scholarly journals Effects of Metal Ions on Aqueous-Phase Decomposition of α-Hydroxyalkyl-Hydroperoxides Derived from Terpene Alcohols

2021 ◽  
Author(s):  
Mingxi Hu ◽  
Kenichi Tonokura ◽  
Yu Morino ◽  
Kei Sato ◽  
Shinichi Enami
Keyword(s):  
Metal Ions ◽  
Aqueous Phase ◽  
Phase Decomposition ◽  
Terpene Alcohols

scholarly journals The role of transition metal ions on HO<sub>x</sub> radicals in clouds: a numerical evaluation of its impact on multiphase chemistry

2004 ◽  
Vol 4 (1) ◽  
pp. 95-110 ◽  
Author(s):  
L. Deguillaume ◽  
M. Leriche ◽  
A. Monod ◽  
N. Chaumerliac
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Aqueous Phase ◽  
Numerical Evaluation ◽  
Transition Metal Ions ◽  
Cloud Chemistry ◽  
Sensitivity Tests ◽  
Fe Speciation ◽  
Deposition Processes

Abstract. A new modelling study of the role of transition metal ions on cloud chemistry has been performed. Developments of the Model of Multiphase Cloud Chemistry (M2C2; Leriche et al., 2001) are described, including the transition metal ions reactivity emission/deposition processes and variable photolysis in the aqueous phase. The model is then applied to three summertime scenarios under urban, remote and marine conditions, described by Ervens et al. (2003). Chemical regimes in clouds are analyzed to understand the role of transition metal ions on cloud chemistry and especially, on HxOy chemistry, which consequently influences the sulphur and the VOCs chemistry in droplets. The ratio of Fe(II)/Fe(III) exhibits a diurnal variation with values in agreement with the available measurements of Fe speciation. In the urban case, sensitivity tests with and without TMI chemistry, show an enhancement of OH concentration in the aqueous phase when TMI chemistry is considered.

scholarly journals Temperature Dependence of Aqueous-Phase Decomposition of α-Hydroxyalkyl-Hydroperoxides

2020 ◽  
Vol 124 (49) ◽  
pp. 10288-10295
Author(s):  
Mingxi Hu ◽  
Kunpeng Chen ◽  
Junting Qiu ◽  
Ying-Hsuan Lin ◽  
Kenichi Tonokura ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Aqueous Phase ◽  
Phase Decomposition

Stability and isomerization of complexes formed by metal ions and cytosine isomers in aqueous phase

2013 ◽  
Vol 19 (8) ◽  
pp. 3447-3461
Author(s):  
Hongqi Ai ◽  
Jingjing Liu ◽  
Kwaichow Chan
Keyword(s):  
Metal Ions ◽  
Aqueous Phase

Biosorption of toxic chromium from aqueous phase by lignin: mechanism, effect of other metal ions and salts

2011 ◽  
Vol 169 (1-3) ◽  
pp. 20-30 ◽  
Author(s):  
Ahmad B. Albadarin ◽  
Ala’a H. Al-Muhtaseb ◽  
Nasir A. Al-laqtah ◽  
Gavin M. Walker ◽  
Stephen J. Allen ◽  
...  
Keyword(s):  
Metal Ions ◽  
Aqueous Phase

Selective Extraction of Metal Ions from Aqueous Phase to Ionic Liquids: A Novel Thermodynamic Approach to Separations

ChemPhysChem ◽  
2014 ◽  
Vol 15 (16) ◽  
pp. 3536-3543 ◽  
Author(s):  
Camiel H. C. Janssen ◽  
Antonio Sánchez ◽  
Mark N. Kobrak
Keyword(s):  
Ionic Liquids ◽  
Metal Ions ◽  
Aqueous Phase ◽  
Selective Extraction ◽  
Thermodynamic Approach
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