Effect of Transition Metal Fragments on the Reverse Fritsch–Buttenberg–Wiechell Type Ring Contraction Reaction of Metallabenzynes to Metal–Carbene Complexes

2018 ◽  
Vol 122 (8) ◽  
pp. 2160-2167 ◽  
Author(s):  
Chakkittakandiyil Anusha ◽  
Susmita De ◽  
Pattiyil Parameswaran
Keyword(s):  
Transition Metal ◽  
Carbene Complexes ◽  
Ring Contraction ◽  
Transition Metal Fragments ◽  
Ring Contraction Reaction

Ring contraction of metallabenzooxirene to metal carbonyl complexes – a comparative study with the Wolff rearrangement of oxirene and benzooxirene

2017 ◽  
Vol 46 (40) ◽  
pp. 13974-13982 ◽  
Author(s):  
Chakkittakandiyil Anusha ◽  
Susmita De ◽  
Pattiyil Parameswaran
Keyword(s):  
Transition Metal ◽  
Comparative Study ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Wolff Rearrangement ◽  
Ring Contraction ◽  
Metal Carbonyl Complexes ◽  
Thermodynamic Feasibility ◽  
Transition Metal Fragments

Transition metal fragments affect the kinetic and thermodynamic feasibility of the Wolff type rearrangement.

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

ChemInform Abstract: A New One-Pot Procedure for a Ring Contraction Reaction Using Iodine/H2O2.

ChemInform ◽  
2009 ◽  
Vol 40 (8) ◽  
Author(s):  
Sabrina B. Ferreira ◽  
Carlos R. Kaiser ◽  
Vitor F. Ferreira
Keyword(s):  
One Pot ◽  
Ring Contraction ◽  
Ring Contraction Reaction

Cyclopropanes from reactions of transition metal carbene complexes with olefins

1987 ◽  
Vol 87 (2) ◽  
pp. 411-432 ◽  
Author(s):  
Maurice. Brookhart ◽  
William B. Studabaker
Keyword(s):  
Transition Metal ◽  
Carbene Complexes
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