Exploring the Origin of the Generalized Anomeric Effects in the Acyclic Nonplanar Systems

2017 ◽  
Vol 121 (29) ◽  
pp. 5548-5560 ◽  
Author(s):  
Neda Hasanzadeh ◽  
Davood Nori-Shargh ◽  
Hooriye Yahyaei ◽  
Seiedeh Negar Mousavi ◽  
Sahar Kamrava
Keyword(s):  
Anomeric Effects

Anomeric effects in Schiff bases of D-glucosamine with aromatic aldehydes

1973 ◽  
Vol 19 (6) ◽  
pp. 1666-1668
Author(s):  
V. P. Panov ◽  
A. K. Trukhmanov ◽  
R. G. Zhbankov
Keyword(s):  
Schiff Bases ◽  
Aromatic Aldehydes ◽  
Anomeric Effects

scholarly journals Ab Initio Modeling of Glycosyl Torsions and Anomeric Effects in a Model Carbohydrate: 2-Ethoxy Tetrahydropyran

2007 ◽  
Vol 93 (1) ◽  
pp. 1-10 ◽  
Author(s):  
H. Lee Woodcock ◽  
Damian Moran ◽  
Richard W. Pastor ◽  
Alexander D. MacKerell ◽  
Bernard R. Brooks
Keyword(s):  
Ab Initio ◽  
Ab Initio Modeling ◽  
Anomeric Effects

On the generalized valence bond description of the anomeric and exo-anomeric effects: an ab initio conformational study of 2-methoxytetrahydropyran

2005 ◽  
Vol 340 (13) ◽  
pp. 2171-2184 ◽  
Author(s):  
Rodrigo S. Bitzer ◽  
André G.H. Barbosa ◽  
Clarissa O. da Silva ◽  
Marco A.C. Nascimento
Keyword(s):  
Ab Initio ◽  
Valence Bond ◽  
Conformational Study ◽  
Generalized Valence Bond ◽  
Anomeric Effects

Anomeric effects involving silicon centres: silanols

1988 ◽  
pp. 67-69 ◽  
Author(s):  
Alan E. Reed ◽  
Christian Schade ◽  
Paul von Ragué Schleyer ◽  
P. Vishnu Kamath ◽  
Jayaraman Chandrasekhar
Keyword(s):  
Anomeric Effects

1,7-Dioxaspiro[5.5]undecanes. An excellent system for the study of stereoelectronic effects (anomeric and exo-anomeric effects) in acetals

1981 ◽  
Vol 59 (7) ◽  
pp. 1105-1121 ◽  
Author(s):  
Pierre Deslongchamps ◽  
Daryl D. Rowan ◽  
Normand Pothier ◽  
Gilles Sauvé ◽  
John K. Saunders
Keyword(s):  
Experimental Results ◽  
Nmr Analysis ◽  
Steric Interactions ◽  
Stereoelectronic Effects ◽  
Anomeric Effects ◽  
Acid Cyclization ◽  
C Nmr

Several isomeric compounds derived from the spiro systems 5 to 9 (Scheme 4) were obtained from the acid cyclization of the appropriate dihydroxy ketone precursor.The configuration and the conformation of the products obtained was determined by 13C nmr analysis and equilibration studies. The experimental results can be rationalized by taking into account the anomeric and the exo-anomeric effects and the usual steric interactions.

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