Sequential Addition Reaction of Sulfanylmethyllithiums and Grignard Reagents to Thioformamides Leading to the Formation of 2-Phenyl-2-sulfanylethyl Tertiary Amines

2016 ◽  
Vol 81 (18) ◽  
pp. 8131-8134 ◽  
Author(s):  
Toshiaki Murai ◽  
Natsumi Mutoh
Keyword(s):  
Addition Reaction ◽  
Grignard Reagents ◽  
Tertiary Amines ◽  
Sequential Addition

Integrated reactions based on the sequential addition to α-imino esters

2014 ◽  
Vol 86 (5) ◽  
pp. 755-764 ◽  
Author(s):  
Kaichiro Koyama ◽  
Isao Mizota ◽  
Makoto Shimizu
Keyword(s):  
Mannich Reaction ◽  
Addition Reaction ◽  
Imino Nitrogen ◽  
Crucial Step ◽  
Sequential Addition ◽  
Imino Esters ◽  
Sequential Reactions

AbstractThis article summarizes integrated sequential reactions with α-imino esters, where the umpolung addition reaction to the imino nitrogen followed by the second addition or oxidation is the crucial step. The following four types of reactions are discussed: (1) tandem N-ethylation/Mannich reaction; (2) N-alkylation/addition reaction; (3) synthesis of indolin-3-ones and tetrahydro-4-quinolones; (4) regioselective tandem N-alkylation/ C-acylation of β,γ-alkynyl α-imino esters.

scholarly journals Mechanism of the Grignard Addition Reaction. XI. Electrode Kinetics and Chemical Reactivity of Grignard Reagents.

1974 ◽  
Vol 28b ◽  
pp. 809-812 ◽  
Author(s):  
Torkil Holm ◽  
Alf Claesson ◽  
Conny Bogentoft ◽  
Ilona Szabo-Lin ◽  
Claes Guthenberg ◽  
...  
Keyword(s):  
Addition Reaction ◽  
Chemical Reactivity ◽  
Grignard Reagents ◽  
Electrode Kinetics ◽  
Grignard Addition
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