scholarly journals Temperature-Dependent Rate Constant for the Reaction of Hydroxyl Radical with 3-Hydroxy-3-methyl-2-butanone

2019 ◽  
Vol 123 (48) ◽  
pp. 10446-10453 ◽  
Author(s):  
Yuri Bedjanian
Keyword(s):  
Hydroxyl Radical ◽  
Rate Constant ◽  
Temperature Dependent ◽  
Dependent Rate

H + HOONO2 ? products: Temperature-dependent rate constant

1981 ◽  
Vol 13 (11) ◽  
pp. 1163-1174 ◽  
Author(s):  
Paula L. Trevor ◽  
John R. Barker
Keyword(s):  
Rate Constant ◽  
Temperature Dependent ◽  
Dependent Rate

O(3P) + HOONO2 ? products: Temperature-dependent rate constant

1981 ◽  
Vol 13 (11) ◽  
pp. 1151-1161 ◽  
Author(s):  
Jenq-sian Chang ◽  
Paula L. Trevor ◽  
John R. Barker
Keyword(s):  
Rate Constant ◽  
Temperature Dependent ◽  
Dependent Rate

Radiolysis studies on the corrosion inhibitors 1 -hexyn-3-ol, cinnamonitrile, and 1,3-diethyl-2-thiourea

1995 ◽  
Vol 73 (12) ◽  
pp. 2137-2142 ◽  
Author(s):  
A.J. Elliot ◽  
M.P. Chenier ◽  
D.C. Ouellette
Keyword(s):  
Hydrogen Atom ◽  
Hydroxyl Radical ◽  
Temperature Dependence ◽  
Rate Constant ◽  
Rate Constants ◽  
Corrosion Inhibitors ◽  
Hydrated Electron

In this publication we report: (i) the rate constants for reaction of the hydrated electron with 1-hexyn-3-ol ((8.6 ± 0.3) × 108 dm3 mol−1 s−1 at 18 °C), cinnamonitrile ((2.3 ± 0.2) × 1010 dm3 mol−1 s−1 at 20 °C), and 1,3-diethyl-2-thiourea ((3.5 ± 0.3) × 108 dm3 mol−1 s−1 at 22 °C). For cinnamonitrile and diethylthiourea, the temperature dependence up to 200 °C and 150 °C, respectively, is also reported; (ii) the rate constants for the reaction of the hydroxyl radical with 1-hexyn-3-ol ((5.5 ± 0.5) × 109 dm3 mol−1 s−1 at 20 °C), cinnamonitrile ((9.2 ± 0.3) × 109 dm3 mol−1 s−1 at 21 °C), and diethylthiourea ((8.0 ± 0.8) × 108 dm3 mol−1 s−1 at 22 °C). For cinnamonitrile, the temperature dependence up to 200 °C is also reported; (iii) the rate constant for the hydrogen atom reacting with 1-hexyn-3-ol ((4.3 ± 0.4) × 109 dm3 mol−1 s−1 at 20 °C). Keywords: radiolysis, corrosion inhibitors, rate constants.

Temperature dependent rate coefficients for the reaction of OH radicals with dimethylbenzoquinones

2015 ◽  
Vol 639 ◽  
pp. 145-150 ◽  
Author(s):  
Iustinian Bejan ◽  
Ian Barnes ◽  
Peter Wiesen ◽  
John C. Wenger
Keyword(s):  
Rate Coefficients ◽  
Oh Radicals ◽  
Temperature Dependent ◽  
Dependent Rate

Multivariate QSARs to model the hydroxyl radical rate constant for halogenated aliphatic hydrocarbons

1994 ◽  
Vol 5 (2) ◽  
pp. 197-208 ◽  
Author(s):  
Lennart Eriksson ◽  
Stefan Rännar ◽  
Michael Sjöström ◽  
Joop L. M. Hermens
Keyword(s):  
Hydroxyl Radical ◽  
Rate Constant ◽  
Aliphatic Hydrocarbons

Multivariate modelling of the rate constant of the gas-phase reaction of haloalkanes with the hydroxyl radical

1991 ◽  
Vol 109-110 ◽  
pp. 307-325 ◽  
Author(s):  
Maria Livia Tosato ◽  
Claudio Chiorboli ◽  
Lennart Eriksson ◽  
Jorgen Jonsson
Keyword(s):  
Hydroxyl Radical ◽  
Gas Phase ◽  
Rate Constant ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
Multivariate Modelling
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