The Line of the Unit Compressibility Factor (Zeno-Line) for Crystal States

2020 ◽  
Vol 124 (24) ◽  
pp. 5021-5027
Author(s):  
E. M. Apfelbaum ◽  
V. S. Vorob’ev
1996 ◽  
Vol 34 (3-4) ◽  
pp. 533-540 ◽  
Author(s):  
A. Koenig ◽  
J. N. Kay ◽  
I. M. Wan

In the context of landfilling dewatered wastewater sludge in Hong Kong, with landfills up to 140 m high, one of the most significant properties of sludge is its physical nature with regard to moisture characteristics and associated geotechnical stability. Commonly, lower limits are set on total solids content, but no geotechnical stability criteria are applied with the exception of Germany where a minimum requirement for vane shear strength is set at 25 kN/m2. The purpose of this study was to determine and evaluate dewatered wastewater sludge from three Hong Kong municipal wastewater treatment plants with regard to the following physical and geotechnical properties: (i) vane shear strength; (ii) consolidation characteristics such as compression index, compressibility factor, coefficient of consolidation and compressibility coefficient; and (iii) hydraulic characteristics such as permeability and intrinsic resistance. Although dewatered sludge exhibits quite different characteristics as compared to soils, predictive logarithmic relationships may be established between various properties which are consistent with the critical state model for soils, conventional filtration and consolidation theory. Such representation provides a valuable basis for understanding the sludge characteristics and behaviour to landfill design.


2018 ◽  
Vol 73 (2) ◽  
pp. 121-125
Author(s):  
Bahtiyar A. Mamedov ◽  
Elif Somuncu ◽  
Iskender M. Askerov

AbstractWe present a new analytical approximation for determining the compressibility factor of real gases at various temperature values. This algorithm is suitable for the accurate evaluation of the compressibility factor using the second virial coefficient with a Lennard–Jones (12-6) potential. Numerical examples are presented for the gases H2, N2, He, CO2, CH4 and air, and the results are compared with other studies in the literature. Our results showed good agreement with the data in the literature. The consistency of the results demonstrates the effectiveness of our analytical approximation for real gases.


1964 ◽  
Vol 4 (04) ◽  
pp. 291-306 ◽  
Author(s):  
C. Kenneth Eilerts

Abstract Finite difference equations were programmed and used to integrate the second-order, second-degree, partial differential equation with variable coefficients that represents the transient linear flow of gas-condensate fluids. Effect was given to the change with pressure of the compressibility factor, the viscosity, and the effective permeability and to change of the absolute permeability with distance. Integrations used as illustrations include recovery of fluid from a reservoir at a constant production rate followed by recovery at a declining rate calculated to maintain a constant pressure at the producing boundary. The time required to attain such a limiting pressure and the fraction of the reserve recovered in that time vary markedly with properties of the fluid represented by the coefficients. Fluid also is returned to the reservoir at a constant rate, until initial formation pressure is attained at the input boundary, and then at a calculated rate that will maintain but not exceed the limiting pressure. The computing programs were used to calculate the results that would be obtained in a series of back-pressure tests made at selected intervals of reservoir depletion. If effect is given to the variations in properties of the fluid that actually occur, then a series of back-pressure curves one for each stage of reserve depletion -- is required to indicate open-flow capacity and related flow characteristics dependably. The isochronal performance method for determining flow characteristics of a well was simulated by computation. Introduction The back-pressure test procedure is based on a derivation of the equation for steady-state radial flow of a gas, the properties of which are of necessity assumed to remain unchanged in applying the test results. The properties of most natural gases being recovered from reservoirs change as the reserve is depleted and pressures decline, and the results of an early back-pressure test may not be dependable for estimating the future delivery capacity of a well. The compressibility factor of a fluid under an initial pressure of 10,000 psia can change 45 per cent and the viscosity can change 70 per cent during the productive life of the reservoir. There are indications that the effective permeability to the flowing fluid can become 50 per cent of the original absolute permeability before enough liquid collects in the structure about a well as pressure declines to permit flow of liquid into the well. The advent of programmed electronic computing made practicable the integration of nonlinear, second-order, partial differential equations pertaining to flow in reservoirs. Aronofsky and Porter represented the compressibility factor and the viscosity by a linear relationship, and integrated the equation for radial flow of gas for pressures up to 1,200 psi. Bruce, Peaceman, Rachford and Rice integrated the partial differential equations for both linear and radial unsteady-state flow of ideal gas in porous media. Their published results were a substantial guide in this study of integration of the partial differential equation of linear flow with coefficients of the equation variable. The computing program was developed to treat effective permeability as being both distance-dependent and pressure-dependent. In this study all examples of effective permeability are assumptions designed primarily to aid in developing programs for giving effect to this and other variable coefficients. The accumulation of data for expressing the pressure dependency of the effective permeability is the objective of a concurrent investigation. SPEJ P. 291^


2021 ◽  
pp. 35-40
Author(s):  
Denis Y. Kutovoy ◽  
Igor A. Yatsenko ◽  
Vladimir B. Yavkin ◽  
Aydar N. Mukhametov ◽  
Petr V. Lovtsov ◽  
...  

The actual problem of the possibility of using the equations of state for the gas phase of natural gas at temperatures below 250 K is considered. To solve it, the compressibility coefficients of natural gas obtained experimentally with high accuracy are required. The technique was developed and experimental study was carried out of compressibility factor aiming expanding temperature range of the state equations GERG-2004 and AGA8-DC92. The proposed technique is based on the fact that to assess the applicability of the equation of state, it is sufficient to obtain the relative value of the compressibility coefficient and not to determine its absolute value. The technique does not require complex equipment and provides high accuracy. The technique was tested on nitrogen, argon, air and methane. Uncertainty of determination of the compressibility factor is not greater than 0.1 %. For two different compositions of natural gas, obtained experimental data were demonstrated that the equations of state GERG-2004 and AGA8-92DC provide uncertainty of the calculation of the compressibility coefficient within 0.1 % in the temperature range from 220 K to 250 K and pressure below 5 MPa.


2021 ◽  
Author(s):  
Vadim Goryachikh ◽  
Fahad Alghamdi ◽  
Abdulrahman Takrouni

Abstract Background information Natural gas liquid (NGL) production facilities, typically, utilize turbo-expander-brake compressor (TE) to generate cold for C2+ separation from the natural gas by isentropic expansion of feed stream and use energy absorbed by expansion to compress residue gas. Experience shows that during operational phase TE can exposed to operation outside of design window that may lead to machine integrity loss and consequent impact on production. At the same time, there is a lack of performance indicators that help operator to monitor operating window of the machine and proactively identify performance deterioration. For instance, TE brake compressor side is always equipped with anti-surge protection system, including surge deviation alarms and trip. However, there is often gap in monitoring deviation from stonewall region. At the same time, in some of the designs (2×50% machines) likelihood of running brake compressor in stonewall is high during one machine trip or train start-up, turndown operating modes. Also, typical compressor performance monitoring systems does not have enough dynamic parameters that may indicate machine process process performance deterioration proactively (real-time calculation of actual polytrophic efficiency, absorbed power etc.) and help operator to take action before catastrophic failure occurs. In addition, typical compressor monitoring systems are based on assumed composition and fixed compressibility factor and do not reflect actual compositions variations that may affect machine performance monitoring. To overcome issues highlighted above, Hawiyah NGL (HNGL) team has developed computerized monitoring and advisory system to monitor the performance of turbo-expander-brake compressor, proactively, identify potentially unsafe conditions or performance deterioration and advice operators on taking necessary actions to avoid unscheduled deferment of production. Computerized performance monitoring system has been implemented in HNGL DCS (Yokogawa) and utilized by control room operators on day-to-day basis. Real-time calculation, analysis and outputs produced by performance monitoring system allow operator to understand how current operating condition are far from danger zone. Proactive deviation alarms and guide messages produce by the system in case of deviation help operators to control machine from entering unsafe region. Actual polytrophic efficiency, adsorbed power calculations provide machine condition status and allow identifying long-term performance deterioration trends.


2021 ◽  
Author(s):  
Oluwasegun Cornelious Omobolanle ◽  
Oluwatoyin Olakunle Akinsete

Abstract Accurate prediction of gas compressibility factor is essential for the evaluation of gas reserves, custody transfer and design of surface equipment. Gas compressibility factor (Z) also known as gas deviation factor can be evaluated by experimental measurement, equation of state and empirical correlation. However, these methods have been known to be expensive, complex and of limited accuracy owing to the varying operating conditions and the presence of non-hydrocarbon components in the gas stream. Recently, newer correlations with extensive application over wider range of operating conditions and crude mixtures have been developed. Also, artificial intelligence is now being deployed in the evaluation of gas compressibility factor. There is therefore a need for a holistic understanding of gas compressibility factor vis-a-vis the cause-effect relations of deviation. This paper presents a critical review of current understanding and recent efforts in the estimation of gas deviation factor.


2017 ◽  
Vol 11 (4) ◽  
pp. 522-540 ◽  
Author(s):  
Isham Alzoubi ◽  
Mahmoud Delavar ◽  
Farhad Mirzaei ◽  
Babak Nadjar Arrabi

Purpose This work aims to determine the best linear model using an artificial neural network (ANN) with the imperialist competitive algorithm (ICA-ANN) and ANN to predict the energy consumption for land leveling. Design/methodology/approach Using ANN, integrating artificial neural network and imperialist competitive algorithm (ICA-ANN) and sensitivity analysis (SA) can lead to a noticeable improvement in the environment. In this research, effects of various soil properties such as embankment volume, soil compressibility factor, specific gravity, moisture content, slope, sand per cent and soil swelling index on energy consumption were investigated. Findings According to the results, 10-8-3-1, 10-8-2-5-1, 10-5-8-10-1 and 10-6-4-1 multilayer perceptron network structures were chosen as the best arrangements and were trained using the Levenberg–Marquardt method as the network training function. Sensitivity analysis revealed that only three variables, namely, density, soil compressibility factor and cut-fill volume (V), had the highest sensitivity on the output parameters, including labor energy, fuel energy, total machinery cost and total machinery energy. Based on the results, ICA-ANN had a better performance in the prediction of output parameters in comparison with conventional methods such as ANN or particle swarm optimization (PSO)-ANN. Statistical factors of root mean square error (RMSE) and correlation coefficient (R2) illustrate the superiority of ICA-ANN over other methods by values of about 0.02 and 0.99, respectively. Originality/value A limited number of research studies related to energy consumption in land leveling have been done on energy as a function of volume of excavation and embankment. However, in this research, energy and cost of land leveling are shown to be functions of all the properties of the land, including the slope, coefficient of swelling, density of the soil, soil moisture and special weight dirt. Therefore, the authors believe that this paper contains new and significant information adequate for justifying publication in an international journal.


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