scholarly journals Predicting Bond Dissociation Energies and Bond Lengths of Coordinatively Unsaturated Vanadium–Ligand Bonds

2020 ◽  
Vol 124 (47) ◽  
pp. 9757-9770
Author(s):  
Junwei Lucas Bao ◽  
Bradley K. Welch ◽  
Inga S. Ulusoy ◽  
Xin Zhang ◽  
Xuefei Xu ◽  
...  

There is little ambiguity when one speaks of bond lengths, but the term ‘bond energy’ has been given several interpretations and it would be useful if we had these in mind in our discussion. In the beginning it was a useful simplification to assume as did Fajans that the energy required to break a particular bond was a constant characteristic of that bond and independent of the molecular environment. Now we know that this is not the case and indeed a great part of our discussion will be concerned with the differences in bond dissociation energies.


2017 ◽  
Vol 417 ◽  
pp. 69-75 ◽  
Author(s):  
David Gatineau ◽  
Antony Memboeuf ◽  
Anne Milet ◽  
Richard B. Cole ◽  
Héloïse Dossmann ◽  
...  

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