scholarly journals Correction to Calculation of Ligand Dissociation Energies in Large Transition-Metal Complexes

2019 ◽  
Vol 15 (7) ◽  
pp. 4295-4296 ◽  
Author(s):  
Tamara Husch ◽  
Leon Freitag ◽  
Markus Reiher
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Ligand Dissociation ◽  
Dissociation Energies

Transfer of trisbipyridine transition metal complexes across the water-dichloroethane interface

1987 ◽  
Vol 52 (4) ◽  
pp. 838-847 ◽  
Author(s):  
Josef Hanzlík ◽  
Jan Hovorka ◽  
Anna Maria Camus
Keyword(s):  
Charge Transfer ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Divalent Cation ◽  
Central Atom ◽  
Transport Parameters ◽  
Chemical Changes ◽  
Ligand Dissociation ◽  
Voltammetric Measurements

Transfer of trisbipyridine transition metal complexes [M(bpy)3]2+ (bpy = bipyridine) across the water-1,2-dichloroethane interface can be classified as a simple transfer of a divalent cation in case that the central atom M = Fe, Ni, Ru or Os, while for M = Co, Cu or Zn the charge transfer is accompanied by considerable chemical changes, such as the ligand dissociation and the solvolysis. Thermodynamic and transport parameters characterizing the transfer of [M(bpy)3]2+ ions from water to 1,2-dichloroethane have been determined from voltammetric measurements.

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

Density Functional Calculations of EPR Parameter g Tensors of Some Transition Metal Complexes

2011 ◽  
Vol 2 (2) ◽  
pp. 139-141
Author(s):  
Vinita Prajapati ◽  
◽  
P.L.Verma P.L.Verma ◽  
Dhirendra Prajapati ◽  
B.K.Gupta B.K.Gupta
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Density Functional Calculations ◽  
Density Functional

Synthesis, Characterization and in vitro Biological Evaluation of a New Schiff Base Derived from Drug and its Complexes with Transition Metal Ions

2018 ◽  
Vol 69 (7) ◽  
pp. 1678-1681
Author(s):  
Amina Mumtaz ◽  
Tariq Mahmud ◽  
M. R. J. Elsegood ◽  
G. W. Weaver
Keyword(s):  
Schiff Base ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Free Ligand ◽  
Transition Metal Ions ◽  
Biological Evaluation ◽  
Pyridoxal Hydrochloride

New series of copper (II), cobalt (II), zinc (II), nickel (II), manganese (II), iron (II) complexes of a novel Schiff base were prepared by the condensation of sulphadizine and pyridoxal hydrochloride. The ligand and metal complexes were characterized by utilizing different instrumental procedures like microanalysis, thermogravimetric examination and spectroscopy. The integrated ligand and transition metal complexes were screened against various bacteria and fungus. The studies demonstrated the enhanced activity of metal complexes against reported microbes when compared with free ligand.

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