Iron-Facilitated Oxidative Radical Decarboxylative Cross-Coupling between α-Oxocarboxylic Acids and Acrylic Acids: An Approach to α,β-Unsaturated Carbonyls

2015 ◽  
Vol 80 (7) ◽  
pp. 3586-3596 ◽  
Author(s):  
Qing Jiang ◽  
Jing Jia ◽  
Bin Xu ◽  
An Zhao ◽  
Can-Cheng Guo
Keyword(s):  
Cross Coupling ◽  
Unsaturated Carbonyls ◽  
Acrylic Acids ◽  
Oxocarboxylic Acids

The Merger of CF3SO2Na and Palladium Catalysis to Enable Decarboxylative Cross-Coupling for the Synthesis of Aromatic Ketones under Room Temperature

2021 ◽  
Author(s):  
Pan Xie ◽  
Cheng Xue ◽  
Cancan Wang ◽  
Dongdong Du ◽  
Sanshan Shi
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Palladium Catalysis ◽  
Cross Coupling ◽  
Boronic Acids ◽  
Aromatic Ketones ◽  
Aryl Ketones ◽  
Oxocarboxylic Acids

A CF3SO2Na/Pd(OAc)2 co-catalyzed strategy is developed to produce aryl ketones via visible-light-induced decarboxylative cross-coupling of α-oxocarboxylic acids and aryl boronic acids. This process was perfomed under air at room temperature,...

Palladium-catalyzed regioselective synthesis of B(4,5)- or B(4)-substituted o-carboranes containing α,β-unsaturated carbonyls

2020 ◽  
Vol 18 (25) ◽  
pp. 4723-4727 ◽  
Author(s):  
Chuyi Zhang ◽  
Qian Wang ◽  
Song Tian ◽  
Jianwei Zhang ◽  
Jiaoyi Li ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Regioselective Synthesis ◽  
Cross Coupling Reaction ◽  
Unsaturated Carbonyls ◽  
Palladium Catalyzed

B(4,5)- or B(4)-Substituted o-carboranes containing α,β-unsaturated carbonyls are regioselectively synthesized through a Pd-catalyzed decarboxylation cross coupling reaction.

Intramolecularly Activated Vinylsilanes: Fluoride-Free Cross-Coupling of (Z)-?-(Trialkylsilyl)acrylic Acids.

ChemInform ◽  
2005 ◽  
Vol 36 (20) ◽  
Author(s):  
Mitsuru Shindo ◽  
Kenji Matsumoto ◽  
Kozo Shishido
Keyword(s):  
Cross Coupling ◽  
Acrylic Acids

Intramolecularly Activated Vinylsilanes: Fluoride-Free Cross-Coupling of (Z)-β-(Trialkylsilyl)acrylic Acids

Synlett ◽  
2004 ◽  
Vol 2005 (01) ◽  
pp. 176-178 ◽  
Author(s):  
Mitsuru Shindo ◽  
Kenji Matsumoto ◽  
Kozo Shishido
Keyword(s):  
Cross Coupling ◽  
Acrylic Acids

Palladium‐Catalysed Oxidative Decarboxylative Cross‐Coupling of Heteroarenes with CF 3 ‐Acrylic Acids

2021 ◽  
Vol 6 (29) ◽  
pp. 7367-7371
Author(s):  
Pan Xiao ◽  
Xavier Pannecoucke ◽  
Jean‐Philippe Bouillon ◽  
Samuel Couve‐Bonnaire
Keyword(s):  
Cross Coupling ◽  
Acrylic Acids
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