Effect of Formaldehyde in Selective Catalytic Reduction of NOx by Ammonia (NH3-SCR) on a Commercial V2O5-WO3/TiO2 Catalyst under Model Conditions

2020 ◽  
Vol 54 (19) ◽  
pp. 11753-11761
Author(s):  
Anh Binh Ngo ◽  
Thanh Huyen Vuong ◽  
Hanan Atia ◽  
Ursula Bentrup ◽  
Vita A. Kondratenko ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Tio2 Catalyst ◽  
Nh3 Scr ◽  
Reduction Of Nox

scholarly journals Fe2O3 enhanced high-temperature arsenic resistance of CeO2–La2O3/TiO2 catalyst for selective catalytic reduction of NOx with NH3

RSC Advances ◽  
2021 ◽  
Vol 11 (16) ◽  
pp. 9395-9402
Author(s):  
Na Wang ◽  
Changfei Ye ◽  
Huidong Xie ◽  
Chang Yang ◽  
Jinhong Zhou ◽  
...  
Keyword(s):  
High Temperature ◽  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Arsenic Resistance ◽  
No Conversion ◽  
Tio2 Catalyst ◽  
Reduction Of Nox ◽  
Better Than

The NO conversion of the CeLa0.5Fe0.2/Ti is obviously better than that of the commercial vanadium-based catalyst with regard to arsenic resistance and it has good N2 selectivity, and good SO2 resistance.

Deactivation of Mn/TiO2 catalyst for NH3-SCR reaction: effect of phosphorous

RSC Advances ◽  
2016 ◽  
Vol 6 (14) ◽  
pp. 11226-11232 ◽  
Author(s):  
Ning-zhi Yang ◽  
Rui-tang Guo ◽  
Qing-shan Wang ◽  
Wei-guo Pan ◽  
Qi-lin Chen ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Reduction Of No ◽  
Tio2 Catalyst ◽  
Nh3 Scr ◽  
Deactivation Mechanism

The deactivation mechanism of phosphorous on a Mn/TiO2 catalyst for selective catalytic reduction of NO with NH3 was investigated in this study.

scholarly journals Promoting effect of Au on Pd/TiO2 catalyst for the selective catalytic reduction of NOx by H2

2019 ◽  
Vol 332 ◽  
pp. 69-75 ◽  
Author(s):  
Kaijiao Duan ◽  
Zhihua Wang ◽  
Christopher Hardacre ◽  
Zhiming Liu ◽  
Sarayute Chansai ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Promoting Effect ◽  
Tio2 Catalyst ◽  
Reduction Of Nox

Time-resolved in situ DRIFTS study on NH3–SCR of NO on CeO2/TiO2 catalyst

2022 ◽  
Author(s):  
Jie Yang ◽  
Shan Ren ◽  
Mingming Wang ◽  
Zhicaho Chen ◽  
Lin Chen ◽  
...  
Keyword(s):  
Nitrogen Oxides ◽  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Time Resolved ◽  
In Situ Drifts ◽  
Tio2 Catalyst ◽  
Nh3 Scr ◽  
Scr Of No

Ce–Ti catalysts were considered as promising replacement for V–Ti based catalysts for selective catalytic reduction (SCR) of nitrogen oxides (NO and NO2) with NH3. In this work, CeO2/TiO2 catalyst was...

Selective Catalytic Reduction of NOx by NH3 over Mn-Promoted V2O5/TiO2 Catalyst

2014 ◽  
Vol 53 (33) ◽  
pp. 12964-12970 ◽  
Author(s):  
Zhiming Liu ◽  
Yuan Li ◽  
Tianle Zhu ◽  
Hang Su ◽  
Junzhi Zhu
Keyword(s):  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Tio2 Catalyst ◽  
Reduction Of Nox

scholarly journals In Situ DRIFTS Studies of NH3-SCR Mechanism over V2O5-CeO2/TiO2-ZrO2 Catalysts for Selective Catalytic Reduction of NOx

Materials ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 1307 ◽  
Author(s):  
Yaping Zhang ◽  
Xiupeng Yue ◽  
Tianjiao Huang ◽  
Kai Shen ◽  
Bin Lu
Keyword(s):  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Nox Reduction ◽  
Oxygen Storage ◽  
In Situ Drifts ◽  
Nh3 Scr ◽  
Nh3 Adsorption ◽  
Reduction Of Nox ◽  
Zro2 Catalyst

TiO2-ZrO2 (Ti-Zr) carrier was prepared by a co-precipitation method and 1 wt. % V2O5 and 0.2 CeO2 (the Mole ratio of Ce to Ti-Zr) was impregnated to obtain the V2O5-CeO2/TiO2-ZrO2 catalyst for the selective catalytic reduction of NOx by NH3. The transient activity tests and the in situ DRIFTS (diffuse reflectance infrared Fourier transform spectroscopy) analyses were employed to explore the NH3-SCR (selective catalytic reduction) mechanism systematically, and by designing various conditions of single or mixing feeding gas and pre-treatment ways, a possible pathway of NOx reduction was proposed. It was found that NH3 exhibited a competitive advantage over NO in its adsorption on the catalyst surface, and could form an active intermediate substance of -NH2. More acid sites and intermediate reaction species (-NH2), at lower temperatures, significantly promoted the SCR activity of the V2O5-0.2CeO2/TiO2-ZrO2 catalyst. The presence of O2 could promote the conversion of NO to NO2, while NO2 was easier to reduce. The co-existence of NH3 and O2 resulted in the NH3 adsorption strength being lower, as compared to tests without O2, since O2 could occupy a part of the active site. Due to CeO2’s excellent oxygen storage-release capacity, NH3 adsorption was weakened, in comparison to the 1 wt. % V2O5-0.2CeO2/TiO2-ZrO2 catalyst. If NOx were to be pre-adsorbed in the catalyst, the formation of nitrate and nitro species would be difficult to desorb, which would greatly hinder the SCR reaction. All the findings concluded that NH3-SCR worked mainly through the Eley-Rideal (E-R) mechanism.

Selective catalytic reduction of NOx by NH3 over MoO3-promoted CeO2/TiO2 catalyst

2014 ◽  
Vol 46 ◽  
pp. 90-93 ◽  
Author(s):  
Zhiming Liu ◽  
Junzhi Zhu ◽  
Shaoxuan Zhang ◽  
Lingling Ma ◽  
Seong Ihl Woo
Keyword(s):  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Tio2 Catalyst ◽  
Reduction Of Nox

Effect of synthesis methods on activity of V2O5/CeO2/WO3-TiO2 catalyst for selective catalytic reduction of NOx with NH3

2016 ◽  
Vol 34 (3) ◽  
pp. 259-267 ◽  
Author(s):  
Meiqing SHEN ◽  
Lili XU ◽  
Jianqiang WANG ◽  
Chenxu LI ◽  
Wulin WANG ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Synthesis Methods ◽  
Tio2 Catalyst ◽  
Reduction Of Nox
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