Tricyclo[2.1.0.02,5]pent-3-ylidene: Stereoelectronic Control of Bridge-Flapping within a Nonclassical Nucleophilic Carbene

Murray G. Rosenberg; Udo H. Brinker

doi:10.1021/acs.joc.0c02414

Tricyclo[2.1.0.02,5]pent-3-ylidene: Stereoelectronic Control of Bridge-Flapping within a Nonclassical Nucleophilic Carbene

The Journal of Organic Chemistry ◽

10.1021/acs.joc.0c02414 ◽

2020 ◽

Vol 86 (1) ◽

pp. 878-891

Author(s):

Murray G. Rosenberg ◽

Udo H. Brinker

Keyword(s):

Stereoelectronic Control

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ChemInform Abstract: MECHANISM OF HYDROLYSIS OF IMIDATE SALTS. IMPORTANCE OF STEREOELECTRONIC CONTROL AND PH OF THE REACTION MEDIUM ON THE CLEAVAGE OF TETRAHEDRAL INTERMEDIATES

Chemischer Informationsdienst ◽

10.1002/chin.197610068 ◽

1976 ◽

Vol 7 (10) ◽

pp. no-no

Author(s):

PIERRE DESLONGCHAMPS ◽

ROLAND J. TAILLEFER

Keyword(s):

Reaction Medium ◽

Mechanism Of Hydrolysis ◽

Stereoelectronic Control ◽

Hydrolysis Of ◽

Tetrahedral Intermediates

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Stereoelectronic Control on the Kinetic Stability of β-Acetoxy-Substituted (η3-Allyl)palladium Complexes in a Mild Acidic Medium

Organometallics ◽

10.1021/om970076c ◽

1997 ◽

Vol 16 (17) ◽

pp. 3779-3785 ◽

Cited By ~ 12

Author(s):

Kálmán J. Szabó ◽

Eike Hupe ◽

Anna L. E. Larsson

Keyword(s):

Acidic Medium ◽

Kinetic Stability ◽

Palladium Complexes ◽

Stereoelectronic Control

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A reaffirmation of stereoelectronic control in the alkaline hydrolysis of methyl and ethyl ethylene phosphate

Tetrahedron ◽

10.1016/s0040-4020(01)89979-8 ◽

1987 ◽

Vol 43 (3) ◽

pp. 469-478 ◽

Cited By ~ 5

Author(s):

David G. Gorenstein ◽

Andrew Charng ◽

Ji-Charng Yang

Keyword(s):

Alkaline Hydrolysis ◽

Stereoelectronic Control ◽

Hydrolysis Of

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Stereoelectronic control in the reactions of ketones and their enol(ate)s

Tetrahedron ◽

10.1016/s0040-4020(01)81073-5 ◽

1989 ◽

Vol 45 (16) ◽

pp. 4913-4938 ◽

Cited By ~ 43

Author(s):

Ralph M. Pollack

Keyword(s):

Stereoelectronic Control

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stereoelectronic control

Catalysis from A to Z ◽

10.1002/9783527809080.cataz15723 ◽

2020 ◽

Keyword(s):

Stereoelectronic Control

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ChemInform Abstract: STEREOELECTRONIC CONTROL IN ACID AND BASE CATALYSIS OF AMIDE HYDROLYSIS. A THEORETICAL STUDY

Chemischer Informationsdienst ◽

10.1002/chin.198021138 ◽

1980 ◽

Vol 11 (21) ◽

Author(s):

J.-M. LEHN ◽

G. WIPFF

Keyword(s):

Theoretical Study ◽

Base Catalysis ◽

Amide Hydrolysis ◽

Acid And Base ◽

Stereoelectronic Control ◽

Acid And Base Catalysis

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Lack of steric hindrance and of stereoelectronic control in proton removal from 4,4-disubstituted cyclohexanones

Journal of the American Chemical Society ◽

10.1021/ja01026a033 ◽

1968 ◽

Vol 90 (24) ◽

pp. 6749-6751 ◽

Cited By ~ 9

Author(s):

Frederick G. Bordwell ◽

Richard G. Scamehorn

Keyword(s):

Steric Hindrance ◽

Stereoelectronic Control

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ChemInform Abstract: LONG-RANGE STEREOELECTRONIC CONTROL BY NORBORNYL FRAMEWORKS OF CYCLOADDITION AND ELECTROPHILIC PROCESSES

Chemischer Informationsdienst ◽

10.1002/chin.198505358 ◽

1985 ◽

Vol 16 (5) ◽

Author(s):

L. A. PAQUETTE

Keyword(s):

Long Range ◽

Stereoelectronic Control

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Stereoelectronic control of ? proton abstraction from iminium ions

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39780000049 ◽

1978 ◽

pp. 49 ◽

Cited By ~ 4

Author(s):

Herbert E. Ferran ◽

Rex D. Roberts ◽

James N. Jacob ◽

Thomas A. Spencer

Keyword(s):

Proton Abstraction ◽

Iminium Ions ◽

Stereoelectronic Control

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Stereoelectronic control of the tertiary ketol rearrangement: implications for the mechanism of the reaction catalysed by the enzymes of branched-chain amino acid metabolism, reductoisomerase and acetolactate decarboxylase

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29910000053 ◽

1991 ◽

pp. 53 ◽

Cited By ~ 8

Author(s):

David H. G. Crout ◽

C. Rupert McIntyre ◽

Nathaniel W. Alcock

Keyword(s):

Amino Acid ◽

Amino Acid Metabolism ◽

Acid Metabolism ◽

Branched Chain Amino Acid ◽

Stereoelectronic Control ◽

Branched Chain ◽

Mechanism Of The Reaction

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