Modifications to EPA Method 3060A to Improve Extraction of Cr(VI) from Chromium Ore Processing Residue-Contaminated Soils

2017 ◽  
Vol 51 (19) ◽  
pp. 11235-11243 ◽  
Author(s):  
Christopher T. Mills ◽  
Carleton R. Bern ◽  
Ruth E. Wolf ◽  
Andrea L. Foster ◽  
Jean M. Morrison ◽  
...  
2018 ◽  
Vol 30 (3) ◽  
pp. 620-624 ◽  
Author(s):  
Vanitha Murugaiyan ◽  
T. Sehar ◽  
S. Selvaraj ◽  
P. Kamatchi Selvaraj

2018 ◽  
Vol 13 (4) ◽  
pp. 98-107
Author(s):  
Wiwat Kamolpornwijit ◽  
Jay N Meegoda ◽  
Janitha H Batagoda

2010 ◽  
Vol 33 (4) ◽  
pp. 102836 ◽  
Author(s):  
L. D. Suits ◽  
T. C. Sheahan ◽  
Andrew M. Millspaugh ◽  
James M. Tinjum ◽  
Timothy A. Boecher

1991 ◽  
Vol 7 (3) ◽  
pp. 159-196 ◽  
Author(s):  
Dennis J. Paustenbach ◽  
Deborah M. Meyer ◽  
Patrick J. Sheehan ◽  
Virginia Lau

Paustenbach, Dennis J., Deborah M. Meyer, Patrick J. Shee han, and Virginia Lau (1991). An assessment and quantitative uncertainty analysis of the health risks to workers exposed to chromium contaminated soils. Toxicol. Industrial Health. Millions of tons of chromite-ore processing residue have been used as fill in various locations in Northern New Jersey and else where in the United States. The primary toxicants in the residue are trivalent chromium [ Cr(III)] and hexavalent chromium [ Cr(VI)]. The hazard posed by Cr(III) is negligible due to its low acute and chronic toxicity. In contrast, Cr(VI) is considered a inhalation human carcinogen at high concentrations. Approxi mately 40 commercial and industrial properties in Northern New Jersey have been identified as containing chromite ore processing residue in the soil. One site, a partially-paved trucking terminal, was evaluated in this assessment. The arithmetic mean and geo metric mean concentrations of total chromium in soil were 977 and 359 mg/kg, respectively. The data were log-normal distrib uted. The arithmetic mean and geometric mean concentrations of Cr(VI) in surface soil were 37.6 and 3.1 mg/kg, respectively. The data could not be fit to a standard distribution, likely due to the large number of samples with concentrations below the method detection limit (65%). Dose was calculated for each exposure route using a Monte Carlo statistical simulation.


2013 ◽  
Vol 24 (3) ◽  
pp. 7-11 ◽  
Author(s):  
Leszek Gersztyn ◽  
Anna Karczewska ◽  
Bernard Gałka

Abstract The aim of this study was to determine the impact of pH on arsenic solubility in soils heavily contaminated by the former arsenic industry. For the purpose of the study, three soil samples were collected from the area affected by ore processing in Złoty Stok. Soils differed in initial pH, calcium carbonate content, organic matter content and total arsenic concentration. The amounts of arsenic released from soils at various pH were measured using extraction tests, where soil samples were shaken with various doses of HCl and NaOH in the presence of 0.01 mol • dm−3 CaCl2 as the background solution. Arsenic solubility in soils was considerably low at neutral or slightly acidic pH and increased considerably in both strongly acidic and alkaline conditions. The importance of these effects for environmental risk was discussed.


2019 ◽  
Vol 2019 ◽  
pp. 1-10
Author(s):  
Yu Liu ◽  
Yin Li ◽  
Yucheng Hu ◽  
Khan M. G. Mostofa ◽  
Siliang Li ◽  
...  

This study explored the stratigraphic distribution and soil/shallow aquifer characteristics surrounding a chromium ore processing residue (COPR) dumpsite at a former chemical factory in China. Total Cr levels in top soils (5–10 cm) nearby the COPR dumpsite were in the range of 8571.4–10711.4 mg/kg. Shallow aquifers (1–6 m) nearby the COPR dumpsite showed a maximum total Cr level of 9756.7 mg/kg. The concentrations of Cr(VI) in groundwater nearby the COPR dumpsite were 766.9–1347.5 mg/L. These results display that the top soils, shallow aquifers, and groundwater of the study site are severely polluted by Cr(VI). Then, three aquifers (silt, clay, and silty clay), respectively, collected from the depth of 1.4–2.4 m, 2.4–4.8 m, and 4.8–11.00 m were first used to evaluate the adsorption characteristics and transport behavior of Cr(VI) in shallow aquifers by both batch and column experiments. The adsorption of Cr(VI) on tested aquifers was well described by pseudo-second-order equation and Freundlich model. The adsorption capacities of Cr(VI) on three aquifers followed the order: clay > silty clay > silt. The kinetics proved that Cr(VI) is not easily adsorbed by the aquifer mediums but transports with groundwater. Thermodynamics indicated that Cr(VI) adsorption on tested aquifers was feasible, spontaneous, and endothermic. Cr(VI) adsorption on tested aquifers decreased with increasing pH. Furthermore, the transport of Cr(VI) in adsorption columns followed the sequence of clay < silty clay < silt. Desorption column experiments infer that the Cr(VI) adsorbed on aquifers will desorb and release into groundwater in the case of rainwater leaching. Therefore, a proper treatment of the COPR and a comprehensive management of soils are vital to prevent groundwater pollution.


Author(s):  
Jay N. Meegoda ◽  
Wiwat Kamolpornwijit ◽  
Zhengbo Hu ◽  
Robert Mueller ◽  
Ravi Patraju

2011 ◽  
Author(s):  
Wiwat Kamolpornwijit ◽  
Jay N. Meegoda

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