants after 5 days is 26.1% for SLS, 20.8% for EH-14, and 18.4% for SA-9.

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