The Solubility of Hydrogen Sulfide and Carbon Dioxide in Propylene Carbonate

2015 ◽  
Vol 60 (12) ◽  
pp. 3738-3744 ◽  
Author(s):  
Fang-Yuan Jou ◽  
Alan E. Mather ◽  
Kurt A. G. Schmidt
1988 ◽  
Vol 44 (1) ◽  
pp. 105-115 ◽  
Author(s):  
Florentino Murrieta-Guevara ◽  
Ascencion Romero-Martinez ◽  
Arturo Trejo

1992 ◽  
Vol 70 (1) ◽  
pp. 55-57 ◽  
Author(s):  
Yuming Xu ◽  
Lili Li ◽  
Loren G. Hepler

Partial molar volumes at infinite dilution for three acidic gases (carbon dioxide, hydrogen sulfide, and sulfur dioxide) in four physical solvents (propylene carbonate, methyl cyanoacetate, N-formyl morpholine, and Selexol) have been obtained using our new dilatometer. These partial molar volumes, in combination with the Henry's law constants obtained previously, have been used in the Krichevsky–Kasarnovsky equation for predicting the solubilities of acidic gases in physical solvents at high pressures. Keywords: partial molar volume, solubility, physical solvents.


2021 ◽  
Vol 12 (12) ◽  
pp. 1776-1786
Author(s):  
Zhou Wang ◽  
Ying Mu

Stereoregular poly(propylene carbonate)s and poly(propylene succinate-block-carbonate)s were synthesized with new chiral salenCo(iii) catalysts carrying bulky substituents.


2013 ◽  
Vol 53 (6) ◽  
pp. 580
Author(s):  
Mathew K. Pines ◽  
Tracy Muller ◽  
Clive J. C. Phillips

Noxious gases produced at hazardous concentrations in animal housing systems may affect the health and wellbeing of both animals and workers. In order to determine if the gaseous emissions from a pre-export assembly depot for sheep constituted a risk, atmospheric ammonia was measured in eight sheep buildings at an Australian assembly depot. Additionally, meteorological variables and distance from excreta were measured to determine their influence on ammonia, carbon dioxide and hydrogen sulfide concentrations. Repeat measurements were made at 12 sites in each building on 4 separate days, and four buildings were mapped using longitudinal and latitudinal transects. Concentrations of ammonia, carbon dioxide and hydrogen sulfide were all below the recommended safety thresholds for humans and livestock. There were positive correlations between ammonia and the following variables: ambient temperature and moisture content, and negative correlations with distance from animal excreta. Understanding these relationships will help to understand the reasons for ammonia accumulation in such buildings.


2012 ◽  
Vol 10 (3) ◽  
pp. 97-118
Author(s):  
Krzysztof Biernat ◽  
Izabela Różnicka

Both governmental and international programs support the promotion of biofuels and aim to increase the limit of renewable energy used in the fuel energy balance. Biogas is produced during the anaerobic methane fermentationprocess and it is known as a significant source of renewable energy, contributing to agriculture and environmental protection. Three types of biogas can be distinguished: biogas from sewage sludge, biogas collected from land`fils, andagricultural biogas. There are several possibilities of using upgraded biogas. Biogas can be used in cogeneration systems to provide heat and electricity, in transportation as a motor fuel and in the production of biohydrogen. Biogas upgrading process leads to a product which is characterized by the same parameters as compressed natural gas. Direct biogas use in the production of hydrogen is possible because of prior purification from traces like hydrogen sulfide, except carbon dioxide, by which the reaction can proceed in the desired manner.


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