Cobalt-Catalyzed Protodeboronation of Aryl and Vinyl Boronates

2021 ◽  
Author(s):  
Ninglin Li ◽  
Fuqiang Xiong ◽  
Ke Gao
Keyword(s):  
Vinyl Boronates

scholarly journals Nickel-Catalyzed Three-Component Olefin Reductive Dicarbofunctionalization to Access Highly Functionalized Alkylborates

2020 ◽  
Author(s):  
Xiao-Xu Wang ◽  
Xi Lu ◽  
Shi-Jiang He ◽  
Yao Fu
Keyword(s):  
Natural Products ◽  
Late Stage ◽  
Functional Group ◽  
Coupling Efficiency ◽  
Convergent Synthesis ◽  
Drug Molecules ◽  
Aryl Iodides ◽  
Alkyl Bromides ◽  
Vinyl Boronates ◽  
Convenient Access

We report a three-component olefin reductive dicarbofunctionalization for constructing densely functionalized alkylborates, specifically, nickel-catalyzed reductive dialkylation and alkylarylation of vinyl boronates with a variety of alkyl bromides and aryl iodides. This reaction exhibits good coupling efficiency and excellent functional group compatibility, providing convenient access to the late-stage modification of complex natural products and drug molecules. Combined with versatile alkylborate transformations, this reaction could also find applications in the modular and convergent synthesis of complex, densely functionalized compounds.

A convergent approach to γ-carbonyl vinyl boronates

2005 ◽  
pp. 3077 ◽  
Author(s):  
Markus R. Heinrich ◽  
Lisa A. Sharp ◽  
Samir Z. Zard
Keyword(s):  
Convergent Approach ◽  
Vinyl Boronates

scholarly journals Application of Green Solvents: PEG and scCO2 in the Mono- or Biphasic Catalytic Systems for the Repetitive Batch Coupling of Vinylsilanes with Vinyl Boronates toward 1-Boryl-1-silylethenes

2020 ◽  
Vol 59 (23) ◽  
pp. 17555-17564
Author(s):  
Monika Ludwiczak ◽  
Jakub Szyling ◽  
Adriana Garbicz ◽  
Tomasz Sokolnicki ◽  
Jadwiga Pyziak ◽  
...  
Keyword(s):  
Green Solvents ◽  
Catalytic Systems ◽  
Vinyl Boronates

Iron-Catalyzed Borylation Reactions of Alkynes: An Efficient Synthesis of E-Vinyl Boronates

Synlett ◽  
2014 ◽  
Vol 25 (08) ◽  
pp. 1132-1136 ◽  
Author(s):  
Bojja Sreedhar ◽  
Vikas Rawat
Keyword(s):  
Efficient Synthesis ◽  
Vinyl Boronates

Synthesis of Vinyl Boronates

Synfacts ◽  
2015 ◽  
Vol 11 (07) ◽  
pp. 0753-0753
Keyword(s):  
Vinyl Boronates

ChemInform Abstract: Iridium-Catalyzed Enantioselective Hydrogenation of Vinyl Boronates.

ChemInform ◽  
2010 ◽  
Vol 41 (10) ◽  
Author(s):  
Alexander Paptchikhine ◽  
Pradeep Cheruku ◽  
Mattias Engman ◽  
Pher G. Andersson
Keyword(s):  
Enantioselective Hydrogenation ◽  
Vinyl Boronates

ChemInform Abstract: Copper-Promoted Coupling of Vinyl Boronates and Alcohols: A Mild Synthesis of Allyl Vinyl Ethers.

ChemInform ◽  
2010 ◽  
Vol 41 (27) ◽  
pp. no-no
Author(s):  
Ryan E. Shade ◽  
Alan M. Hyde ◽  
John-Carl Olsen ◽  
Craig A. Merlic
Keyword(s):  
Vinyl Ethers ◽  
Vinyl Boronates ◽  
Allyl Vinyl Ethers
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