Cadmium Metal–Organic Frameworks Based on Ditopic Triazamacrocyclic Linkers: Unusual Structural Features and Selective CO2Capture

2017 ◽  
Vol 17 (7) ◽  
pp. 3665-3676 ◽  
Author(s):  
Hervé Feuchter ◽  
Guillaume Ortiz ◽  
Yoann Rousselin ◽  
Alla Bessmertnykh-Lemeune ◽  
Stéphane Brandès
Keyword(s):  
Metal Organic Frameworks ◽  
Structural Features ◽  
Cadmium Metal ◽  
Metal Organic

scholarly journals Structural Features of Zirconium-Based Metal–Organic Frameworks Affecting Radiolytic Stability

2020 ◽  
Vol 59 (16) ◽  
pp. 7520-7526 ◽  
Author(s):  
Sylvia L. Hanna ◽  
David X. Rademacher ◽  
Donald J. Hanson ◽  
Timur Islamoglu ◽  
Alyssa K. Olszewski ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Structural Features ◽  
Radiolytic Stability ◽  
Metal Organic

BTC-based metal-organic frameworks: Correlation between relevant structural features and CO2 adsorption performances

Fuel ◽  
2018 ◽  
Vol 222 ◽  
pp. 319-326 ◽  
Author(s):  
Valentina Gargiulo ◽  
Michela Alfè ◽  
Federica Raganati ◽  
Luciana Lisi ◽  
Riccardo Chirone ◽  
...  
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Frameworks ◽  
Structural Features ◽  
Metal Organic

Long lifetime photoluminescence emission of 3D cadmium metal–organic frameworks based on the 5-(4-pyridyl)tetrazole ligand

2015 ◽  
Vol 427 ◽  
pp. 131-137 ◽  
Author(s):  
Antonio J. Calahorro ◽  
Alfonso Salinas-Castillo ◽  
David Fairen-Jimenez ◽  
Jose M. Seco ◽  
Claudio Mendicute-Fierro ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Photoluminescence Emission ◽  
Cadmium Metal ◽  
Metal Organic ◽  
Long Lifetime

Bidimensional cadmium metal-organic frameworks based on 1,3-bis(4-pyridyl)propane displaying long lifetime photoluminescence emission

Polyhedron ◽  
2015 ◽  
Vol 91 ◽  
pp. 47-51 ◽  
Author(s):  
Antonio J. Calahorro ◽  
David Briones ◽  
José M. Seco ◽  
Alfonso Salinas-Castillo ◽  
Antonio Rodríguez-Diéguez ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Photoluminescence Emission ◽  
Cadmium Metal ◽  
Metal Organic ◽  
Long Lifetime

Structural features and applications of metal–organic frameworks containing thiazole- and thiazolidine-based spacers

CrystEngComm ◽  
2015 ◽  
Vol 17 (2) ◽  
pp. 218-228 ◽  
Author(s):  
A. Rossin ◽  
G. Giambastiani
Keyword(s):  
Heterogeneous Catalysis ◽  
Crystal Structures ◽  
Network Topology ◽  
Metal Organic Frameworks ◽  
Structural Features ◽  
Metal Organic

This highlight describes the crystal structures and network topology of thiazole- and thiazolidine-containing MOFs and CPs along with their applications in the fields of CO2 adsorption, luminescence, magnetism and heterogeneous catalysis.

Robustness, Selective Gas Separation, and Nitrobenzene Sensing on Two Isomers of Cadmium Metal–Organic Frameworks Containing Various Metal–O–Metal Chains

2018 ◽  
Vol 57 (20) ◽  
pp. 12961-12968 ◽  
Author(s):  
Lizhen Liu ◽  
Zizhu Yao ◽  
Yingxiang Ye ◽  
Liangji Chen ◽  
Quanjie Lin ◽  
...  
Keyword(s):  
Gas Separation ◽  
Metal Organic Frameworks ◽  
Cadmium Metal ◽  
Metal Organic

Crystal engineering on superpolyhedral building blocks in metal–organic frameworks applied in gas adsorption

2015 ◽  
Vol 71 (6) ◽  
pp. 613-618 ◽  
Author(s):  
Ying-Pin Chen ◽  
Tian-Fu Liu ◽  
Stephen Fordham ◽  
Hong-Cai Zhou
Keyword(s):  
Surface Area ◽  
Crystal Engineering ◽  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Supercritical Drying ◽  
Building Blocks ◽  
Structural Features ◽  
Open Channels ◽  
Bet Surface Area ◽  
Metal Organic

Two metal–organic frameworks [PCN-426(Ni) and PCN-427(Cu)] have been designed and synthesized to investigate the structure predictability using a SBB (supermolecular building blocks) approach. Tetratopic ligands featuring 120° angular carboxylate moieties were coordinated with a [Ni3(μ3-O)] cluster and a [Cu2O2] unit, respectively. As topologically predicted, 4-connected networks with square coordination adopted the nbo net for the Ni-MOF and ssb net for the Cu-MOF. PCN-426(Ni) was augmented with 12-connected octahedral SBBs, while PCN-427(Cu) was constructed with tetragonal open channels. After a CO2 supercritical drying procedure, the PCN-426(Ni) possessed a Brunauer–Emmett–Teller (BET) surface area as high as 3935 m2 g−1 and impressively high N2 uptake of 1500 cm3 g−1. This work demonstrates the generalization of the SBB strategy, finding an alternative to inconvenient synthetic processes to achieve the desired structural features.

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