Soluting Effect in Ternary Aqueous Solutions of Ionic Liquids by Isopiestic Equilibrium Studies and Applying the Linear Isopiestic Relations for Estimating Their Speed of Sound, Density, and Surface Tension Data

2020 ◽  
Vol 65 (9) ◽  
pp. 4435-4442 ◽  
Author(s):  
Sahar Shokri ◽  
Rahmat Sadeghi
Keyword(s):  
Surface Tension ◽  
Ionic Liquids ◽  
Aqueous Solutions ◽  
Speed Of Sound ◽  
Surface Tension Data ◽  
Equilibrium Studies ◽  
Sound Density

The Density and Surface Tension of Aqueous Solutions of Propionate Ionic Liquids: [C4mim][Pro] and [C6mim][Pro] at Different Temperatures

2016 ◽  
Vol 45 (2) ◽  
pp. 188-199 ◽  
Author(s):  
Jing Tong ◽  
Teng-Fei Chen ◽  
Lin-Fu Wang ◽  
Duo Zhang ◽  
Qi Yang ◽  
...  
Keyword(s):  
Surface Tension ◽  
Ionic Liquids ◽  
Aqueous Solutions ◽  
Different Temperatures

Molecular dynamics simulations of aqueous solutions of ionic liquids

2010 ◽  
Vol 75 (3) ◽  
pp. 333-348
Author(s):  
Karel Matas ◽  
Jiří Kolafa
Keyword(s):  
Molecular Dynamics ◽  
Surface Tension ◽  
Ionic Liquids ◽  
Aqueous Solutions ◽  
Structural Changes ◽  
Positive Charge ◽  
Anomalous Increase ◽  
Alkyl Chains ◽  
Cation Layer ◽  
Dynamics Simulations

We performed a molecular dynamics study of aqueous solutions of ionic liquids 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) and 1-octyl-3-methylimidazolium chloride ([OMIM]Cl) in order to elucidate the anomalous dependence of the surface tension on concentration. We found that cations are placed preferably at the surface with alkyl chains pointing towards vacuum. Anions compensate the surplus of a positive charge on the surface by forming a layer below the cation layer. At lower concentrations the surface tension decreases with concentration. At higher concentrations the surface becomes saturated by cations and the decrease slows down. The decrease of surface tension with concentration is a consequence of the structural changes, although the experimentally observed anomalous increase at even higher concentrations was not reproduced.

Probing the self-aggregation of ionic liquids in aqueous solutions using density and speed of sound data

2013 ◽  
Vol 59 ◽  
pp. 43-48 ◽  
Author(s):  
M. Tariq ◽  
F. Moscoso ◽  
F.J. Deive ◽  
A. Rodriguez ◽  
M.A. Sanromán ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Aqueous Solutions ◽  
Speed Of Sound ◽  
The Self ◽  
Self Aggregation ◽  
Sound Data
Sign in / Sign up

Export Citation Format

Share Document