Infrared Study of OCS Binding and Size-Selective Reactivity with Gold Clusters, Aun+ (n = 1–10)

Alice E. Green; Sascha Schaller; Gabriele Meizyte; Benjamin J. Rhodes; Sean P. Kealy; Alexander S. Gentleman; Wieland Schöllkopf; André Fielicke; Stuart R. Mackenzie

doi:10.1021/acs.jpca.0c03813

Infrared Study of OCS Binding and Size-Selective Reactivity with Gold Clusters, Aun+ (n = 1–10)

The Journal of Physical Chemistry A ◽

10.1021/acs.jpca.0c03813 ◽

2020 ◽

Vol 124 (26) ◽

pp. 5389-5401 ◽

Cited By ~ 3

Author(s):

Alice E. Green ◽

Sascha Schaller ◽

Gabriele Meizyte ◽

Benjamin J. Rhodes ◽

Sean P. Kealy ◽

...

Keyword(s):

Gold Clusters ◽

Infrared Study ◽

Selective Reactivity

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An infrared study of CO adsorption on magnesia-supported ruthenium, gold, and bimetallic ruthenium-gold clusters

Journal of Catalysis ◽

10.1016/0021-9517(80)90335-8 ◽

1980 ◽

Vol 61 (1) ◽

pp. 19-28 ◽

Cited By ~ 36

Author(s):

J SCHWANK

Keyword(s):

Co Adsorption ◽

Gold Clusters ◽

Infrared Study

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Crystal structure images of large gold clusters and growing crystals by HRTEM

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010011218x ◽

1984 ◽

Vol 42 ◽

pp. 428-429

Author(s):

L.R. Wallenberg ◽

J.-O. Bovin ◽

G. Schmid

Keyword(s):

Crystal Structure ◽

Nucleation And Growth ◽

Close Packing ◽

Gold Clusters ◽

Molecular Weight Determination ◽

Growth Mechanisms ◽

Starting Point ◽

Different Types ◽

Nucleation And Growth Mechanisms ◽

Points Of View

Metallic clusters are interesting from various points of view, e.g. as a mean of spreading expensive catalysts on a support, or following heterogeneous and homogeneous catalytic events. It is also possible to study nucleation and growth mechanisms for crystals with the cluster as known starting point.Gold-clusters containing 55 atoms were manufactured by reducing (C6H5)3PAuCl with B2H6 in benzene. The chemical composition was found to be Au9.2[P(C6H5)3]2Cl. Molecular-weight determination by means of an ultracentrifuge gave the formula Au55[P(C6H5)3]Cl6 A model was proposed from Mössbauer spectra by Schmid et al. with cubic close-packing of the 55 gold atoms in a cubeoctahedron as shown in Fig 1. The cluster is almost completely isolated from the surroundings by the twelve triphenylphosphane groups situated in each corner, and the chlorine atoms on the centre of the 3x3 square surfaces. This gives four groups of gold atoms, depending on the different types of surrounding.

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Aldehyde gold clusters for molecular labeling

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010014066x ◽

1995 ◽

Vol 53 ◽

pp. 858-859

Author(s):

James F. Hainfeld ◽

Frederic R. Furuya

Keyword(s):

Covalent Bond ◽

Aldehyde Group ◽

Gold Clusters ◽

Side Reactions ◽

Amino Groups ◽

Sodium Cyanoborohydride ◽

Schiff’S Base ◽

Protein Molecules ◽

Hydroxysuccinimide Esters ◽

Primary Amino

Glutaraldehyde is a useful tissue and molecular fixing reagents. The aldehyde moiety reacts mainly with primary amino groups to form a Schiff's base, which is reversible but reasonably stable at pH 7; a stable covalent bond may be formed by reduction with, e.g., sodium cyanoborohydride (Fig. 1). The bifunctional glutaraldehyde, (CHO-(CH2)3-CHO), successfully stabilizes protein molecules due to generally plentiful amines on their surface; bovine serum albumin has 60; 59 lysines + 1 α-amino. With some enzymes, catalytic activity after fixing is preserved; with respect to antigens, glutaraldehyde treatment can compromise their recognition by antibodies in some cases. Complicating the chemistry somewhat are the reported side reactions, where glutaraldehyde reacts with other amino acid side chains, cysteine, histidine, and tyrosine. It has also been reported that glutaraldehyde can polymerize in aqueous solution. Newer crosslinkers have been found that are more specific for the amino group, such as the N-hydroxysuccinimide esters, and are commonly preferred for forming conjugates. However, most of these linkers hydrolyze in solution, so that the activity is lost over several hours, whereas the aldehyde group is stable in solution, and may have an advantage of overall efficiency.

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