Mechanism of an Organoboron-Catalyzed Domino Reaction: Kinetic and Computational Studies of Borinic Acid-Catalyzed Regioselective Chloroacylation of 2,3-Epoxy Alcohols

2017 ◽  
Vol 82 (2) ◽  
pp. 1085-1095 ◽  
Author(s):  
Graham E. Garrett ◽  
Kashif Tanveer ◽  
Mark S. Taylor
Keyword(s):  
Reaction Kinetic ◽  
Domino Reaction ◽  
Computational Studies ◽  
Acid Catalyzed ◽  
Epoxy Alcohols ◽  
Borinic Acid

Borinic Acid Catalyzed, Regioselective Chloroacylations and Chlorosulfonylations of 2,3-Epoxy Alcohols

2015 ◽  
Vol 17 (14) ◽  
pp. 3482-3485 ◽  
Author(s):  
Kashif Tanveer ◽  
Kareem Jarrah ◽  
Mark S. Taylor
Keyword(s):  
Acid Catalyzed ◽  
Epoxy Alcohols ◽  
Borinic Acid

Borinic Acid-Catalyzed, Regioselective Ring Opening of 3,4-Epoxy Alcohols

2018 ◽  
Vol 20 (17) ◽  
pp. 5375-5379 ◽  
Author(s):  
Grace Wang ◽  
Graham E. Garrett ◽  
Mark S. Taylor
Keyword(s):  
Ring Opening ◽  
Acid Catalyzed ◽  
Epoxy Alcohols ◽  
Borinic Acid

ChemInform Abstract: Borinic Acid Catalyzed, Regioselective Chloroacylations and Chlorosulfonylations of 2,3-Epoxy Alcohols.

ChemInform ◽  
2015 ◽  
Vol 46 (46) ◽  
pp. no-no
Author(s):  
Kashif Tanveer ◽  
Kareem Jarrah ◽  
Mark S. Taylor
Keyword(s):  
Acid Catalyzed ◽  
Epoxy Alcohols ◽  
Borinic Acid

Borinic acid catalyzed α-addition to isocyanide with aldehyde and water

2011 ◽  
Vol 52 (20) ◽  
pp. 2557-2559 ◽  
Author(s):  
Takahiro Soeta ◽  
Yuuki Kojima ◽  
Yutaka Ukaji ◽  
Katsuhiko Inomata
Keyword(s):  
Acid Catalyzed ◽  
Borinic Acid

Intercepting the Nazarov Oxyallyl Intermediate with α-Formyl­vinyl Anion Equivalents to Access Formal Morita–Baylis–Hillman Alkylation Products

Synlett ◽  
2017 ◽  
Vol 28 (12) ◽  
pp. 1486-1490 ◽  
Author(s):  
F. West ◽  
Yen-Ku Wu ◽  
Rongrong Lin
Keyword(s):  
Lewis Acid ◽  
Stereoselective Synthesis ◽  
Domino Reaction ◽  
Alkylation Process ◽  
Acid Catalyzed

A Lewis acid catalyzed cationic domino reaction involving sequential electrocyclization and polar addition of allenol ethers onto the resulting oxyallyl species is described. The overall sequence allows a highly stereoselective synthesis of densely substituted cyclopentanoid compounds containing α-formylvinyl functionality which is formally equivalent to products of a Morita–Baylis–Hillman alkylation process.

Borinic Acid/Halide Co-catalyzed Semipinacol Rearrangements of 2,3-Epoxy Alcohols

2018 ◽  
Vol 20 (17) ◽  
pp. 5327-5331 ◽  
Author(s):  
Kashif Tanveer ◽  
Seung-Joon Kim ◽  
Mark S. Taylor
Keyword(s):  
Acid Halide ◽  
Epoxy Alcohols ◽  
Borinic Acid

Mechanistic insight into the acid-catalyzed isomerization of biomass-derived polysubstituted pyrrolidines: an experimental and DFT study

2017 ◽  
Vol 15 (2) ◽  
pp. 426-434 ◽  
Author(s):  
Gabriela G. Gerosa ◽  
Nicolás Grimblat ◽  
Rolando A. Spanevello ◽  
Alejandra G. Suárez ◽  
Ariel M. Sarotti
Keyword(s):  
Dft Study ◽  
Computational Studies ◽  
Mechanistic Insight ◽  
Acid Catalyzed ◽  
Insight Into

The mechanism of the acid-catalyzed isomerization of polysubstituted pyrrolidines was unravelled by a combination of experimental, spectroscopic and computational studies.

Kinetics and Products of the Acid-Catalyzed Ring-Opening of Atmospherically Relevant Butyl Epoxy Alcohols

2010 ◽  
Vol 114 (31) ◽  
pp. 8106-8113 ◽  
Author(s):  
Nathan C. Eddingsaas ◽  
David G. VanderVelde ◽  
Paul O. Wennberg
Keyword(s):  
Ring Opening ◽  
Acid Catalyzed ◽  
Epoxy Alcohols ◽  
Atmospherically Relevant
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