DFT Probe into the Mechanism of Formic Acid Dehydrogenation Catalyzed by Cp*Co, Cp*Rh, and Cp*Ir Catalysts with 4,4′-Amino-/Alkylamino-Functionalized 2,2′-Bipyridine Ligands

2021 ◽  
Author(s):  
Neethinathan Johnee Britto ◽  
Madhavan Jaccob
Keyword(s):  
Formic Acid ◽  
Formic Acid Dehydrogenation

scholarly journals Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex

2021 ◽  
Author(s):  
Nicolas Lentz ◽  
Alicia Aloisi ◽  
Pierre Thuéry ◽  
Emmanuel Nicolas ◽  
Thibault Cantat
Keyword(s):  
Formic Acid ◽  
Cobalt Complex ◽  
Formic Acid Dehydrogenation

CdS Nanorods Anchored with Crystalline FeP Nanoparticles for Efficient Photocatalytic Formic Acid Dehydrogenation

2021 ◽  
Author(s):  
Taotao Wang ◽  
Lechen Yang ◽  
Daochuan Jiang ◽  
Hongyun Cao ◽  
Antony Charles Minja ◽  
...  
Keyword(s):  
Formic Acid ◽  
Cds Nanorods ◽  
Formic Acid Dehydrogenation

scholarly journals Synthesis of palladium-rhodium bimetallic nanoparticles for formic acid dehydrogenation

2021 ◽  
Vol 52 ◽  
pp. 301-309
Author(s):  
Ilaria Barlocco ◽  
Sofia Capelli ◽  
Elisa Zanella ◽  
Xiaowei Chen ◽  
Juan J. Delgado ◽  
...  
Keyword(s):  
Formic Acid ◽  
Bimetallic Nanoparticles ◽  
Formic Acid Dehydrogenation

Versatile Rh- and Ir-Based Catalysts for CO2 Hydrogenation, Formic Acid Dehydrogenation, and Transfer Hydrogenation of Quinolines

2018 ◽  
Vol 57 (22) ◽  
pp. 14186-14198 ◽  
Author(s):  
Jairo Fidalgo ◽  
Margarita Ruiz-Castañeda ◽  
Gabriel García-Herbosa ◽  
Arancha Carbayo ◽  
Félix A. Jalón ◽  
...  
Keyword(s):  
Formic Acid ◽  
Co2 Hydrogenation ◽  
Transfer Hydrogenation ◽  
Formic Acid Dehydrogenation

scholarly journals Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex

2020 ◽  
Author(s):  
Nicolas Lentz ◽  
Alicia Aloisi ◽  
Pierre Thuéry ◽  
Emmanuel Nicolas ◽  
Thibault Cantat
Keyword(s):  
Formic Acid ◽  
Cobalt Complex ◽  
Intermediate Formation ◽  
Mechanistic Study ◽  
Catalytic Dehydrogenation ◽  
Turnover Number ◽  
Promising Solution ◽  
The Common ◽  
Safe Transport ◽  
Formic Acid Dehydrogenation

The reversible storage of hydrogen through the intermediate formation of Formic Acid (FA) is a promising solution to its safe transport and distribution. However, the common necessity of using bases or additives in the catalytic dehydrogenation of FA is a limitation. In this context, two new cobalt complexes (<b>1</b> and <b>2</b>) were synthesized with a pincer PP(NH)P ligand containing a phosphoramine moiety. Their reaction with an excess FA yields a cobalt(I)-hydride complex (<b>3</b>). We report here the unprecedented catalytic activity of <b>3</b> in the dehydrogenation of FA, with a turnover frequency (TOF) of 4000 h<sup>-1</sup> and a turnover number (TON) of 454, without the need for bases or additives. A mechanistic study reveals that the ligand has a non-innocent behaviour due to intermolecular hydrogen bonding, which is influenced by the concentration of formic acid

scholarly journals Ultrasmall CoP Nanoparticles as Efficient Cocatalysts for Photocatalytic Formic Acid Dehydrogenation

Joule ◽  
2018 ◽  
Vol 2 (3) ◽  
pp. 549-557 ◽  
Author(s):  
Shuang Cao ◽  
Yong Chen ◽  
Hui Wang ◽  
Jie Chen ◽  
Xinghua Shi ◽  
...  
Keyword(s):  
Formic Acid ◽  
Formic Acid Dehydrogenation
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