Reaction Dynamics Following Ionization of Ammonia Dimer Adsorbed on Ice Surface

2016 ◽  
Vol 120 (37) ◽  
pp. 7301-7310 ◽  
Author(s):  
Hiroto Tachikawa
Author(s):  
George C. Ruben ◽  
Kenneth A. Marx

In vitro collapse of DNA by trivalent cations like spermidine produces torus (donut) shaped DNA structures thought to have a DNA organization similar to certain double stranded DNA bacteriophage and viruses. This has prompted our studies of these structures using freeze-etch low Pt-C metal (9Å) replica TEM. With a variety of DNAs the TEM and biochemical data support a circumferential DNA winding model for hydrated DNA torus organization. Since toruses are almost invariably oriented nearly horizontal to the ice surface one of the most accessible parameters of a torus population is annulus (ring) thickness. We have tabulated this parameter for populations of both nicked, circular (Fig. 1: n=63) and linear (n=40: data not shown) ϕX-174 DNA toruses. In both cases, as can be noted in Fig. 1, there appears to be a compact grouping of toruses possessing smaller dimensions separated from a dispersed population possessing considerably larger dimensions.


1987 ◽  
Vol 48 (C1) ◽  
pp. C1-495-C1-501 ◽  
Author(s):  
Y. FURUKAWA ◽  
M. YAMAMOTO ◽  
T. KURODA

1991 ◽  
Vol 174 (Part_2) ◽  
pp. 225-225
Author(s):  
Wolfgang Schirmer

2012 ◽  
Vol 40 (2) ◽  
pp. 124-150
Author(s):  
Klaus Wiese ◽  
Thiemo M. Kessel ◽  
Reinhard Mundl ◽  
Burkhard Wies

ABSTRACT The presented investigation is motivated by the need for performance improvement in winter tires, based on the idea of innovative “functional” surfaces. Current tread design features focus on macroscopic length scales. The potential of microscopic surface effects for friction on wintery roads has not been considered extensively yet. We limit our considerations to length scales for which rubber is rough, in contrast to a perfectly smooth ice surface. Therefore we assume that the only source of frictional forces is the viscosity of a sheared intermediate thin liquid layer of melted ice. Rubber hysteresis and adhesion effects are considered to be negligible. The height of the liquid layer is driven by an equilibrium between the heat built up by viscous friction, energy consumption for phase transition between ice and water, and heat flow into the cold underlying ice. In addition, the microscopic “squeeze-out” phenomena of melted water resulting from rubber asperities are also taken into consideration. The size and microscopic real contact area of these asperities are derived from roughness parameters of the free rubber surface using Greenwood-Williamson contact theory and compared with the measured real contact area. The derived one-dimensional differential equation for the height of an averaged liquid layer is solved for stationary sliding by a piecewise analytical approximation. The frictional shear forces are deduced and integrated over the whole macroscopic contact area to result in a global coefficient of friction. The boundary condition at the leading edge of the contact area is prescribed by the height of a “quasi-liquid layer,” which already exists on the “free” ice surface. It turns out that this approach meets the measured coefficient of friction in the laboratory. More precisely, the calculated dependencies of the friction coefficient on ice temperature, sliding speed, and contact pressure are confirmed by measurements of a simple rubber block sample on artificial ice in the laboratory.


1982 ◽  
Vol 3 ◽  
pp. 32-35 ◽  
Author(s):  
R. L. Brooks

During the operational lifetime of the Seasat altimeter from 3 July to 10 October 1978, more than 450 overflights were made over East Antarctica inland to latitude 72°S. An analysis of selected passes over a variety of ice features demonstrates that the oceanographic altimeter performed surprisingly well over the ice sheet and ice shelves, acquiring useful measurements during approximately 70% of each pass. The altimeter's onboard tracking system dampened out the ice-surface elevations, but post-flight retracking of the stored return waveforms reveals excellent ice-surface details. After waveform retracking, the altimeter repeatability is better than ±1 m.


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