Low-Pressure Selectivity, Stepwise Gas Sorption Behaviors, and Luminescent Properties (Experimental Findings and Theoretical Correlation) of Three Zn(II)-Based Metal–Organic Frameworks

2017 ◽  
Vol 17 (7) ◽  
pp. 3965-3973 ◽  
Author(s):  
Yun-Long Wu ◽  
Fan Yang ◽  
Jinjie Qian ◽  
Guo-Ping Yang ◽  
Jing Jin ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Luminescent Properties ◽  
Low Pressure ◽  
Gas Sorption ◽  
Metal Organic ◽  
Experimental Findings

scholarly journals Increasing the Stability of Metal-Organic Frameworks

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Mathieu Bosch ◽  
Muwei Zhang ◽  
Hong-Cai Zhou
Keyword(s):  
Metal Organic Frameworks ◽  
Luminescent Properties ◽  
Vacuum Treatment ◽  
Donor Ligands ◽  
Gas Sorption ◽  
Nitrogen Donor Ligands ◽  
Metal Centers ◽  
Ligand Interactions ◽  
Metal Organic ◽  
The Stability

Metal-organic frameworks (MOFs) are a new category of advanced porous materials undergoing study by many researchers for their vast variety of both novel structures and potentially useful properties arising from them. Their high porosities, tunable structures, and convenient process of introducing both customizable functional groups and unsaturated metal centers have afforded excellent gas sorption and separation ability, catalytic activity, luminescent properties, and more. However, the robustness and reactivity of a given framework are largely dependent on its metal-ligand interactions, where the metal-containing clusters are often vulnerable to ligand substitution by water or other nucleophiles, meaning that the frameworks may collapse upon exposure even to moist air. Other frameworks may collapse upon thermal or vacuum treatment or simply over time. This instability limits the practical uses of many MOFs. In order to further enhance the stability of the framework, many different approaches, such as the utilization of high-valence metal ions or nitrogen-donor ligands, were recently investigated. This review details the efforts of both our research group and others to synthesize MOFs possessing drastically increased chemical and thermal stability, in addition to exemplary performance for catalysis, gas sorption, and separation.

Homochiral lanthanoid(iii) mesoxalate metal–organic frameworks: synthesis, crystal growth, chirality, magnetic and luminescent properties

CrystEngComm ◽  
2012 ◽  
Vol 14 (8) ◽  
pp. 2635 ◽  
Author(s):  
Beatriz Gil-Hernández ◽  
Jana K. Maclaren ◽  
Henning A. Höppe ◽  
Jorge Pasán ◽  
Joaquín Sanchiz ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Metal Organic Frameworks ◽  
Luminescent Properties ◽  
Metal Organic

Metal-organic frameworks from pre-synthesized heterometallic (d-f) complexes: Synthesis, structure and luminescent properties

2021 ◽  
Vol 517 ◽  
pp. 120216
Author(s):  
Aleksandr A. Sapianik ◽  
Evgeny R. Dudko ◽  
Denis G. Samsonenko ◽  
Vladimir A. Lazarenko ◽  
Pavel V. Dorovatovskii ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Luminescent Properties ◽  
Metal Organic

Systematic and Dramatic Tuning on Gas Sorption Performance in Heterometallic Metal–Organic Frameworks

2016 ◽  
Vol 138 (8) ◽  
pp. 2524-2527 ◽  
Author(s):  
Quan-Guo Zhai ◽  
Xianhui Bu ◽  
Chengyu Mao ◽  
Xiang Zhao ◽  
Pingyun Feng
Keyword(s):  
Metal Organic Frameworks ◽  
Gas Sorption ◽  
Metal Organic

Syntheses, characterization and luminescent properties of two lead(II) fumarate metal-organic frameworks

Polyhedron ◽  
2009 ◽  
Vol 28 (4) ◽  
pp. 647-652 ◽  
Author(s):  
Kou-Lin Zhang ◽  
Wei Liang ◽  
Yan Chang ◽  
Li-Min Yuan ◽  
Seik Weng Ng
Keyword(s):  
Metal Organic Frameworks ◽  
Luminescent Properties ◽  
Metal Organic

A series of microporous and robust Ln-MOFs showing luminescent properties and catalytic performances towards Knoevenagel reactions

2021 ◽  
Author(s):  
Qing-Xia Yao ◽  
Miaomiao Tian ◽  
Jun Zheng ◽  
Jintang Xue ◽  
Xuze Pan ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Frameworks ◽  
Luminescent Properties ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Catalytic Performances

A series of microporous Ln(III)-based metal-organic frameworks (1-Ln) have been hydrothermally synthesized by using 4,4',4''-nitrilotribenzoic acid (H3NTB). Single crystal X-ray diffraction analyses show 1-Ln are isostructural and have 3D porous...

scholarly journals A combined experimental and theoretical study of gas sorption on nanoporous silver triazolato metal–organic frameworks

2014 ◽  
Vol 183 ◽  
pp. 62-68 ◽  
Author(s):  
Guang Yang ◽  
Juan A. Santana ◽  
Milton E. Rivera-Ramos ◽  
Omar García-Ricard ◽  
Jose J. Saavedra-Arias ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Metal Organic Frameworks ◽  
Gas Sorption ◽  
Metal Organic
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