Interplay between Kinetics and Thermodynamics on the Probability Nucleation Rate of a Urea–Water Crystallization System

2018 ◽  
Vol 18 (4) ◽  
pp. 2305-2315 ◽  
Author(s):  
Shijie Xu ◽  
Yifu Chen ◽  
Junbo Gong ◽  
Jingkang Wang
Keyword(s):  
Nucleation Rate ◽  
Kinetics And Thermodynamics ◽  
Crystallization System ◽  
Water Crystallization

Adsorption of safranine T from aqueous medium by nano mesoporous MCM-41: adsorption equilibrium, kinetics, and thermodynamics

2020 ◽  
Vol 10 ◽  
Author(s):  
Xiao-Dong Li ◽  
Qing-Zhou Zhai
Keyword(s):  
Electron Microscopy ◽  
Ph Value ◽  
Particle Diameter ◽  
Spherical Particles ◽  
Practical Significance ◽  
Average Particle ◽  
Average Pore ◽  
Kinetics And Thermodynamics ◽  
Safranine T ◽  
Mcm 41

Introduction: In industrial production, a small amount of saffron T emissions will cause increase of water color and increase of chemical oxygen consumption, so study of the decolorization of saffron T wastewater has an important practical significance. Methods: MCM (Mobil Composition of Matter)-41 molecular sieve was synthesized by hydrothermal method. Power Xray diffraction and scanning electron microscopy were used to characterize the sample. Safranine T dye was adsorbed from water by the MCM-41 prepared. Kinetics and thermodynamics of the adsorption were studied. Results: The MCM-41 sample presented spherical particles and regular. The BET (Brunner-Emmett-Teller) specific surface area of the sample determined by 77 K low temperature nitrogen adsorption-desorption isotherm was 932 m2 /g. Its average particle diameter was 110 nm. TEM (transmission electron microscopy) results showed that the sample structure presented a honeycomb pore structure and the average pore diameter was 3.0 nm. The results showed that when room temperature was 20 ± 1 ℃, adsorbate safranine T: adsorbent MCM-41 = 20 : 1，the optimum pH value of adsorption was 4.0 and contact time was 20 min, the adsorption rate reached 98.29% and the adsorption capacity was 19.66 mg/g. The entropy change and enthalpy change of the adsorption system are respectively ΔS0 = 157.5 J/(mol·K); ΔH0 = 21.544 kJ/mol. When temperature was 277.15, 293.15, 303.15 K，the free energy change was respectively △G1 0 = -22.107 kJ/mol, △G2 0 = -24.627 kJ/mol, △G3 0 = -26.202 kJ/mol. Conclusion: The adsorption of safranine T by MCM-41 belongs to a pseudo-second-order adsorption. This adsorption accords with the Freundlich equation and belongs to a heterogeneous adsorption. The adsorption is an endothermic reaction of entropy increase, being spontaneous.

scholarly journals Kinetics and thermodynamics of oxygen, CO, and azide binding by the subcomponents of soybean leghemoglobin.

1990 ◽  
Vol 265 (32) ◽  
pp. 19588-19593
Author(s):  
K D Martin ◽  
L Saari ◽  
G X Wang ◽  
T Wang ◽  
L J Parkhurst ◽  
...  
Keyword(s):  
Kinetics And Thermodynamics ◽  
Azide Binding ◽  
Soybean Leghemoglobin
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