1-[3-(Diethylamino)phenyl]ethyl (DEAPE): A Photolabile Protecting Group for Hydroxyl and Carboxyl Groups

2018 ◽  
Vol 83 (18) ◽  
pp. 10736-10742 ◽  
Author(s):  
Xiong Ding ◽  
Pengfei Wang
Keyword(s):  
Carboxyl Groups ◽  
Protecting Group ◽  
Photolabile Protecting Group

Photolabile Protecting Group‐Mediated Synthesis of 2‐Deoxy‐Glycosides

2021 ◽  
Author(s):  
Xiaoqian Li ◽  
Zhi Ma ◽  
Rongkun Liu ◽  
Mattan Hurevich ◽  
You Yang
Keyword(s):  
Protecting Group ◽  
Photolabile Protecting Group

Novel Photolabile Protecting Group for Carbonyl Compounds

2007 ◽  
Vol 9 (8) ◽  
pp. 1533-1535 ◽  
Author(s):  
Pengfei Wang ◽  
Huayou Hu ◽  
Yun Wang
Keyword(s):  
Carbonyl Compounds ◽  
Protecting Group ◽  
Photolabile Protecting Group

scholarly journals Sunscreen-Assisted Selective Photochemical Transformations

Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2125
Author(s):  
Or Eivgi ◽  
N. Gabriel Lemcoff
Keyword(s):  
Photochemical Reaction ◽  
Reaction Pathway ◽  
General Procedure ◽  
Molar Absorptivity ◽  
Photochemical Reactions ◽  
The Other ◽  
Protecting Group ◽  
Selective Reaction ◽  
Photochemical Transformations ◽  
Photolabile Protecting Group

In this review, we describe a simple and general procedure to accomplish selective photochemical reaction sequences for two chromophores that are responsive to similar light frequencies. The essence of the method is based on the exploitation of differences in the molar absorptivity at certain wavelengths of the photosensitive groups, which is enhanced by utilizing light-absorbing auxiliary filter molecules, or “sunscreens”. Thus, the filter molecule hinders the reaction pathway of the least absorbing molecule or group, allowing for the selective reaction of the other. The method was applied to various photochemical reactions, from photolabile protecting group removal to catalytic photoinduced olefin metathesis in different wavelengths and using different sunscreen molecules. Additionally, the sunscreens were shown to be effective also when applied externally to the reaction mixture, avoiding any potential chemical interactions between sunscreen and substrates and circumventing the need to remove the light-filtering molecules from the reaction mixture, adding to the simplicity and generality of the method.

A chemoselective photolabile protecting group for aldehydes

2020 ◽  
Vol 61 (14) ◽  
pp. 151709
Author(s):  
Jing Xu ◽  
Shouguo Zhang ◽  
Hongpeng Yang ◽  
Xiaoxue Wen ◽  
Tao Peng ◽  
...  
Keyword(s):  
Protecting Group ◽  
Photolabile Protecting Group

Synthesis and Photochemistry of a New Photolabile Protecting Group for Propargylic Alcohols

Synlett ◽  
2016 ◽  
Vol 28 (05) ◽  
pp. 560-564 ◽  
Author(s):  
Youlai Zhang ◽  
Huan Zhang ◽  
Chi Ma ◽  
Junru Li ◽  
Yasuhiro Nishiyama ◽  
...  
Keyword(s):  
Protecting Group ◽  
Propargylic Alcohols ◽  
Photolabile Protecting Group

Synthesis of photolabile protecting group (PPG) protected uronic acid building blocks: applications in carbohydrate synthesis with the assistance of a continuous flow photoreactor

2019 ◽  
Vol 6 (23) ◽  
pp. 3859-3863 ◽  
Author(s):  
Varsha Tiwari ◽  
Adesh Kumar Singh ◽  
Priyanka Chaudhary ◽  
Peter H. Seeberger ◽  
Jeyakumar Kandasamy
Keyword(s):  
Continuous Flow ◽  
Uronic Acid ◽  
Building Blocks ◽  
Protecting Group ◽  
Carbohydrate Synthesis ◽  
Photolabile Protecting Group

Photolabile groups protected uronic acid building blocks were synthesized and used for carbohydrate synthesis with the help of a continuous flow photo-reactor.

Development of a photolabile protecting group for phosphodiesters in oligonucleotides

2015 ◽  
Vol 25 (10) ◽  
pp. 2129-2132 ◽  
Author(s):  
Hisao Saneyoshi ◽  
Kanami Shimamura ◽  
Naoki Sagawa ◽  
Yuki Ando ◽  
Takahito Tomori ◽  
...  
Keyword(s):  
Protecting Group ◽  
Photolabile Protecting Group

scholarly journals New Safety-Catch Photolabile Protecting Group

2007 ◽  
Vol 9 (26) ◽  
pp. 5453-5456 ◽  
Author(s):  
Emmanuel Riguet ◽  
Christian G. Bochet
Keyword(s):  
Protecting Group ◽  
Photolabile Protecting Group
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