Comparison of Thiyl, Alkoxyl, and Alkyl Radical Addition to Double Bonds: The Unusual Contrasting Behavior of Sulfur and Oxygen Radical Chemistry

2016 ◽  
Vol 120 (10) ◽  
pp. 1750-1755 ◽  
Author(s):  
Isa Degirmenci ◽  
Michelle L. Coote
Keyword(s):  
Alkyl Radical ◽  
Oxygen Radical ◽  
Radical Addition ◽  
Double Bonds ◽  
Radical Chemistry

scholarly journals Chain propagation determines the chemo- and regioselectivity of alkyl radical additions to C–O vs. C–C double bonds

2020 ◽  
Vol 11 (3) ◽  
pp. 731-736 ◽  
Author(s):  
Tiffany O. Paulisch ◽  
Felix Strieth-Kalthoff ◽  
Christian Henkel ◽  
Lena Pitzer ◽  
Dirk M. Guldi ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Alkyl Radical ◽  
Radical Addition ◽  
Chain Propagation ◽  
Double Bonds

Reversible radical addition followed by an irreversible electron transfer leads to regio- and chemoselectivity control of radical additions to π-systems.

Free Radical Addition of Butanethiol to Vegetable Oil Double Bonds

2009 ◽  
Vol 57 (4) ◽  
pp. 1282-1290 ◽  
Author(s):  
Grigor B. Bantchev ◽  
James A. Kenar ◽  
Girma Biresaw ◽  
Moon Gyu Han
Keyword(s):  
Free Radical ◽  
Vegetable Oil ◽  
Radical Addition ◽  
Double Bonds ◽  
Free Radical Addition

Highly cis- and trans-selective alkyl radical addition to α-methylene-γ-phenyl-γ-butyrolactams

2009 ◽  
Vol 50 (12) ◽  
pp. 1301-1302 ◽  
Author(s):  
Tomoko Yajima ◽  
Masako Hamano ◽  
Hajime Nagano
Keyword(s):  
Alkyl Radical ◽  
Radical Addition ◽  
Cis And Trans

Comparison of the Kinetics and Thermodynamics for Methyl Radical Addition to CC, CO, and CS Double Bonds

2004 ◽  
Vol 126 (6) ◽  
pp. 1732-1740 ◽  
Author(s):  
David J. Henry ◽  
Michelle L. Coote ◽  
Rodolfo Gómez-Balderas ◽  
Leo Radom
Keyword(s):  
Radical Addition ◽  
Double Bonds ◽  
Methyl Radical ◽  
Kinetics And Thermodynamics

scholarly journals One-Pot Four-Component Reaction: Aqueous TiCl3/PhN+2-Mediated Alkyl Radical Addition to Imines Generated in situ.

ChemInform ◽  
2005 ◽  
Vol 36 (27) ◽  
Author(s):  
Rosalba Cannella ◽  
Angelo Clerici ◽  
Nadia Pastori ◽  
Eva Regolini ◽  
Ombretta Porta
Keyword(s):  
Alkyl Radical ◽  
Radical Addition ◽  
One Pot
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