Thermodynamic Modeling of Time-Dependent Interfacial Properties in Reactive Liquid–Liquid Systems Close to the Critical Point

2019 ◽  
Vol 65 (2) ◽  
pp. 312-318
Author(s):  
Andreas Danzer ◽  
Sabine Enders
Keyword(s):  
Critical Point ◽  
Thermodynamic Modeling ◽  
Interfacial Properties ◽  
Time Dependent ◽  
Liquid Systems ◽  
Reactive Liquid

Thermodynamic modeling of ternary and quaternary (liquid+liquid) systems containing water, FeCl3, HCl and diisopropyl ether

2013 ◽  
Vol 67 ◽  
pp. 83-90
Author(s):  
Miran Milosevic ◽  
Ilse Hendriks ◽  
Ralph E.R. Smits ◽  
Boelo Schuur ◽  
André B. de Haan
Keyword(s):  
Thermodynamic Modeling ◽  
Diisopropyl Ether ◽  
Liquid Systems

scholarly journals Thermodynamic modeling of ternary liquid-liquid systems with forming immiscibility islands

2013 ◽  
Vol 56 (6) ◽  
pp. 1034-1042 ◽  
Author(s):  
Andre Zuber ◽  
Rodrigo Raimundo ◽  
Marcos Rogério Mafra ◽  
Lúcio Cardozo Filho ◽  
José Vladimir Oliveira ◽  
...  
Keyword(s):  
Thermodynamic Modeling ◽  
Liquid Systems

Critical point phenomena in the electrical resistivity of binary liquid systems: CS2 + CH3CN and CS2 + CH3NO2

Pramana ◽  
1976 ◽  
Vol 7 (4) ◽  
pp. 266-276 ◽  
Author(s):  
E S R Gopal ◽  
M V Lele ◽  
J Ramakrishnan ◽  
P Chandra Sekhar ◽  
S V Subramanyam
Keyword(s):  
Electrical Resistivity ◽  
Critical Point ◽  
Binary Liquid ◽  
Critical Point Phenomena ◽  
Liquid Systems

Solubility and critical phenomena in reactive liquid–liquid systems

2009 ◽  
Vol 81 (9) ◽  
pp. 1591-1602 ◽  
Author(s):  
Alexander Toikka ◽  
Maria Toikka
Keyword(s):  
Chemical Equilibrium ◽  
Ternary Systems ◽  
Phase Rule ◽  
Fluid Mixtures ◽  
Composition Tetrahedron ◽  
Liquid Systems ◽  
Reactive Liquid ◽  
Nonequilibrium Chemical Reaction ◽  
Critical Phases ◽  
Binary And Ternary Systems

The goal of this work is to consider solubility phenomena in reactive fluid mixtures with liquid-phase splitting. One of the main tasks is to analyze peculiarities of liquid–liquid (LL) systems with equilibrium and nonequilibrium chemical reaction. The special aim is to consider the critical states in these systems. The reactive liquid–liquid equilibrium (LLE) is treated on the base of phase rule. The topology of diagrams of reactive LLE is discussed for some types of binary and ternary systems. Examples are presented of a possible transformation of phase diagrams caused by the shifting of chemical equilibrium and by changes in the shape of the binodal. The transformations resulting in the reactive critical phase formation are considered. Quaternary mixtures are also discussed with the use of experimental data on the solubility in the system with n-propyl acetate synthesis reaction. The mutual crossing of the chemical equilibrium surface and binodal in the composition tetrahedron leads to the origin of the area of simultaneous chemical and LLE with two critical points (reactive critical phases). The shape of the curve of simultaneous chemical and phase equilibrium is also presented in the square of transformed composition variables.

scholarly journals Critical Fluctuations of Time-Dependent Magnetization in Ordering Processes near the Disorder-Induced Critical Point

2008 ◽  
Author(s):  
Hiroki Ohta ◽  
Shin-ichi Sasa ◽  
Michio Tokuyama ◽  
Irwin Oppenheim ◽  
Hideya Nishiyama
Keyword(s):  
Critical Point ◽  
Time Dependent ◽  
Critical Fluctuations
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