Ligand Effects on the Linear Response Hubbard U: The Case of Transition Metal Phthalocyanines

2019 ◽  
Vol 123 (14) ◽  
pp. 3214-3222
Author(s):  
Iulia Emilia Brumboiu ◽  
Soumyajyoti Haldar ◽  
Johann Lüder ◽  
Olle Eriksson ◽  
Heike C. Herper ◽  
...  
Keyword(s):  
Transition Metal ◽  
Linear Response ◽  
Metal Phthalocyanines ◽  
Ligand Effects ◽  
Hubbard U

Reversible Electrochromism in the Thin Films of Single-Transition Metal Phthalocyanines

1993 ◽  
Vol 22 (8) ◽  
pp. 1299-1302 ◽  
Author(s):  
Naoki Toshima ◽  
Shin-ichi Kawamura ◽  
Tsuyoshi Tominaga
Keyword(s):  
Thin Films ◽  
Transition Metal ◽  
Metal Phthalocyanines ◽  
Single Transition

Non-Linear Response of Transition Metal Tri-and Tetra-Chalcogenides

1985 ◽  
Vol 121 (1-4) ◽  
pp. 39-47
Author(s):  
P. Monceau ◽  
M. Renard ◽  
J. Richard ◽  
M. C. Saint-lager ◽  
Z. Z. Wang
Keyword(s):  
Transition Metal ◽  
Linear Response ◽  
Non Linear

Transition Metal Phthalocyanines as Nitrogen Oxydes Sensors

2021 ◽  
pp. 1-20
Author(s):  
Anna Maria Paoletti ◽  
Giovanna Pennesi ◽  
Gentilina Rossi ◽  
Amanda Generosi ◽  
Barbara Paci ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Phthalocyanines

Protonation of some non-transition metal phthalocyanines — spectral and photophysicochemical consequences

2012 ◽  
Vol 16 (07n08) ◽  
pp. 885-894 ◽  
Author(s):  
Abimbola O. Ogunsipe ◽  
Mopelola A. Idowu ◽  
Taofeek B. Ogunbayo ◽  
Isaac A. Akinbulu
Keyword(s):  
Transition Metal ◽  
Rate Constant ◽  
Rate Equation ◽  
Aluminum Chloride ◽  
Ground State ◽  
Triplet States ◽  
Metal Phthalocyanines ◽  
Excited Triplet ◽  
Kinetics Of ◽  
Excited Triplet States

The photophysics and photochemistry of phthalocyanine complexes of magnesium (MgPc), aluminum chloride (ClAlPc) and zinc (ZnPc) are studied in N,N′-dimethylformamide (DMF). The values obtained for the photophysical and photochemical parameters are normal for simple metallophthalocyanine (MPc) complexes. Protonation of the azomethine bridges reduced the photoactivities of the complexes considerably; however the excited triplet states of the protonated species are more stable towards ground state oxygen. The interaction of the non-protonated MPcs with ground state oxygen is shown to be diffusion-assisted, with bimolecular rate constant values of the order of 1010 M-1.s-1. MgPc could not be protonated; it was easily demetalated by the protonating acid. The kinetics of the demetalation yielded the rate equation: Rate = 0.1[MgPc][H+]2/3

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