scholarly journals Product Detection of the CH Radical Reactions with Ammonia and Methyl-Substituted Amines

2019 ◽  
Vol 123 (11) ◽  
pp. 2178-2193
Author(s):  
Jeremy Bourgalais ◽  
Kacee L. Caster ◽  
Olivier Durif ◽  
David L. Osborn ◽  
Sebastien D. Le Picard ◽  
...  
Keyword(s):  
Radical Reactions ◽  
Ch Radical

Kinetics and mechanisms of CH radical reactions with fluoromethanes and carbon tetrachloride

1988 ◽  
Vol 120 (2) ◽  
pp. 311-317 ◽  
Author(s):  
S. Zabarnick ◽  
J.W. Fleming ◽  
M.C. Lin
Keyword(s):  
Carbon Tetrachloride ◽  
Radical Reactions ◽  
Ch Radical

Temperature dependence of CH radical reactions with H2O and CH2O

1988 ◽  
Vol 21 (1) ◽  
pp. 713-719 ◽  
Author(s):  
S. Zabarnick ◽  
J.W. Fleming ◽  
M.C. Lin
Keyword(s):  
Temperature Dependence ◽  
Radical Reactions ◽  
Ch Radical

ChemInform Abstract: Kinetics of CH Radical Reactions with N2O, SO2, OCS, CS2, and SF6

ChemInform ◽  
1989 ◽  
Vol 20 (49) ◽  
Author(s):  
S. ZABARNICK ◽  
J. W. FLEMING ◽  
M. C. LIN
Keyword(s):  
Radical Reactions ◽  
Ch Radical ◽  
Kinetics Of

Kinetics of CH radical reactions with selected molecules at room temperature

1981 ◽  
Vol 56 (3) ◽  
pp. 355-365 ◽  
Author(s):  
J.E. Butler ◽  
J.W. Fleming ◽  
L.P. Goss ◽  
M.C. Lin
Keyword(s):  
Room Temperature ◽  
Radical Reactions ◽  
Ch Radical ◽  
Kinetics Of

Kinetics of CH radical reactions with N2O, SO2, OCS, CS2, and SF6

1989 ◽  
Vol 21 (9) ◽  
pp. 765-774 ◽  
Author(s):  
S. Zabarnick ◽  
J. W. Fleming ◽  
M. C. Lin
Keyword(s):  
Radical Reactions ◽  
Ch Radical ◽  
Kinetics Of

Temperature dependence of CH radical reactions with O2, NO, CO and CO2

1982 ◽  
Vol 19 (1) ◽  
pp. 73-79 ◽  
Author(s):  
M.R. Berman ◽  
J.W. Fleming ◽  
A.B. Harvey ◽  
M.C. Lin
Keyword(s):  
Temperature Dependence ◽  
Radical Reactions ◽  
Ch Radical

Spatiotemporal Control of Amide Radicals During Photocatalysis

2020 ◽  
Author(s):  
Shogo Mori ◽  
Takahiro Aoki ◽  
Kaliyamoorthy Selvam ◽  
Shunichi Fukuzumi ◽  
Jieun Jung ◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Nickel Complex ◽  
Nickel Complexes ◽  
Semiconductor Material ◽  
Radical Reactions ◽  
Substitution Reactions ◽  
Carbon Neutrality ◽  
Spatiotemporal Control ◽  
Scalable Production ◽  
Salt Waste

Despite the continuing popularity of radical reactions in organic synthesis, much remains to be explored in this area. Herein, we describe how spatiotemporal control can be exerted over the formation and reactivity of divergent exchangeable formamide radicals using nickel complexes with a semiconductor material (TiO<sub>2</sub>) under irradiation from near-UV–Vis light. Depending on the bipyridine ligand used and the quantity of the nickel complex that is hybridized on or nonhydridized over the TiO<sub>2</sub> surface, these radicals selectively undergo substitution reactions at the carbon center of carbon–bromine bonds that proceed via three different pathways. As the scalable production of formamides from CO<sub>2</sub> does not produce salt waste, these methods could add a new dimension to the search for carbon neutrality through the indirect incorporation of CO<sub>2</sub> into organic frameworks.

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