Selective Removal of Nitrosamines from a Model Amine Carbon-Capture Waterwash Using Low-Cost Activated-Carbon Sorbents

2017 ◽  
Vol 51 (18) ◽  
pp. 10913-10922 ◽  
Author(s):  
Leland R. Widger ◽  
Megan Combs ◽  
Amit R. Lohe ◽  
Cameron A. Lippert ◽  
Jesse G. Thompson ◽  
...  
2021 ◽  
Vol 17 (3) ◽  
pp. 87-95
Author(s):  
Ilkhom Tagaev ◽  
Manzura Muratova ◽  
Lyudmila Andriyko ◽  
Mohigul Yusuf Kizi Boykhonova

Introduction. Bentonite clays are traditional inexpensive and effective adsorbents that have a high potential for removing heavy metals from wastewater due to their abundance, chemical and mechanical stability, high exchange ability, and unique structural properties.Problem Statement. To obtain activated carbon, high-temperature muffle furnaces are used with the consumption of a large amount of electricity, which is economically unprofitable. In addition, the resulting sorbents must be in the form of granules or tablets, have high strength and the ability to be repeatedly used in technological processes.Purpose. Development of a method for the production of low-cost granular sorbents based on bentonite as amineral component, activated carbon, as well as natural production waste (sunflower husk, straw, sawdust, etc. as modifiers), which can be removed from the activation process to increase porosity of these materials.Materials and Methods. Angren brown coal; bentonite of the Navbakhor deposit was used as a sorbent and a basic substance for the granules formation; modifiers were sodium chloride, potassium, chopped straw, sawdust. Methods of thermal decarbonization and activation of the obtained granules under the optimal conditions (950 °С, 45 min) were applied; the bulk density, the specific surface area, pore types and their total volume was determined by optical microscopy and nitrogen adsorption methods.Results. Inexpensive hybrid bentonite-carbon sorbents in the form of high-strength granules were synthesized.The optimal ratio of the main components is Bentonite:Coal = 1 : 2, size (2.5 mm) and strength of granules (83—99%), total pore volume 0.863—1.01 cm3/g, confirmed the presence of macro-, meso- and micropores. The most promising sample has a specific surface area (Langmuir) 184 m2/g.Conclusions. The method for obtaining new effective granular carbon sorbents of low cost, having high sorption capacity relative to organic and inorganic pollutants for purification of industrial process waters has been proposed.


Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 122
Author(s):  
Renwei Lu ◽  
Xiaolong Ren ◽  
Chong Wang ◽  
Changzhen Zhan ◽  
Ding Nan ◽  
...  

Lithium-ion hybrid capacitors (LICs) are regarded as one of the most promising next generation energy storage devices. Commercial activated carbon materials with low cost and excellent cycling stability are widely used as cathode materials for LICs, however, their low energy density remains a significant challenge for the practical applications of LICs. Herein, Na0.76V6O15 nanobelts (NaVO) were prepared and combined with commercial activated carbon YP50D to form hybrid cathode materials. Credit to the synergism of its capacitive effect and diffusion-controlled faradaic effect, NaVO/C hybrid cathode displays both superior cyclability and enhanced capacity. LICs were assembled with the as-prepared NaVO/C hybrid cathode and artificial graphite anode which was pre-lithiated. Furthermore, 10-NaVO/C//AG LIC delivers a high energy density of 118.9 Wh kg−1 at a power density of 220.6 W kg−1 and retains 43.7 Wh kg−1 even at a high power density of 21,793.0 W kg−1. The LIC can also maintain long-term cycling stability with capacitance retention of approximately 70% after 5000 cycles at 1 A g−1. Accordingly, hybrid cathodes composed of commercial activated carbon and a small amount of high energy battery-type materials are expected to be a candidate for low-cost advanced LICs with both high energy density and power density.


Fermentation ◽  
2021 ◽  
Vol 7 (3) ◽  
pp. 119
Author(s):  
Vasiliki Summerson ◽  
Claudia Gonzalez Viejo ◽  
Damir D. Torrico ◽  
Alexis Pang ◽  
Sigfredo Fuentes

The incidence and intensity of bushfires is increasing due to climate change, resulting in a greater risk of smoke taint development in wine. In this study, smoke-tainted and non-smoke-tainted wines were subjected to treatments using activated carbon with/without the addition of a cleaving enzyme treatment to hydrolyze glycoconjugates. Chemical measurements and volatile aroma compounds were assessed for each treatment, with the two smoke taint amelioration treatments exhibiting lower mean values for volatile aroma compounds exhibiting positive ‘fruit’ aromas. Furthermore, a low-cost electronic nose (e-nose) was used to assess the wines. A machine learning model based on artificial neural networks (ANN) was developed using the e-nose outputs from the unsmoked control wine, unsmoked wine with activated carbon treatment, unsmoked wine with a cleaving enzyme plus activated carbon treatment, and smoke-tainted control wine samples as inputs to classify the wines according to the smoke taint amelioration treatment. The model displayed a high overall accuracy of 98% in classifying the e-nose readings, illustrating it may be a rapid, cost-effective tool for winemakers to assess the effectiveness of smoke taint amelioration treatment by activated carbon with/without the use of a cleaving enzyme. Furthermore, the use of a cleaving enzyme coupled with activated carbon was found to be effective in ameliorating smoke taint in wine and may help delay the resurgence of smoke aromas in wine following the aging and hydrolysis of glycoconjugates.


2015 ◽  
Vol 659 ◽  
pp. 304-309
Author(s):  
Khemmakorn Gomonsirisuk ◽  
Thanakorn Wasanapiarnpong

Organic contaminated wastes water from petrochemical industries can be removed by adsorbent and photocatalyst. In this work, the degradation rate of phenol have been studied at different ratios of activated carbon/NaA zeolite composite materials coated with TiO2 photocatalyst which are easily to be fabricated into tubular shape by extrusion method. In addition, the foam-inserted composite can be floated on the surface of waste water for the higher phocatalyst activity. While the composite is the low cost adsorbent with high absorption and high ion exchange properties. In order to optimize the efficiency of material, the various ratios of activated carbon/NaA zeolite (3:1, 1:1 and 1:3) and amount of coated TiO2 on the specimen’s surface was studied by UV/Vis spectrophotometer which related to phenol concentration. Moreover the various amount of phenolic resins (10, 20, 30, 40 and 50 wt%) at different reduction firing temperatures (600 and 650 °C) with soaking time of 1, 2 and 3 hours affected to the compressive strength of samples. For the characterization, XRD is used to characterize the phase and SEM is used to provide the morphology of the prepared composite materials.


2021 ◽  
Author(s):  
Emmanuel Ayodele ◽  
Victoria Ezeagwula ◽  
Precious Igbokwubiri

Abstract Bamboo trees are one of the fastest growing trees in tropical rainforests around the world, they have various uses ranging from construction to fly ash generation used in oil and gas cementing, to development of activated carbon which is one of the latest uses of bamboo trees. This paper focuses on development of activated carbon from bamboo trees for carbon capture and sequestration. The need for improved air quality becomes imperative as the SDG Goal 12 and SDG Goal13 implies. One of the major greenhouse gases is CO2 which accounts for over 80% of greenhouse gases in the environment. Eliminating the greenhouse gases without adding another pollutant to the environment is highly sought after in the 21st century. Bamboo trees are mostly seen as agricultural waste with the advent of scaffolding and other support systems being in the construction industry. Instead of burning bamboo trees or using them for cooking in the local communities which in turn generates CO2 and fly ash, an alternative was considered in this research work, which is the usage of bamboo trees to generate activated, moderately porous and high surface area carbon for extracting CO2 from various CO2 discharge sources atmosphere and for water purification. This paper focuses on the quality testing of activated carbon that can effectively absorb CO2. The porosity, pore volume, bulk volume, and BET surface area were measured. The porosity of the activated carbon is 27%, BET surface area as 1260m²/g. Fixed carbon was 11.7%, Volatility 73%, ash content 1.7%.


2014 ◽  
Vol 9 (1) ◽  
pp. 166-174 ◽  
Author(s):  
Rajeshwar M. Shrestha ◽  
Margit Varga ◽  
Imre Varga ◽  
Amar P. Yadav ◽  
Bhadra P. Pokharel ◽  
...  

Activated carbons were prepared from Lapsi seed stone by the treatment with H2SO4 and HNO3 for the removal of Ni (II) ions from aqueous solution. Two activated carbon have been prepared from Lapsi seed stones by treating with conc.H2SO4 and a mixture of H2SO4 and HNO3 in the ratio of 1:1 by weight for removal of Ni(II) ions. Chemical characterization of the resultant activated carbons was studied by Fourier Transform Infrared Spectroscopy and Boehm titration which revealed the presence of oxygen containing surface functional groups like carboxyl, lactones and phenols in the carbons. The optimum pH for nickel adsorption is found to be 5. The adsorption data were better fitted with the Langmuir equations than Freundlich adsorption equation to describe the equilibrium isotherms. The maximum adsorption capacity of Ni (II) on the resultant activated carbons was 28.25.8 mg g-1 with H2SO4 and 69.49 mg g-1 with a mixture of H2SO4 and HNO3. The waste material used in the preparation of the activated carbons is inexpensive and readily available. Hence the carbons prepared from Lapsi seed stones can act as potential low cost adsorbents for the removal of Ni (II) from water. DOI: http://dx.doi.org/10.3126/jie.v9i1.10680Journal of the Institute of Engineering, Vol. 9, No. 1, pp. 166–174


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