Synthesis of Medium-Ring-Sized Benzolactams by Using Strong Electrophiles and Quantitative Evaluation of Ring-Size Dependency of the Cyclization Reaction Rate

2019 ◽  
Vol 85 (2) ◽  
pp. 876-901 ◽  
Author(s):  
Hiroaki Kurouchi ◽  
Tomohiko Ohwada
Keyword(s):  
Quantitative Evaluation ◽  
Reaction Rate ◽  
Cyclization Reaction ◽  
Ring Size ◽  
Size Dependency ◽  
Medium Ring

scholarly journals Selenium halide-induced bridge formation in [2.2]paracyclophanes

2014 ◽  
Vol 10 ◽  
pp. 2550-2555 ◽  
Author(s):  
Laura G Sarbu ◽  
Henning Hopf ◽  
Peter G Jones ◽  
Lucian M Birsa
Keyword(s):  
Ring Size ◽  
Ethynyl Group ◽  
Bridge Formation ◽  
Medium Ring

An addition/elimination sequence of selenium halides to pseudo-geminally bis(acetylene) substituted [2.2]paracyclophanes leads to new bridges with an endo-exo-diene substructure. The reactions have been found to be sensitive to the substitution of the ethynyl group. The formation of dienes with a zig-zag configuration is related to that observed for non-conjugated cyclic diynes of medium ring size.

ChemInform Abstract: trans- and cis-Bicyclo(n.1.0)alk-2-ynes of Medium Ring Size.

ChemInform ◽  
2010 ◽  
Vol 28 (41) ◽  
pp. no-no
Author(s):  
H. DETERT ◽  
H. MEIER
Keyword(s):  
Ring Size ◽  
Medium Ring

Selective Favorskii rearrangment of α,α,α′-dibromochlorocycloalkanones of medium ring size

1983 ◽  
pp. 2471-2474 ◽  
Author(s):  
Antonio Abad ◽  
Manuel Arnó ◽  
Jośe R. Pedro ◽  
Eliseo Seoane
Keyword(s):  
Ring Size ◽  
Medium Ring

ChemInform Abstract: THE SYNTHESIS OF OXOALKANOLIDES OF THE MEDIUM RING SIZE

1977 ◽  
Vol 8 (45) ◽  
pp. no-no
Author(s):  
T. WAKAMATSU ◽  
K. AKASAKA ◽  
Y. BAN
Keyword(s):  
Ring Size ◽  
Medium Ring

The robinson annulation of some medium ring size 2-hydroxymethylenecyclanones

Tetrahedron ◽  
1974 ◽  
Vol 30 (6) ◽  
pp. 745-748 ◽  
Author(s):  
Vinod Dave ◽  
J.S. Whitehurst
Keyword(s):  
Ring Size ◽  
Robinson Annulation ◽  
Medium Ring

Solvolysis of medium ring size cycloalkenyl triflates

Tetrahedron ◽  
1976 ◽  
Vol 32 (1) ◽  
pp. 37-41 ◽  
Author(s):  
R.J. Hargrove ◽  
P.J. Stang
Keyword(s):  
Ring Size ◽  
Medium Ring
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