Nazarov Reactions Intercepted by (4 + 3) Cycloadditions with Oxygen-Substituted Dienes

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The SnCl4 mediated reactions of cross conjugated aryl enynone-Co2(CO)6 and dienynone-Co2(CO)6 complexes afford benzocycloheptynone complexes or cycloheptenynone complexes in a thermal vinylogous Nazarov process. The rate of ring closure is...


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