Alkali Counterions Impact Crystallization Kinetics of Apatite Nanocrystals from Amorphous Calcium Phosphate in Water at High pH

2018 ◽  
Vol 18 (11) ◽  
pp. 6723-6728 ◽  
Author(s):  
Casper Jon Steenbjerg Ibsen ◽  
Hanna Leemreize ◽  
Bjørn Fridur Mikladal ◽  
Jonas Skovgaard ◽  
Martin Bremholm ◽  
...  
Keyword(s):  
Calcium Phosphate ◽  
Crystallization Kinetics ◽  
Amorphous Calcium Phosphate ◽  
High Ph ◽  
Kinetics Of

Hydrothermal crystallization kinetics of m-ZrO2 and t-ZrO2

1990 ◽  
Vol 5 (11) ◽  
pp. 2698-2705 ◽  
Author(s):  
Raymond P. Denkewicz ◽  
Kevor S. TenHuisen ◽  
James H. Adair
Keyword(s):  
Crystallization Kinetics ◽  
Low Ph ◽  
Formation Mechanisms ◽  
Gel Structure ◽  
Hydrothermal Conditions ◽  
High Ph ◽  
Ph Values ◽  
Ph Conditions ◽  
Apparent Activation Energies ◽  
Kinetics Of

The isothermal nucleation and crystallization kinetics of hydrothermally prepared monoclinic and tetragonal ZrO2 have been determined at various pH conditions. It is shown that monoclinic ZrO2 precipitates at low pH whereas at high pH tetragonal ZrO2 crystallizes from an amorphous zirconium (hydrous) oxide, Zr(OH)xOy, precursor. At intermediate pH conditions mixtures of the polymorphs are formed suggestive of kinetically competing particle formation mechanisms. The data are explained by the proposed existence of three controlling regimes for the formation of crystalline ZrO2: dissolution/precipitation at low pH, a solubility controlled regime at intermediate pH values, and a gel structure controlled regime at high pH. Apparent activation energies for the nucleation and crystallization of monoclinic and tetragonal ZrO2 formed under hydrothermal conditions are presented.

scholarly journals Insights into the kinetics of thermally induced crystallization of amorphous calcium phosphate

2018 ◽  
Vol 20 (46) ◽  
pp. 29221-29235 ◽  
Author(s):  
Vuk Uskoković ◽  
Smilja Marković ◽  
Ljiljana Veselinović ◽  
Srečo Škapin ◽  
Nenad Ignjatović ◽  
...  
Keyword(s):  
Calcium Phosphate ◽  
Bone Metabolism ◽  
Bone Remodeling ◽  
Amorphous Calcium Phosphate ◽  
Thermally Induced ◽  
P Transformations ◽  
Kinetics Of ◽  
Induced Crystallization

Transformations between amorphous and crystalline apatite mechanistically govern some of the most essential processes in bone metabolism, including biomineralization and bone remodeling.

Light transmittance and polymerization kinetics of amorphous calcium phosphate composites

2016 ◽  
Vol 21 (4) ◽  
pp. 1173-1182 ◽  
Author(s):  
Matej Par ◽  
Danijela Marovic ◽  
Hrvoje Skenderovic ◽  
Ozren Gamulin ◽  
Eva Klaric ◽  
...  
Keyword(s):  
Calcium Phosphate ◽  
Amorphous Calcium Phosphate ◽  
Polymerization Kinetics ◽  
Light Transmittance ◽  
Kinetics Of

Synthesis and Crystallization Kinetics of Y 2CaA1 4SiO 12 Garnet-Type Glass-Ceramic

2020 ◽  
Author(s):  
Liyuan Wang ◽  
Jiaxi Liu ◽  
Nan Lu ◽  
Zengchao Yang ◽  
Gang He ◽  
...  
Keyword(s):  
Crystallization Kinetics ◽  
Glass Ceramic ◽  
Kinetics Of

Reordering and Crystallization of Silicon Carbide Amorphized by Neutron Irradiation

2000 ◽  
Vol 650 ◽  
Author(s):  
Lance L. Snead ◽  
Martin Balden
Keyword(s):  
Thin Film ◽  
Silicon Carbide ◽  
Crystallization Kinetics ◽  
Neutron Irradiation ◽  
Onset Temperature ◽  
Kinetics Of Crystallization ◽  
Crystallization Onset Temperature ◽  
Crystallization Onset ◽  
Kinetics Of

ABSTRACTDensification and crystallization kinetics of bulk SiC amorphized by neutron irradiation is studied. The temperature of crystallization onset of this highly pure, fully amorphous bulk SiC was found to be between 875-885°C and crystallization is nearly complete by 950°C. In-situ TEM imaging confirms the onset of crystallization, though thin-film effects apparently alter the kinetics of crystallization above this temperature. It requires >1125°C for complete crystallization of the TEM foil. Annealing at temperatures between the irradiation and crystallization onset temperature is seen to cause significant densification attributed to a relaxation, or reordering, of the as-amorphized structure.

Crystallization kinetics of compatibilized blends of polypropylene and polyethylenimine

2021 ◽  
Author(s):  
Pratim Kumar Patra ◽  
Aanchal Jaisingh ◽  
Vishal Goel ◽  
Gurpreet Singh Kapur ◽  
Leena Nebhani
Keyword(s):  
Crystallization Kinetics ◽  
Kinetics Of ◽  
Compatibilized Blends

scholarly journals Reversal of Root Caries with Casein Phosphopeptide-Amorphous Calcium Phosphate and Fluoride Varnish in Xerostomia

2021 ◽  
pp. 1-10
Author(s):  
Ahmed Sleibi ◽  
Anwar R. Tappuni ◽  
Aylin Baysan
Keyword(s):  
Calcium Phosphate ◽  
Amorphous Calcium Phosphate ◽  
Primary Root ◽  
Severity Index ◽  
Salivary Flow ◽  
Root Caries ◽  
Carious Lesions ◽  
Group 2 ◽  
Casein Phosphopeptide ◽  
Group 1

Different formulas of topical fluoride have been used to manage root carious lesions. This clinical trial aimed to investigate the efficacy of a dental varnish containing casein phosphopeptide-amorphous calcium phosphate (CPP-ACP) and fluoride compared with fluoride alone in reversing/arresting root caries in xerostomic patients over 1 year. A total of 80 patients (age range 45–92 years) with primary root caries (<i>n</i> = 184 root carious lesions) and unstimulated salivary flow rate of &#x3c;0.2 mL/min were randomly allocated to receive either dental varnish containing CPP-ACP and 5% fluoride (group 1: MI varnish; GC, Japan) (<i>n</i> = 41, 83 lesions), or dental varnish with 5% fluoride alone (group 2: NUPRO White; Dentsply, USA) (<i>n</i> = 39, 101 lesions). Clinical assessments with Severity Index (SI) for root caries, DIAGNOdent measurements, and varnish application were carried out at baseline, 3, 6, and 12 months. Standard oral hygiene instructions with 1,450 ppm fluoride toothpastes were provided for both groups. After 3 months, 63.9% (<i>n</i> = 46) of root caries in group 1 became hard (SI: 0) compared with 39.3% (<i>n</i> = 35) in group 2 (<i>p</i> &#x3c; 0.01). After 6 and 12 months, the differences in SI were insignificant (group 1, <i>n</i> = 60, 83.3%) (group 2, <i>n</i> = 66, 74.2%) (<i>p</i> = 0.36), and (group 1, <i>n</i> = 60, 89.6%) (group 2, <i>n</i> = 67, 81.7%, <i>n</i> = 1 soft, 1.2%) (<i>p</i> = 0.29), respectively. In both groups, noncavitated leathery lesions were more likely to become hard when compared to the cavitated root caries. A significant decrease in plaque index, surface roughness, lesion dimension, and DIAGNOdent readings with a significant increase in lesion distance from the gingival margin was reported in both groups (<i>p</i> &#x3c; 0.05). This study has provided evidence that fluoride dental varnish either with or without calcium and phosphate has the potential to arrest/reverse root caries, especially noncavitated lesions for patients with xerostomia.

Crystallization kinetics of amorphous acetonitrile nanoscale films

2021 ◽  
Vol 154 (14) ◽  
pp. 144703
Author(s):  
R. Scott Smith ◽  
M. Tylinski ◽  
Greg A. Kimmel ◽  
Bruce D. Kay
Keyword(s):  
Crystallization Kinetics ◽  
Nanoscale Films ◽  
Kinetics Of
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