Visible-Light-Induced Deaminative Alkylation/Cyclization of Alkyl Amines with N-Methacryloyl-2-phenylbenzoimidazoles in Continuous-Flow Organo-Photocatalysis

2021 ◽  
Vol 86 (18) ◽  
pp. 12908-12921 ◽  
Author(s):  
Vankudoth Ramesh ◽  
Maram Gangadhar ◽  
Jagadeesh Babu Nanubolu ◽  
Praveen Reddy Adiyala
2020 ◽  
Author(s):  
Cristian Cavedon ◽  
Eric T. Sletten ◽  
Amiera Madani ◽  
Olaf Niemeyer ◽  
Peter H. Seeberger ◽  
...  

Protecting groups are key in the synthesis of complex molecules such as carbohydrates to distinguish functional groups of similar reactivity. The harsh conditions required to cleave stable benzyl ether protective groups are not compatible with many other protective and functional groups. The mild, visible light-mediated debenzylation disclosed here renders benzyl ethers orthogonal protective groups. Key to success is the use of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) as stoichiometric or catalytic photooxidant such that benzyl ethers can be cleaved in the presence of azides, alkenes, and alkynes. The reaction time for this transformation can be reduced from hours to minutes in continuous flow. <br>


2017 ◽  
Vol 8 (42) ◽  
pp. 6496-6505 ◽  
Author(s):  
Maarten Rubens ◽  
Phanumat Latsrisaeng ◽  
Tanja Junkers

Visible-light induced photoiniferter polymerization in continuous flow reactors is very efficient in yielding low dispersity methacrylate block copolymers.


2016 ◽  
Vol 1 (6) ◽  
pp. 636-648 ◽  
Author(s):  
Thomas H. Rehm ◽  
Sylvain Gros ◽  
Patrick Löb ◽  
Albert Renken

A microstructured falling film reactor was applied to the dye-sensitized photochemical conversion of 1,5-dihydroxynaphthalene to juglone for reactor and process evaluation.


2020 ◽  
Vol 362 (15) ◽  
pp. 3116-3120
Author(s):  
Yu‐Zhao Wang ◽  
Wu‐Jie Lin ◽  
Jian‐Yu Zou ◽  
Wei Yu ◽  
Xue‐Yuan Liu
Keyword(s):  

2019 ◽  
Vol 2020 (10) ◽  
pp. 1429-1432 ◽  
Author(s):  
Anne-Laure Barthelemy ◽  
Guillaume Dagousset ◽  
Emmanuel Magnier

2020 ◽  
Vol 22 (5) ◽  
pp. 1565-1571 ◽  
Author(s):  
Praveen Reddy Adiyala ◽  
Seungwook Jang ◽  
Niraj K. Vishwakarma ◽  
Yoon-Ho Hwang ◽  
Dong-Pyo Kim

Continuous-flow visible-light-induced decarboxylative annulation using a polydimethylsiloxane microreactor containing immobilized Ru3+ has been established for the construction of fused imidazole derivatives.


ChemSusChem ◽  
2019 ◽  
Vol 12 (12) ◽  
pp. 2581-2586 ◽  
Author(s):  
Shinde Vidyacharan ◽  
Bandaru T. Ramanjaneyulu ◽  
Seungwook Jang ◽  
Dong‐Pyo Kim

2018 ◽  
Vol 51 (14) ◽  
pp. 5165-5172 ◽  
Author(s):  
Neomy Zaquen ◽  
Jonathan Yeow ◽  
Tanja Junkers ◽  
Cyrille Boyer ◽  
Per B. Zetterlund

Tetrahedron ◽  
2019 ◽  
Vol 75 (26) ◽  
pp. 3636-3642 ◽  
Author(s):  
Quan Shu ◽  
Yaming Li ◽  
Tong Liu ◽  
Siyu Zhang ◽  
Linlin Jiang ◽  
...  

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