Multiphase Photochemistry of Iron-Chloride Containing Particles as a Source of Aqueous Chlorine Radicals and Its Effect on Sulfate Production

2020 ◽  
Vol 54 (16) ◽  
pp. 9862-9871
Author(s):  
Masao Gen ◽  
Ruifeng Zhang ◽  
Yongjie Li ◽  
Chak K. Chan
Keyword(s):  
Iron Chloride ◽  
Sulfate Production ◽  
Chlorine Radicals

Removal of Residual Nutrients and Chemical Additives From Secondary Sewage by Reverse osmosis

1975 ◽  
Vol 10 (1) ◽  
pp. 101-109
Author(s):  
H. Kirk Johnston ◽  
H.S. Lim
Keyword(s):  
Reverse Osmosis ◽  
Membrane Fouling ◽  
Pilot Plant ◽  
Waste Treatment ◽  
Iron Chloride ◽  
Treatment Technique ◽  
Chemical Additives ◽  
Cellulose Acetate Membranes ◽  
Municipal Wastewaters ◽  
Nutrient Solutions

Abstract The suitability of reverse osmosis as a renovation technique for the treatment of municipal wastewaters has been assessed. Cellulose acetate membranes capable of 70% and 90% NaCl rejections were employed in both laboratory and pilot plant studies to evaluate the efficiency of this technique in removing the residual precipitant chemicals generally employed in phosphorus removal programs (iron chloride, alum, and lime) and the nutrients (phosphates, nitrates and ammonia) characteristic of municipal wastewaters. Secondary sewage and raw sewage as well as prepared nutrient solutions were employed in the course of this program. Both laboratory and pilot plant studies indicated consistently outstanding removal efficiencies for the species examined, almost independent of the nature of the waste solutions being treated. Permeation of the purified effluent was subject to significant reductions due to membrane fouling. This characteristic was most pronounced for the more permeable (less selective) membranes. Routine chemical and physical cleanings enable satisfactory flux levels to be maintained, thereby suggesting that reverse osmosis may become a viable municipal waste treatment technique.

Phyto-Facilitated Bimetallic ZnFe2O4 Nanoparticles via Boswellia carteri: Synthesis, Characterization and Anti-Cancer Activity.

2020 ◽  
Vol 21 ◽  
Author(s):  
Amer Imraish ◽  
Afnan Al-Hunaiti ◽  
Tuqa Abu-Thiab ◽  
Abed Al-Qader Ibrahim ◽  
Eman Hwaitat ◽  
...  
Keyword(s):  
Anticancer Activity ◽  
Cell Lines ◽  
Metallic Nanoparticles ◽  
Bimetallic Nanoparticles ◽  
Iron Chloride ◽  
Nano Particles ◽  
Adverse Side Effect ◽  
Wide Range ◽  
Anti Cancer ◽  
Znfe2o4 Nanoparticles

Background: The growing unsatisfaction toward the available traditional chemotherapeutic agents enhanced the need to develop new methods for obtaining materials with more effective and safe anti-cancer properties. Over the past few years, usage of metallic nanoparticles has been a target for researchers of different scientific and commercial fields due to their tiny sizes, environment friendly properties and wide range applications. To overcome the obstacles of traditional physical and chemical methods for synthesis of such nanoparticles, a new less expensive and eco-friendly method has been adopted using natural existing organisms as a reducing agent to mediate synthesis of the desired metallic nanoparticles from their precursors, a process called green biosynthesis of nanoparticles. Objective: Here in the present study, zinc iron bimetallic nanoparticles (ZnFe2O4) were synthesized via an aqueous extract of Boswellia Carteri resin mixed with zinc acetate and iron chloride precursors, and they were tested for their anticancer activity. Methods: Various analytic methods were applied for the characterization of the Phyto synthesized ZnFe2O4 and they were tested for their anticancer activity against MDA-MB-231, K562, MCF-7 cancer cell lines and normal fibroblasts. Results: Our results demonstrate the synthesis of cubic structured bimetallic nanoparticles ZnFe2O4 with an average diameter 10.54 nm. MTT cytotoxicity assay demonstrate that our phyto-synthesized ZnFe2O4 nanoparticles exhibited a selective and potent anticancer activity against K562 and MDA-MB-231 cell lines with IC50 values 4.53 µM and 4.19 µM, respectively. Conclusion: In conclusion, our bio synthesized ZnFe2O4 nano particles show a promising environmentally friendly of low coast chemotherapeutic approach against selective cancers with a predicted low adverse side effect toward normal cells. Further in vivo advanced animal research should be done to execute their applicability in living organisms.

scholarly journals A Novel Iron Chloride Red-Ox Concentration Flow Cell Battery (ICFB) Concept; Power and Electrode Optimization

Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 1109
Author(s):  
Robert Bock ◽  
Björn Kleinsteinberg ◽  
Bjørn Selnes-Volseth ◽  
Odne Stokke Burheim
Keyword(s):  
Energy Storage ◽  
Large Scale ◽  
Fossil Fuels ◽  
Flow Cell ◽  
Iron Chloride ◽  
Carbon Electrodes ◽  
Concentration Difference ◽  
Term Energy ◽  
Short And Long Term

For renewable energies to succeed in replacing fossil fuels, large-scale and affordable solutions are needed for short and long-term energy storage. A potentially inexpensive approach of storing large amounts of energy is through the use of a concentration flow cell that is based on cheap and abundant materials. Here, we propose to use aqueous iron chloride as a reacting solvent on carbon electrodes. We suggest to use it in a red-ox concentration flow cell with two compartments separated by a hydrocarbon-based membrane. In both compartments the red-ox couple of iron II and III reacts, oxidation at the anode and reduction at the cathode. When charging, a concentration difference between the two species grows. When discharging, this concentration difference between iron II and iron III is used to drive the reaction. In this respect it is a concentration driven flow cell redox battery using iron chloride in both solutions. Here, we investigate material combinations, power, and concentration relations.

scholarly journals Suicide by intoxication with iron (III) chloride

2021 ◽  
Author(s):  
Sławomir Majdanik ◽  
Barbara Potocka-Banaś ◽  
Sebastian Glowinski ◽  
Krzysztof Borowiak
Keyword(s):  
Prussian Blue ◽  
Chloride Ions ◽  
Iron Chloride ◽  
Histopathological Analysis ◽  
Fatal Intoxication ◽  
Internal Organs ◽  
Specific Staining ◽  
Iron Supplements ◽  
Staining Protocol ◽  
Hematoxylin And Eosin

Abstract Purpose Cases of iron intoxication are not very often encountered in toxicology practice, and most of those reported concern accidental intoxications with iron supplements in young children. The paper presents a rare case of a suicide by intoxication in an adult woman who ingested a solution of iron (III) chloride. Methods A forensic was at the Department of Forensic Medicine, PMU in Szczecin. Toxicology tests of blood sampled from the deceased were performed using a 644 CIBA CORNING ion selective analyzer and proprietary reagent kits. Histopathological was with the use of the standard staining protocol (hematoxylin and eosin) and staining specific for iron (Prussian blue). Results Autopsy revealed a distinct yellow discolouration and thrombotic necrosis of the oral mucosa and almost the whole gastrointestinal tract, as well as similar changes in the adjacent internal organs. Considerably high levels of iron and chloride ions were detected in specimens of internal organs preserved during autopsy. Histopathological analysis performed with the use of staining specific for iron (Prussian blue) also confirmed the presence of iron in the examined tissues, especially in the intestines and liver. Conclusions Considering the above findings, it was concluded in the forensic report that the death of the woman was caused by the ingestion of iron chloride. The reported case of fatal intoxication is one of the few described in the literature, and its course implies that in the case of initially diagnosed intoxication with corrosive compounds, the possibility of using metal-containing poison should also be considered in the differential diagnosis. In addition to routine toxicological tests performed in fatal cases we also draw attention to the possibility of using specific staining protocols for microscopic specimens.

Statistical studies of adsorption isotherms of iron nitrate and iron chloride on a thin layer of porphyrin

2017 ◽  
Vol 248 ◽  
pp. 235-245 ◽  
Author(s):  
Mohamed Ben Yahia ◽  
Salah Knani ◽  
Layla Ben Haj Hsan ◽  
Manel Ben Yahia ◽  
Hbib Nasri ◽  
...  
Keyword(s):  
Thin Layer ◽  
Adsorption Isotherms ◽  
Iron Chloride ◽  
Iron Nitrate ◽  
Statistical Studies

scholarly journals The Relative Importance of Scavenging, Oxidation, and Ice-Phase Processes in the Production and Wet Deposition of Sulfate

2005 ◽  
Vol 62 (7) ◽  
pp. 2118-2135 ◽  
Author(s):  
Vlado Spiridonov ◽  
Mladjen Curic
Keyword(s):  
Wet Deposition ◽  
Lower Percentage ◽  
Relative Importance ◽  
Total Sulfur ◽  
Sulfate Production ◽  
Relative Contribution ◽  
Cloud Resolving Model ◽  
Cloud Scavenging ◽  
Nucleation Scavenging ◽  
Ice Phase

Abstract The relative importance of various processes to sulfate production and wet deposition is examined by using a cloud-resolving model coupled with a sulfate chemistry submodel. Results using different versions of the model are then compared and principal differences with respect to their dynamics, microphysics, and chemistry are carefully discussed. The results imply that the dominant microphysical and chemical conversions of sulfate in the 3D run are nucleation, scavenging, and oxidation. Due to the lower cloud water and rainwater pH, oxidation does not contribute as significantly to the sulfate mass in the 2D run as the 3D. Sensitivity tests have revealed that in-cloud scavenging in the 2D run for continental nonpolluted and continental polluted clouds accounted for 29.4% and 31.5% of the total sulfur deposited, respectively. The 3D run shows a lower percentage contribution to sulfur deposition for about 28.2% and 29.6%. In addition, subcloud scavenging for the 2D run contributed about 32.7% and 38.2%. In-cloud oxidation in the 2D run accounted for about 24.5% to 30.4% of the total sulfur mass deposited. Subcloud oxidation contributed from 21.0% to 20.6% of the total sulfur mass removed by wet deposition. In-cloud oxidation for the 3D run shows slightly lower percentage values when compared to those from the 2D run. The relative contribution of subcloud oxidation for continental nonpolluted and polluted clouds exceeds those values in the 2D run by approximately 7% and 10%, respectively. Ignoring the ice phase and considering those types of convective clouds in the 2D run may lead to a higher value of the total sulfur mass removed by the wet deposition of about 33.9% to 39.2% for the continental nonpolluted and 36.2% to 45.6% for the continental polluted distributions relative to the base runs.

scholarly journals Mass spectrometric measurement of hydrogen isotope fractionation for the reactions of chloromethane with OH and Cl

2018 ◽  
Author(s):  
Frank Keppler ◽  
Enno Bahlmann ◽  
Markus Greule ◽  
Heinz Friedrich Schöler ◽  
Julian Wittmer ◽  
...  
Keyword(s):  
Hydrogen Isotope ◽  
Isotope Fractionation ◽  
Isotope Effects ◽  
Isotope Analysis ◽  
Isotope Ratio Mass Spectrometry ◽  
Detailed Knowledge ◽  
Mass Spectrometric Measurement ◽  
Isotopic Analyses ◽  
Chlorine Radicals ◽  
Stable Hydrogen Isotope

Abstract. Chloromethane (CH3Cl) is an important provider of chlorine to the stratosphere but yet lacks detailed knowledge of its budget. Stable isotope analysis is potentially a powerful tool to constrain CH3Cl flux estimates. The largest degree of isotope fractionation is expected to occur for deuterium in CH3Cl in the hydrogen abstraction reactions with its main sink reactant tropospheric OH and its minor sink reactant Cl atoms. We determined the isotope fractionation by stable hydrogen isotope analysis of the fraction of CH3Cl remaining after reaction with hydroxyl and chlorine radicals in a 3.5 m3 Teflon smog-chamber at 293 ± 1 K. We measured the increasing stable hydrogen isotope values of the unreacted CH3Cl using compound specific thermal conversion isotope ratio mass spectrometry. The isotope fractionations of CH3Cl for the reactions with hydroxyl and chlorine radicals were found to be −242 ± 7 mUr (or ‰) and −280 ± 11 mUr, respectively. For comparison, we performed similar experiments using methane (CH4) as the target compound with OH and obtained a fractionation constant of −205 ± 6 mUr which is in good agreement with values previously reported. The observed large kinetic isotope effects are helpful when employing isotopic analyses of CH3Cl in the atmosphere to improve our knowledge of its atmospheric budget.

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