Plant Assimilation Kinetics and Metabolism of 2-Mercaptobenzothiazole Tire Rubber Vulcanizers by Arabidopsis

2016 ◽  
Vol 50 (13) ◽  
pp. 6762-6771 ◽  
Author(s):  
Gregory H. LeFevre ◽  
Andrea C. Portmann ◽  
Claudia E. Müller ◽  
Elizabeth S. Sattely ◽  
Richard G. Luthy
2019 ◽  
Vol 91 (8) ◽  
pp. 5200-5206 ◽  
Author(s):  
Stefan Trautner ◽  
Johannes Lackner ◽  
Wolfgang Spendelhofer ◽  
Norbert Huber ◽  
Johannes D. Pedarnig

Materials ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 225
Author(s):  
Andrea Petrella ◽  
Michele Notarnicola

Lightweight cement mortars containing end-of-life tire rubber (TR) as aggregate were prepared and characterized by rheological, thermal, mechanical, microstructural, and wetting tests. The mixtures were obtained after total replacement of the conventional sand aggregate with untreated TR with different grain sizes (0–2 mm and 2–4 mm) and distributions (25%, 32%, and 40% by weight). The mortars showed lower thermal conductivities (≈90%) with respect to the sand reference due to the differences in the conductivities of the two phases associated with the low density of the aggregates and, to a minor extent, to the lack of adhesion of tire to the cement paste (evidenced by microstructural detection). In this respect, a decrease of the thermal conductivities was observed with the increase of the TR weight percentage together with a decrease of fluidity of the fresh mixture and a decrease of the mechanical strengths. The addition of expanded perlite (P, 0–1 mm grain size) to the mixture allowed us to obtain mortars with an improvement of the mechanical strengths and negligible modification of the thermal properties. Moreover, in this case, a decrease of the thermal conductivities was observed with the increase of the P/TR dosage together with a decrease of fluidity and of the mechanical strengths. TR mortars showed discrete cracks after failure without separation of the two parts of the specimens, and similar results were observed in the case of the perlite/TR samples thanks to the rubber particles bridging the crack faces. The super-elastic properties of the specimens were also observed in the impact compression tests in which the best performances of the tire and P/TR composites were evidenced by a deep groove before complete failure. Moreover, these mortars showed very low water penetration through the surface and also through the bulk of the samples thanks to the hydrophobic nature of the end-of-life aggregate, which makes these environmentally sustainable materials suitable for indoor and outdoor elements.


Author(s):  
Sajjad Noura ◽  
Abdulnaser M. Al-Sabaeei ◽  
Gailan Ismat Safaeldeen ◽  
Ratnasamy Muniandy ◽  
Alan Carter

2021 ◽  
pp. 117462
Author(s):  
Victor Carrasco-Navarro ◽  
Ana-Belén Muñiz González ◽  
Jouni Sorvari ◽  
Jose-Luis Martínez Guitarte

Author(s):  
Shaosen Ma ◽  
Guangping Huang ◽  
Khaled Obaia ◽  
Soon Won Moon ◽  
Wei Victor Liu

The objective of this study is to investigate the hysteresis loss of ultra-large off-the-road (OTR) tire rubber compounds based on typical operating conditions at mine sites. Cyclic tensile tests were conducted on tread and sidewall compounds at six strain levels ranging from 10% to 100%, eight strain rates from 10% to 500% s−1 and 14 rubber temperatures from −30°C to 100°C. The test results showed that a large strain level (e.g. 100%) increased the hysteresis loss of tire rubber compounds considerably. Hysteresis loss of tire rubber compounds increased with a rise of strain rates, and the increasing rates became greater at large strain levels (e.g. 100%). Moreover, a rise of rubber temperatures caused a decrease in hysteresis loss; however, the decrease became less significant when the rubber temperatures were above 10°C. Compared with tread compounds, sidewall compounds showed greater hysteresis loss values and more rapid increases in hysteresis loss with the rising strain rate.


Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1139
Author(s):  
Hans van Hoek ◽  
Jacques Noordermeer ◽  
Geert Heideman ◽  
Anke Blume ◽  
Wilma Dierkes

De-vulcanization of rubber has been shown to be a viable process to reuse this valuable material. The purpose of the de-vulcanization is to release the crosslinked nature of the highly elastic tire rubber granulate. For present day passenger car tires containing the synthetic rubbers Styrene-Butadiene Rubber (SBR) and Butadiene Rubber (BR) and a high amount of silica as reinforcing filler, producing high quality devulcanizate is a major challenge. In previous research a thermo-chemical mechanical approach was developed, using a twin-screw extruder and diphenyldisulfide (DPDS) as de-vulcanization agent.The screw configuration was designed for low shear in order to protect the polymers from chain scission, or uncontrolled spontaneuous recombination which is the largest problem involved in de-vulcanization of passenger car tire rubber. Because of disadvantages of DPDS for commercial use, 2-2′-dibenzamidodiphenyldisulfide (DBD) was used in the present study. Due to its high melting point of 140 °C the twin-screw extruder process needed to be redesigned. Subsequent milling of the devulcanizate at 60 °C with a narrow gap-width between the mill rolls greatly improved the quality of the devulcanizate in terms of coherence and tensile properties after renewed vulcanization. As the composition of passenger car tire granulate is very complex, the usefulness of the Horikx-Verbruggen analysis as optimization parameter for the de-vulcanization process was limited. Instead, stress-strain properties of re-vulcanized de-vulcanizates were used. The capacity of the twin-screw extruder was limited by the required residence time, implying a low screw speed. A best tensile strength of 8 MPa at a strain at break of 160% of the unblended renewed vulcanizate was found under optimal conditions.


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