Transition-Metal-Free Oxidation of Benzylic C–H Bonds of Six-Membered N-Heteroaromatic Compounds

Xianying Gao; Shuaijun Han; Maolin Zheng; Apeng Liang; Jingya Li; Dapeng Zou; Yusheng Wu; Yangjie Wu

doi:10.1021/acs.joc.9b00035

Transition-Metal-Free Oxidation of Benzylic C–H Bonds of Six-Membered N-Heteroaromatic Compounds

The Journal of Organic Chemistry ◽

10.1021/acs.joc.9b00035 ◽

2019 ◽

Vol 84 (7) ◽

pp. 4040-4049 ◽

Cited By ~ 1

Author(s):

Xianying Gao ◽

Shuaijun Han ◽

Maolin Zheng ◽

Apeng Liang ◽

Jingya Li ◽

...

Keyword(s):

Transition Metal ◽

Heteroaromatic Compounds ◽

Metal Free ◽

Free Oxidation

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ChemInform Abstract: Transition Metal-Free Oxidation of Ynamides for Synthesis of α-Keto-imides.

ChemInform ◽

10.1002/chin.201444040 ◽

2014 ◽

Vol 45 (44) ◽

pp. no-no

Author(s):

Takuya Chikugo ◽

Yuta Yauchi ◽

Masataka Ide ◽

Tetsuo Iwasawa

Keyword(s):

Transition Metal ◽

Metal Free ◽

Free Oxidation

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Reductive and Transition-Metal-Free: Oxidation of Secondary Alcohols by Sodium Hydride

Journal of the American Chemical Society ◽

10.1021/ja904224y ◽

2011 ◽

Vol 133 (13) ◽

pp. 5160-5160 ◽

Cited By ~ 4

Author(s):

Xinbo Wang ◽

Bo Zhang ◽

David Zhigang Wang

Keyword(s):

Transition Metal ◽

Sodium Hydride ◽

Secondary Alcohols ◽

Metal Free ◽

Free Oxidation

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Melamine Hydrogen Peroxide (MHP): Novel and Efficient Reagent for the Chemo- and Homoselective and Transition Metal–Free Oxidation of Thiols and Sulfides

Phosphorus Sulfur and Silicon and the Related Elements ◽

10.1080/10426500902758386 ◽

2009 ◽

Vol 185 (1) ◽

pp. 193-203 ◽

Cited By ~ 24

Author(s):

Gholamabbas Chehardoli ◽

Mohammad Ali Zolfigol

Keyword(s):

Hydrogen Peroxide ◽

Transition Metal ◽

Metal Free ◽

Free Oxidation ◽

Efficient Reagent

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Novel transition metal free oxidation of aromatic aldehydes to carboxylic acids using N-methylpyrrolidin-2-one hydrotribromide (MPHT) as catalyst and hydrogen peroxide as oxidant

Catalysis Communications ◽

10.1016/j.catcom.2006.05.035 ◽

2007 ◽

Vol 8 (1) ◽

pp. 83-87 ◽

Cited By ~ 24

Author(s):

Jomy K. Joseph ◽

Suman L. Jain ◽

Bir Sain

Keyword(s):

Hydrogen Peroxide ◽

Transition Metal ◽

Carboxylic Acids ◽

Aromatic Aldehydes ◽

Metal Free ◽

Free Oxidation

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Efficient Transition Metal Free Oxidation of Benzylic and Secondary Alcohols to the Carbonyl Compounds Using an N-Bromosuccinimide/NH4Cl System.

ChemInform ◽

10.1002/chin.200643036 ◽

2006 ◽

Vol 37 (43) ◽

Author(s):

Suman L. Jain ◽

Bir Sain

Keyword(s):

Transition Metal ◽

Carbonyl Compounds ◽

Secondary Alcohols ◽

Metal Free ◽

Free Oxidation

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ChemInform Abstract: Transition Metal-Free Oxidation of Activated Alcohols to Aldehydes and Ketones in 1,1,1,3,3,3-Hexafluoro-2-propanol.

ChemInform ◽

10.1002/chin.201245041 ◽

2012 ◽

Vol 43 (45) ◽

pp. no-no

Author(s):

Samad Khaksar ◽

Saeed Mohammadzadeh Talesh

Keyword(s):

Transition Metal ◽

Metal Free ◽

Aldehydes And Ketones ◽

Free Oxidation

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tert-Butylhydroperoxide-Mediated Oxidation of Carbazole-3-carboxyaldehydes

Synlett ◽

10.1055/s-0036-1591897 ◽

2018 ◽

Vol 29 (08) ◽

pp. 1084-1086

Author(s):

Ramu Meesala ◽

Ahmad Arshad ◽

Mallikarjuna Pichika ◽

Mohd Mordi ◽

Sharif Mansor

Keyword(s):

Aqueous Solution ◽

Transition Metal ◽

Carboxylic Acids ◽

Metal Free ◽

Tert Butylhydroperoxide ◽

Free Oxidation ◽

Mediated Oxidation

Oxidation of carbazole-3-carboxyaldehydes promoted by a 70% aqueous solution of tert-butylhydroperoxide leads to the corresponding carbazole-3-carboxylic acids in good yields. This transition-metal-free oxidation protocol is attractive for the synthesis of pharmaceutically important carbazole analogues.

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