Expanded Theory of H- and J-Molecular Aggregates: The Effects of Vibronic Coupling and Intermolecular Charge Transfer

2018 ◽  
Vol 118 (15) ◽  
pp. 7069-7163 ◽  
Author(s):  
Nicholas J. Hestand ◽  
Frank C. Spano
Keyword(s):  
Charge Transfer ◽  
Vibronic Coupling ◽  
Molecular Aggregates ◽  
Intermolecular Charge Transfer

Superposition-state N2+ produced in the intermolecular charge transfer from low-energy Ar+ to N2

2021 ◽  
Vol 154 (23) ◽  
pp. 234303
Author(s):  
Jie Hu ◽  
Jing-Chen Xie ◽  
Chun-Xiao Wu ◽  
Shan Xi Tian
Keyword(s):  
Charge Transfer ◽  
Low Energy ◽  
Superposition State ◽  
Intermolecular Charge Transfer

Amorphous Co(OH)2 nanocages achieving efficient photo-induced charge transfer for significant SERS activity

2022 ◽  
Author(s):  
Jian Yu ◽  
CHEN CHAO ◽  
Jie Lin ◽  
Xiangyu Meng ◽  
Lin Qiu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Raman Scattering ◽  
Vibronic Coupling ◽  
Substrate Molecule ◽  
Surface Enhanced ◽  
Critical Issues ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering ◽  
Induced Charge ◽  
Molecule Interactions

Boosting substrate-molecule interactions, especially the strong vibronic coupling and efficient photo-induced charge transfer (PICT) transitions, are critical issues to improve surface-enhanced Raman scattering (SERS) sensitivity of non-metal substrates. Here, by...

scholarly journals Metal-Free C-Se Cross-Coupling Enabled by Photoinduced Intermolecular Charge Transfer

2021 ◽  
Author(s):  
Chen Zhu ◽  
Serik Zhumagazy ◽  
Huifeng Yue ◽  
Magnus Rueping
Keyword(s):  
Charge Transfer ◽  
Visible Light ◽  
Electron Donor ◽  
Cross Coupling ◽  
Metal Free ◽  
Intermolecular Charge Transfer ◽  
Donor Acceptor

Metal-free C-Se cross-couplings via the formation of electron-donor-acceptor (EDA) complexes have been developed. The visible-light induced reactions can be applied for the synthesis of a series of unsymmetrical diaryl selenides...

scholarly journals Intermolecular Charge-Transfer-Induced Strong Optical Emission from Herringbone H-Aggregates

2021 ◽  
Author(s):  
Qi Sun ◽  
Jiajun Ren ◽  
Tong Jiang ◽  
Qian Peng ◽  
Qi Ou ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Optical Emission ◽  
Light Emitting ◽  
High Charge ◽  
Organic Light ◽  
Intermolecular Charge Transfer ◽  
Transfer Integrals ◽  
Strong Luminescence ◽  
Theoretical Finding ◽  
Three State Model

Superior organic light-emitting transistors (OLETs) materials require two conventionally exclusive properties: strong luminescence and high charge mobilities. We propose a three-state model through localized diabatization to quantitative analyze excited state structures for various herringbone (HB) H-aggregates and demonstrate that for some investigated systems, the low-lying intermolecular charge-transfer (CT) state couples with the bright Frenkel exciton (FE) and forms a dipole-allowed S<sub>1</sub> that lies below the dark state, proceeding strong luminescence. Specifically, such conversion in luminescence properties occurs when the electron- and hole-transfer integrals ( and ) are of the same sign and is notably larger than the excitonic coupling (<i>J</i>), i.e., . This theoretical finding can not only explain and rationalize recent experimental results on DPA and dNaAnt, both with OLET property, but also unravel an exciting scenario where strong luminescence and high charge mobilities are compatible, which will considerably broaden the aperture of novel OLET design.

Sign in / Sign up

Export Citation Format

Share Document