Two Porous Polyoxometalate-Resorcin[4]arene-Based Supramolecular Complexes: Selective Adsorption of Organic Dyes and Electrochemical Properties

2018 ◽  
Vol 18 (10) ◽  
pp. 6046-6053 ◽  
Author(s):  
Qiu-Yi Zhai ◽  
Juan Su ◽  
Ting-Ting Guo ◽  
Jin Yang ◽  
Jian-Fang Ma ◽  
...  
2021 ◽  
Author(s):  
Jeena N. Baby ◽  
Lavanya Chandrasekar ◽  
Sea-Fue Wang ◽  
Sriram Balasubramanian ◽  
Ashwini Anantharaman ◽  
...  

By serving as alternatives to toxic and hazardous solvents, green solvents assist in implementing the idea of sustainability. The use of these neoeric reaction media dramatically reduces energy requirements and...


2021 ◽  
Vol 60 (3) ◽  
pp. 1571-1578
Author(s):  
Xinli Shi ◽  
Yucong Zu ◽  
Shuangshuang Jiang ◽  
Fuxing Sun

2021 ◽  
Author(s):  
Yu Liu ◽  
Yan Wang ◽  
Xiao-Sa Zhang ◽  
Wen-Ze Li ◽  
Ai-Ai Yang ◽  
...  

Abstract 3D metal-organic frameworks (MOFs) can be appropriate templates for the fabrication of nanomaterials due to they have active sites exposed on the channel or surface, which thus provide them with improved catalytic performance. In this study, a 3D cobalt-based MOF [Co(H2bpta)]n (Co-MOF), where H4bpta denotes 2,2′,4,4′-biphenyltetracarboxylic acid, has been constructed with the use of a ligand with a high carbon content. On this basis, a 2D magnetic carbon-coated cobalt nanoparticle composite (C@Co) was prepared by using the title MOF. Magnetic C@Co can readily absorb dye from the solution and can thus act as an inexpensive and fast-acting adsorbent. Moreover, we have explored the adsorption isotherms, kinetics and thermodynamics of the anion dyes in detail. The adsorption capacity of the C@Co for investigated methyl orange (MO) and congo red (CR) dyes were 773.48 and 495.66 mg g− 1, respectively. It is noteworthy that MO adsorption is higher in existing materials. Thermodynamic studies suggest that the adsorption processes are spontaneous and exothermic. This study opens a new insight into the synthesis and application of carbon-based materials that enable the selective removal of organic dyes.


CrystEngComm ◽  
2018 ◽  
Vol 20 (41) ◽  
pp. 6438-6448 ◽  
Author(s):  
Xiuli Wang ◽  
Xue Bai ◽  
Hongyan Lin ◽  
Junjun Sun ◽  
Guocheng Liu ◽  
...  

Three novel polyoxometalate (POM)-based cobalt complexes have been synthesized and structurally characterized. The adsorption activities for organic dyes and electrochemical properties have been studied in detail.


Chemosphere ◽  
2021 ◽  
pp. 133073
Author(s):  
Mansour A.S. Salem ◽  
Amjad Mumtaz Khan ◽  
Yahiya Kadaf Manea ◽  
Ajaz Ahmad Wani

Polyhedron ◽  
2020 ◽  
Vol 191 ◽  
pp. 114816
Author(s):  
Xiaoyin Zhang ◽  
Ziao Zong ◽  
Xia Zhang ◽  
Dongmei Zhang ◽  
Qingdan Luo ◽  
...  

2016 ◽  
Vol 18 (9) ◽  
Author(s):  
Jincan Jia ◽  
Honghong Wang ◽  
Helin Niu ◽  
Jingshuai Chen ◽  
Jiming Song ◽  
...  

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