External Oxidant-Dependent Reactivity Switch in Copper-Mediated Intramolecular Carboamination of Alkynes: Access to a Different Class of Fluorescent Ionic Nitrogen-Doped Polycyclic Aromatic Hydrocarbons

2019 ◽  
Vol 84 (7) ◽  
pp. 4120-4130 ◽  
Author(s):  
Aslam C. Shaikh ◽  
Somsuvra Banerjee ◽  
Ravindra D. Mule ◽  
Saibal Bera ◽  
Nitin T. Patil
Synlett ◽  
2019 ◽  
Vol 31 (03) ◽  
pp. 211-222
Author(s):  
Junzhi Liu ◽  
Xinliang Feng

Bottom-up organic synthesis serves as an efficient method to provide atomically precise heteroatom-doped polycyclic aromatic hydrocarbons (PAHs) with not only well-defined size and edge structures but also specific concentrations and positions of the heteroatoms. We provide a plenary account of the preparation of nitrogen-doped PAHs (N-PAHs) through 1,3-dipolar cycloaddition between different dipolarophiles, as well as pyrazine-type N-doped diaza-hexa-peri-hexabenzocoronene (diaza-HBC). Additionally, we present the synthesis of a class of helical N-charged PAHs, including one charged aza[5]helicene and two charged aza[4]helicenes. Moreover, the bottom-up organic synthesis strategy is further extended to the construction of novel nitrogen-boron-nitrogen (NBN)-containing PAHs. Finally, we discuss the synthesis of four-coordinate boron chromophores containing 6,12,18-tris(alkyl amine)-5,11,17-triazatrinaphthylene derivative ligands.1 Introduction2 Nitrogen-Doped PAHs Based on Dibenzo-9a-azaphenalene (DBAP)3 Cationic Nitrogen-Doped Helical PAHs4 Nitrogen–Boron–Nitrogen-Doped PAHs5 Conclusion and Outlook


Nanoscale ◽  
2018 ◽  
Vol 10 (21) ◽  
pp. 10073-10078 ◽  
Author(s):  
Fuxin Wang ◽  
Yu Zheng ◽  
Junlang Qiu ◽  
Shuqin Liu ◽  
Yexiang Tong ◽  
...  

A graphene-based metal and nitrogen-doped carbon is successfully developed and applied as an excellent fiber coating for SPME.


2017 ◽  
Vol 41 (22) ◽  
pp. 13619-13624 ◽  
Author(s):  
Cheng-Fang Liu ◽  
Cheng Cheng ◽  
Yi Jiang ◽  
Wen-Yong Lai ◽  
Wei Huang

A novel series of nitrogen-doped star-shaped polycyclic aromatic hydrocarbons based on naphthalenes-fused triazatruxenes with fine-tunable optoelectronic properties have been developed.


2019 ◽  
Vol 64 (1) ◽  
pp. 55-67
Author(s):  
Vlad Pӑnescu ◽  
◽  
Mihaela Cӑtӑlina Herghelegiu ◽  
Sorin Pop ◽  
Mircea Anton ◽  
...  

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