Experimental Measurements of Volumetric and Acoustic Properties of Binary Mixtures of 1-Butyl-3-methylimidazolium Hexafluorophosphate with Molecular Solvents

2020 ◽  
Vol 65 (7) ◽  
pp. 3406-3419
Author(s):  
Heloísa Emi Hoga ◽  
Gustavo Vieira Olivieri ◽  
Ricardo Belchior Torres
Keyword(s):  
Binary Mixtures ◽  
Acoustic Properties ◽  
Experimental Measurements ◽  
Molecular Solvents

Ionic liquids: Solvation ability and polarity

2009 ◽  
Vol 81 (4) ◽  
pp. 767-776 ◽  
Author(s):  
Cinzia Chiappe ◽  
Marco Malvaldi ◽  
Christian Silvio Pomelli
Keyword(s):  
Ionic Liquids ◽  
Kinetic Data ◽  
Classification Criteria ◽  
Experimental Measurements ◽  
Molecular Liquids ◽  
The Poor ◽  
Poor Understanding ◽  
The Many ◽  
Molecular Solvents

The role of ionic liquids (ILs) as solvents in chemistry is limited by the poor understanding of the solvation phenomenon in these media. The usual classification criteria used for molecular solvents through various experimental measurements fail to insert ILs into a univocal classification for ILs. Here, we first discuss the unsuitability of the usual interpretative scheme for molecular liquids and elucidate schematically the mechanism of solvation in ILs, pointing out the peculiarities that differentiate them with respect to molecular liquids. Second, we focus on reactivity and reaction kinetics in ILs, underlining the many problems that the complexity of these media reflects on the interpretation of kinetic data and some possible approaches to understand qualitatively the (often not trivial) kinetic problems for reactions performed in ILs.

scholarly journals Universality in Critical Anomaly of Acoustic Properties of Binary Mixtures

1984 ◽  
Vol 23 (S1) ◽  
pp. 60 ◽  
Author(s):  
Hajime Tanaka ◽  
Toshio Nishi ◽  
Yasaku Wada
Keyword(s):  
Binary Mixtures ◽  
Acoustic Properties ◽  
Critical Anomaly

Vapor Liquid Equilibria of Binary Mixtures of 1-Butyl-3-methylimidazolium Triflate (C4mimTfO) and Molecular Solvents: n-Alkyl Alcohols and Water

2018 ◽  
Vol 122 (22) ◽  
pp. 6017-6032 ◽  
Author(s):  
Marcus Stuckenholz ◽  
Emanuel A. Crespo ◽  
Lourdes F. Vega ◽  
Pedro J. Carvalho ◽  
João A. P. Coutinho ◽  
...  
Keyword(s):  
Binary Mixtures ◽  
Vapor Liquid Equilibria ◽  
Molecular Solvents ◽  
Vapor Liquid

Ionic Liquids as Binary Mixtures with Selected Molecular Solvents, Reactivity Characterisation and Molecular-Microscopic Properties

2012 ◽  
pp. 335-362 ◽  
Author(s):  
Pedro M. E. Mancini ◽  
Maria V. Bravo ◽  
Graciela G. Fortunato ◽  
Claudia G. Adam
Keyword(s):  
Ionic Liquids ◽  
Binary Mixtures ◽  
Molecular Solvents

Solvatochromism of Binary Mixtures of 2,2,2-Trifluoroethanol + Ionic Liquid [bmim][Tf2N]: A Comparative Study with Molecular Solvents

2019 ◽  
Vol 64 (3) ◽  
pp. 1140-1154 ◽  
Author(s):  
Md Rabiul Islam ◽  
Faiz Warsi ◽  
Abbul Bashar Khan ◽  
Tasneem Kausar ◽  
Imran Khan ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Comparative Study ◽  
Binary Mixtures ◽  
Molecular Solvents
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