Insight into the Controllable Synthesis of Cu(I)/Cu(II) Metal–Organic Complexes: Size-Exclusive Selective Dye Adsorption and Semiconductor Properties

2017 ◽  
Vol 17 (5) ◽  
pp. 2549-2559 ◽  
Author(s):  
Yang Song ◽  
Rui-Qing Fan ◽  
Kai Xing ◽  
Xi Du ◽  
Ting Su ◽  
...  
Keyword(s):  
Dye Adsorption ◽  
Controllable Synthesis ◽  
Organic Complexes ◽  
Metal Organic ◽  
Insight Into ◽  
Semiconductor Properties

New Ce(iii) sulfate–tartrate-based MOFs: an insight into the controllable self-assembly of acentric metal–organic complexes

CrystEngComm ◽  
2013 ◽  
Vol 15 (48) ◽  
pp. 10618 ◽  
Author(s):  
Jin-Li Qi ◽  
Yue-Qing Zheng ◽  
Wei Xu ◽  
Hong-Lin Zhu ◽  
Jian-Li Lin ◽  
...  
Keyword(s):  
Self Assembly ◽  
Organic Complexes ◽  
Metal Organic ◽  
Insight Into

Solvent-controlled synthesis of various Anderson-type polyoxometalate-based metal–organic complexes with excellent capacity for the chromatographic separation of dyes

CrystEngComm ◽  
2018 ◽  
Vol 20 (1) ◽  
pp. 51-62 ◽  
Author(s):  
Xiu-Li Wang ◽  
Ge Song ◽  
Hong-Yan Lin ◽  
Xiang Wang ◽  
Guo-Cheng Liu ◽  
...  
Keyword(s):  
Chromatographic Separation ◽  
Dye Adsorption ◽  
Separation Performance ◽  
Controlled Synthesis ◽  
Organic Complexes ◽  
Metal Organic ◽  
Short Time

A series of Anderson-type POMs-based metal-organic complexes were synthesized in different solvents, which show excellent dye adsorption and chromatographic separation performance in a short time.

Various Anderson-type polyoxometalate-based metal–organic complexes induced by diverse solvents: assembly, structures and selective adsorption for organic dyes

2020 ◽  
Vol 49 (4) ◽  
pp. 1265-1275 ◽  
Author(s):  
Jia-Hui Li ◽  
Xiu-Li Wang ◽  
Ge Song ◽  
Hong-Yan Lin ◽  
Xiang Wang ◽  
...  
Keyword(s):  
Chromatographic Separation ◽  
Organic Dyes ◽  
Selective Adsorption ◽  
Dye Adsorption ◽  
Organic Complexes ◽  
Metal Organic ◽  
Short Time

A series of Anderson-type polyoxometalates (POMs)-based metal–organic complexes with different structures have been synthesized, they show excellent dye adsorption and chromatographic separation in a short time.

Quantum Mechanical Interpretation of the Ultra-Low Energy Methyl-Rotation Dynamics in Porous Metal-Organic Frameworks Probed by Low-Frequency Vibrational Spectroscopy and ab initio Simulations

2018 ◽  
Author(s):  
Qi Li ◽  
Adam J. Zaczek ◽  
Timothy M. Korter ◽  
J. Axel Zeitler ◽  
Michael T. Ruggiero
Keyword(s):  
Ab Initio ◽  
Metal Organic Frameworks ◽  
Low Frequency ◽  
Rotor Dynamics ◽  
Quantum Mechanical ◽  
Valuable Insight ◽  
Void Space ◽  
Ab Initio Simulations ◽  
Metal Organic ◽  
Insight Into

<div>Understanding the nature of the interatomic interactions present within the pores of metal-organic frameworks</div><div>is critical in order to design and utilize advanced materials</div><div>with desirable applications. In ZIF-8 and its cobalt analogue</div><div>ZIF-67, the imidazolate methyl-groups, which point directly</div><div>into the void space, have been shown to freely rotate - even</div><div>down to cryogenic temperatures. Using a combination of ex-</div><div>perimental terahertz time-domain spectroscopy, low-frequency</div><div>Raman spectroscopy, and state-of-the-art ab initio simulations,</div><div>the methyl-rotor dynamics in ZIF-8 and ZIF-67 are fully charac-</div><div>terized within the context of a quantum-mechanical hindered-</div><div>rotor model. The results lend insight into the fundamental</div><div>origins of the experimentally observed methyl-rotor dynamics,</div><div>and provide valuable insight into the nature of the weak inter-</div><div>actions present within this important class of materials.</div>

Semiconductors

2018 ◽  
Author(s):  
L. Solymar ◽  
D. Walsh ◽  
R. R. A. Syms
Keyword(s):  
Crystal Growth ◽  
Molecular Beam ◽  
Vapour Deposition ◽  
Energy Levels ◽  
Chemical Vapour ◽  
Optical Excitation ◽  
Organic Chemical ◽  
Metal Organic ◽  
Mathematical Relations ◽  
Semiconductor Properties

Both intrinsic and extrinsic semiconductors are discussed in terms of their band structure. The acceptor and donor energy levels are introduced. Scattering is discussed, from which the conductivity of semiconductors is derived. Some mathematical relations between electron and hole densities are derived. The mobilities of III–V and II–VI compounds and their dependence on impurity concentrations are discussed. Band structures of real and idealized semiconductors are contrasted. Measurements of semiconductor properties are reviewed. Various possibilities for optical excitation of electrons are discussed. The technology of crystal growth and purification are reviewed, in particular, molecular beam epitaxy and metal-organic chemical vapour deposition.

A 2-Fold Interpenetrated Nitrogen-Rich Metal–Organic Framework: Dye Adsorption and CO2 Capture and Conversion

2021 ◽  
Author(s):  
Xiao-Li Yang ◽  
Yang-Tian Yan ◽  
Wen-Juan Wang ◽  
Ze-Ze Hao ◽  
Wen-Yan Zhang ◽  
...  
Keyword(s):  
Co2 Capture ◽  
Metal Organic Framework ◽  
Dye Adsorption ◽  
Metal Organic ◽  
Organic Framework

Enhanced Dye Adsorption of Mixed‐Matrix Membrane by Covalent Incorporation of Metal‐Organic Framework with Poly(styrene‐ alt ‐maleic anhydride)

2021 ◽  
Vol 6 (19) ◽  
pp. 4689-4697
Author(s):  
Xuan Thang Cao ◽  
The Ky Vo ◽  
Tran Nguyen Minh An ◽  
Trinh Duy Nguyen ◽  
Daniel Manaye Kabtamu ◽  
...  
Keyword(s):  
Maleic Anhydride ◽  
Metal Organic Framework ◽  
Dye Adsorption ◽  
Mixed Matrix Membrane ◽  
Mixed Matrix ◽  
Metal Organic ◽  
Organic Framework

Interplay of coordinative and supramolecular interactions in formation of a series of metal–organic complexes bearing diverse dimensionalities

2009 ◽  
pp. 5365 ◽  
Author(s):  
Jian-Qiang Liu ◽  
Ya-Nan Zhang ◽  
Yao-Yu Wang ◽  
Jun-Cheng Jin ◽  
Elmira Kh. Lermontova ◽  
...  
Keyword(s):  
Supramolecular Interactions ◽  
Organic Complexes ◽  
Metal Organic
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