Standard Protocol and Quality Assessment of Soil Phosphorus Speciation by P K-Edge XANES Spectroscopy

2015 ◽  
Vol 49 (17) ◽  
pp. 10521-10528 ◽  
Author(s):  
Florian Werner ◽  
Jörg Prietzel
2007 ◽  
Vol 36 (6) ◽  
pp. 1856-1863 ◽  
Author(s):  
Kerem Güngör ◽  
Astrid Jürgensen ◽  
K. G. Karthikeyan

Geoderma ◽  
2013 ◽  
Vol 195-196 ◽  
pp. 251-259 ◽  
Author(s):  
Jun Zhou ◽  
Yanhong Wu ◽  
Jörg Prietzel ◽  
Haijian Bing ◽  
Dong Yu ◽  
...  

Soil Systems ◽  
2019 ◽  
Vol 3 (3) ◽  
pp. 61 ◽  
Author(s):  
Carlos ◽  
Francisco ◽  
Wedisson ◽  
Leonardus ◽  
Jörg ◽  
...  

Bulk soil phosphorus speciation by X-ray absorption spectroscopy (XAS) using fluorescence yield-mode measurements is an important tool for phosphorus research because of the low soil P contents. However, when measuring in fluorescence mode, increasing the concentration of the absorbing atom can dampen the XAS spectral features because of self-absorption and affect the linear combination (LC) fitting results. To reduce the self-absorption for samples of high P contents, thick boron nitride diluted samples are produced, yet the effects of self-absorption on P speciation results via LC fitting of P K-edge XANES spectroscopy, and the possible benefits of data processing optimization are unknown. Toward this end, we produced a series of ternary standard mixtures (calcium-iron-aluminum phosphates) and an example soil sample both diluted using boron nitride over a range from 1 to ~900 mmol kg−1 for the soil sample and up to ~6000 mmol kg−1 for the standard mixture. We show that by optimizing background subtraction and normalization values, consistent results with less than 10% error can be obtained for samples with up to 300 mmol kg−1 P. Our results highlight the applicability of optimized P K-edge XANES fitting across a wide range of concentrations encountered in natural environments.


2019 ◽  
Vol 195 ◽  
pp. 104389 ◽  
Author(s):  
Fayong Li ◽  
Xinqiang Liang ◽  
Huifang Zhang ◽  
Guangming Tian

2017 ◽  
Vol 46 (6) ◽  
pp. 1190-1197 ◽  
Author(s):  
Dean Hesterberg ◽  
Ian McNulty ◽  
Juergen Thieme

2020 ◽  
Vol 183 (3) ◽  
pp. 367-381
Author(s):  
Frank Schmieder ◽  
Jon Petter Gustafsson ◽  
Wantana Klysubun ◽  
Franz Zehetner ◽  
Matthew Riddle ◽  
...  

2005 ◽  
Vol 39 (19) ◽  
pp. 7485-7491 ◽  
Author(s):  
Shinjiro Sato ◽  
Dawit Solomon ◽  
Charles Hyland ◽  
Quirine M. Ketterings ◽  
Johannes Lehmann

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