Enantioselective Total Syntheses of the Proposed and Revised Structures of Methoxystemofoline: A Stereochemical Revision

2021 ◽  
Author(s):  
Su-Yu Huang ◽  
Long-Hui Gao ◽  
Xiong-Zhi Huang ◽  
Pei-Qiang Huang
Keyword(s):  
Total Syntheses

Development of Recent Total Syntheses Based on the Heck Reaction

2013 ◽  
Vol 17 (19) ◽  
pp. 2192-2224 ◽  
Author(s):  
Majid Heravi ◽  
Elaheh Hashemi ◽  
Nazanin Ghobadi
Keyword(s):  
Heck Reaction ◽  
Total Syntheses

Applications of Barton-McCombie Reaction in Total Syntheses

2014 ◽  
Vol 11 (6) ◽  
pp. 787-823 ◽  
Author(s):  
Majid Heravi ◽  
Atefe Bakhtiari ◽  
Zeinab Faghihi
Keyword(s):  
Total Syntheses

Formal Total Syntheses of Crocacin A-D

2005 ◽  
Vol 70 (10) ◽  
pp. 1696-1708 ◽  
Author(s):  
Magnus Besev ◽  
Christof Brehm ◽  
Alois Fürstner
Keyword(s):  
Natural Products ◽  
Aldol Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Total Syntheses ◽  
Cross Coupling Reactions ◽  
Palladium Catalyzed ◽  
The Common ◽  
Selective Addition

A concise route to the common polyketide fragment5of crocacin A-D (1-4) is presented which has previously been converted into all members of this fungicidal and cytotoxic family of dipeptidic natural products by various means. Our synthesis features asyn-selective titanium aldol reaction controlled by a valinol-derived auxiliary, a zinc-mediated, palladium-catalyzedanti-selective addition of propargyl mesylate10to the chiral aldehyde9, as well as a comparison of palladium-catalyzed Stille and Suzuki cross-coupling reactions for the formation of the diene moiety of the target.

Total syntheses of (+)-paeonilactone B and (−)-paeonisuffrone

1995 ◽  
Vol 36 (2) ◽  
pp. 267-268 ◽  
Author(s):  
Susumi Hatakeyama ◽  
Mitsuhiro Kawamura ◽  
Yasuko Mukugi ◽  
Hiroshi Irie
Keyword(s):  
Total Syntheses

Total syntheses of (+)- and (−)-Crinane via Pd(0)-Catalyzed deacylative allylation

Tetrahedron ◽  
2021 ◽  
Vol 82 ◽  
pp. 131928
Author(s):  
Mrinal K. Das ◽  
Abhinay Yadav ◽  
Satyajit Majumder ◽  
Ayan Mondal ◽  
Alakesh Bisai
Keyword(s):  
Total Syntheses

scholarly journals Synthesis and Biological Activities of Cyclodepsipeptides of Aurilide Family from Marine Origin

Marine Drugs ◽  
2021 ◽  
Vol 19 (2) ◽  
pp. 55
Author(s):  
Synthia Michon ◽  
Florine Cavelier ◽  
Xavier J. Salom-Roig
Keyword(s):  
Cell Lines ◽  
Cancer Cell ◽  
Biological Activities ◽  
Natural Compounds ◽  
Cancer Cell Lines ◽  
Hydroxy Ester ◽  
Marine Cyanobacteria ◽  
Synthetic Analogues ◽  
Marine Origin ◽  
Total Syntheses

Aurilides are a class of depsipeptides occurring mainly in marine cyanobacteria. Members of the aurilide family have shown to exhibit strong cytotoxicity against various cancer cell lines. These compounds bear a pentapeptide, a polyketide, and an α-hydroxy ester subunit in their structure. A large number of remarkable studies on aurilides have emerged since 1996. This comprehensive account summarizes the biological activities and total syntheses of natural compounds of the aurilide family as well as their synthetic analogues.

Sign in / Sign up

Export Citation Format

Share Document