Hydrogen and Hydrocarbon Gases, Polycyclic Aromatic Hydrocarbons, and Amorphous Carbon Produced by Multiple Shock Compression of Liquid Benzene up to 27.4 GPa

2017 ◽  
Vol 121 (34) ◽  
pp. 6471-6480 ◽  
Author(s):  
Koichi Mimura ◽  
Tamihito Nishida
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Shock Compression ◽  
Amorphous Carbon ◽  
Aromatic Hydrocarbons ◽  
Hydrocarbon Gases ◽  
Liquid Benzene ◽  
Polycyclic Aromatic ◽  
Multiple Shock

Raman spectra of submicron amorphous carbon grains and mixtures of polycyclic aromatic hydrocarbons

1988 ◽  
Vol 28 (6) ◽  
pp. 383-388 ◽  
Author(s):  
A. Blanco ◽  
E. Bussoletti ◽  
L. Colangeli ◽  
S. Fonti ◽  
V. Orofino
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Raman Spectra ◽  
Amorphous Carbon ◽  
Aromatic Hydrocarbons ◽  
Polycyclic Aromatic

scholarly journals Dust in planetary nebulae

2016 ◽  
Vol 12 (S323) ◽  
pp. 121-127
Author(s):  
G. C. Sloan
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Amorphous Carbon ◽  
Infrared Spectra ◽  
Aromatic Hydrocarbons ◽  
Planetary Nebulae ◽  
Emission Feature ◽  
Asymptotic Giant Branch ◽  
Strong Emission ◽  
Polycyclic Aromatic ◽  
Central Stars

AbstractInfrared spectra from the Spitzer Space Telescope trace the evolution of carbon-rich dust from the asymptotic giant branch (AGB) to young planetary nebulae (PNe). On the AGB, amorphous carbon dominates the dust, but SiC and MgS also appear. In more evolved systems with warmer central stars, the spectra reveal the unidentified 21 μm feature, features from aliphatic hydrocarbons, and spectra from polycyclic aromatic hydrocarbons (PAHs), often with shifted feature positions indicative of the presence of aliphatics. More evolved systems with hot central stars show more typical PAH spectra, along with fullerenes and/or an emission feature known as the big-11 feature at ~11 μm. This features arises from a combination of SiC and PAHs, and it is usually accompanied by a shoulder at 18 μm, which while unidentified might be from cool silicate grains. The strong emission from MgS and SiC in young PNe probably arises from coatings on carbonaceous grains.

The Assessment of Contamination and Source of Polycyclic Aromatic Hydrocarbons from the Sediments of the Someş River

2019 ◽  
Vol 64 (1) ◽  
pp. 55-67
Author(s):  
Vlad Pӑnescu ◽  
◽  
Mihaela Cӑtӑlina Herghelegiu ◽  
Sorin Pop ◽  
Mircea Anton ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Polycyclic Aromatic

1,1’-Biaceanthrylene and 2,2'-Biaceanthrylene: Models for Linking Larger Polycyclic Aromatic Hydrocarbons via Five-Membered Rings

2019 ◽  
Author(s):  
Yachu Du ◽  
Kyle Plunkett
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Polycyclic Aromatic Hydrocarbon ◽  
Aromatic Hydrocarbon ◽  
Electronic Properties ◽  
Aromatic Hydrocarbons ◽  
Model Systems ◽  
Redox Potentials ◽  
Dimer Model ◽  
Optical And Electronic Properties ◽  
Polycyclic Aromatic

We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.<br>

1,1’-Biaceanthrylene and 2,2'-Biaceanthrylene: Models for Linking Larger Polycyclic Aromatic Hydrocarbons via Five-Membered Rings

2019 ◽  
Author(s):  
Yachu Du ◽  
Kyle Plunkett
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Polycyclic Aromatic Hydrocarbon ◽  
Aromatic Hydrocarbon ◽  
Electronic Properties ◽  
Aromatic Hydrocarbons ◽  
Model Systems ◽  
Redox Potentials ◽  
Dimer Model ◽  
Optical And Electronic Properties ◽  
Polycyclic Aromatic

We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.<br>

EMISSION OF POLYCYCLIC AROMATIC HYDROCARBONS CONTAINED IN COMBUSTION PRODUCTS OF GASOLINE ENGINES

2018 ◽  
Vol 62 (3) ◽  
pp. 341-346 ◽  
Author(s):  
M. Assad ◽  
V. V. Grushevski ◽  
O. G. Penyazkov ◽  
I. N. Tarasenko
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
High Speed ◽  
Internal Combustion Engines ◽  
Catalytic Converter ◽  
Combustion Products ◽  
Chromatography Method ◽  
Exhaust Gases ◽  
Polycyclic Aromatic ◽  
Load Mode

The concentration of 16 polycyclic aromatic hydrocarbons (PAHs) in the gasoline combustion products emitted into the atmosphere by internal combustion engines (ICE) has been measured using the gas chromatography method. The concentrations of PAHs in the exhaust gases sampled behind a catalytic converter has been determined when the ICE operates in five modes: idle mode, high speed mode, load mode, ICE cold start mode (engine warm-up) and transient mode. Using 92 RON, 95 RON and 98 RON gasoline the effect of the octane number of gasoline on the PAHs content in the exhaust gases has been revealed. The concentration of the most carcinogenic component (benzo(α)pyrene) in the exhaust gases behind a catalytic converter significantly exceeds a reference value of benzo(α)pyrene in the atmospheric air established by the WHO and the EU for ICE in the load mode.

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