Rapid Synthesis of Metal–Organic Frameworks MIL-101(Cr) Without the Addition of Solvent and Hydrofluoric Acid

2016 ◽  
Vol 16 (3) ◽  
pp. 1168-1171 ◽  
Author(s):  
Kunyue Leng ◽  
Yinyong Sun ◽  
Xiaolin Li ◽  
Shun Sun ◽  
Wei Xu
Keyword(s):  
Hydrofluoric Acid ◽  
Metal Organic Frameworks ◽  
Rapid Synthesis ◽  
Metal Organic

Rapid Synthesis of Hierarchical Porous Metal–Organic Frameworks and the Simulation of Growth

2018 ◽  
Vol 18 (11) ◽  
pp. 6661-6669 ◽  
Author(s):  
Hang Zhang ◽  
Jinhao Huo ◽  
Feier Li ◽  
Chongxiong Duan ◽  
Hongxia Xi
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Rapid Synthesis ◽  
Hierarchical Porous ◽  
Metal Organic

Hierarchically porous metal–organic frameworks: rapid synthesis and enhanced gas storage

Soft Matter ◽  
2018 ◽  
Vol 14 (47) ◽  
pp. 9589-9598 ◽  
Author(s):  
Chongxiong Duan ◽  
Hang Zhang ◽  
Feier Li ◽  
Jing Xiao ◽  
Shaojuan Luo ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Gas Storage ◽  
Organic Amine ◽  
Rapid Synthesis ◽  
Hierarchically Porous ◽  
Adsorption Capacities ◽  
Metal Organic ◽  
Diffusion Rates ◽  
Enhanced Adsorption

A simple, rapid and versatile method was developed to increase the pore sizes and pore volumes of microporous MOFs (HKUST-1, ZIF-8, ZIF-67, and ZIF-90) by employing organic amine as the template. The resultant hierarchically porous HKUST-1 exhibited significantly enhanced adsorption capacities and faster diffusion rates for CH4 and CO2 gas storage.

scholarly journals The vapour phase detection of explosive markers and derivatives using two fluorescent metal–organic frameworks

2015 ◽  
Vol 3 (12) ◽  
pp. 6351-6359 ◽  
Author(s):  
Monika Jurcic ◽  
William J. Peveler ◽  
Christopher N. Savory ◽  
David O. Scanlon ◽  
Anthony J. Kenyon ◽  
...  
Keyword(s):  
Microwave Synthesis ◽  
Metal Organic Frameworks ◽  
Vapour Phase ◽  
Sensitive Detection ◽  
Phase Detection ◽  
Rapid Synthesis ◽  
Highly Sensitive ◽  
Metal Organic ◽  
Highly Sensitive Detection

Microwave synthesis of a new Zn-MOF gives rapid synthesis of uniform microcrystals for highly sensitive detection of explosive taggant DMNB.

scholarly journals Developing a sustainable route to environmentally relevant metal–organic frameworks: ultra-rapid synthesis of MFM-300(Al) using microwave heating

2019 ◽  
Vol 21 (18) ◽  
pp. 5039-5045 ◽  
Author(s):  
Ieuan Thomas-Hillman ◽  
Lee A. Stevens ◽  
Marcus Lange ◽  
Jens Möllmer ◽  
William Lewis ◽  
...  
Keyword(s):  
Microwave Heating ◽  
Metal Organic Frameworks ◽  
Rapid Synthesis ◽  
Solvothermal Route ◽  
Metal Organic ◽  
Aqueous Conditions

The synthesis of MFM-300(Al) in aqueous conditions and 10 minutes using microwave heating is reported. The material produced exhibits significantly enhanced uptake of CO2, SO2, and NO2 compared to the 3-day solvothermal route.

Green and rapid synthesis of zirconium metal–organic frameworks via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds

2017 ◽  
Vol 53 (43) ◽  
pp. 5818-5821 ◽  
Author(s):  
Yi-Hao Huang ◽  
Wei-Shang Lo ◽  
Yun-Wei Kuo ◽  
Wen-Jin Chen ◽  
Chia-Her Lin ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Rapid Synthesis ◽  
Metal Organic ◽  
Zirconium Metal

A UiO-66 analog was synthesized in 100 s via water-assisted grinding by the evaluation of linker solubility effects.

scholarly journals Overcoming Crystallinity Limitations of Aluminium Metal–Organic Frameworks by Oxalic Acid Modulated Synthesis

2019 ◽  
Author(s):  
Stefano Canossa ◽  
Adrian Gonzalez-Nelson ◽  
Leonid Shupletsov ◽  
María del Carmen Martín ◽  
Monique van der Veen
Keyword(s):  
Oxalic Acid ◽  
Hydrofluoric Acid ◽  
Metal Organic Frameworks ◽  
Structural Features ◽  
Test System ◽  
Superior Performance ◽  
Metal Organic ◽  
Potential Benefits ◽  
Synthesis Approach ◽  
Aluminium Metal

A modulated synthesis approach based on the chelating properties of oxalic acid (H<sub>2</sub>C<sub>2</sub>O<sub>4</sub>) is presented as a robust and versatile method to achieve highly crystalline Al-based metal–organic frameworks (MOFs). A comparative study on this method and the already established modulation by hydrofluoric acid was conducted using MIL-53 as test system. The superior performance of oxalic acid modulation in terms of crystallinity and absence of undesired impurities is explained by assessing the coordination modes of the two modulators and the structural features of the product. The validity of our approach was confirmed for a diverse set of Al-MOFs, namely X-MIL-53 (X = OH, CH<sub>3</sub>O, Br, NO<sub>2</sub>), CAU-10, MIL-69, and Al(OH)ndc (ndc = 1,4-naphtalenedicarboxylate), highlighting the potential benefits of extending the use of this modulator to other coordination materials.<br>

Mechanochemistry Enables Targeted Synthesis of Mixed-Metal Microporous Metal-Organic Frameworks Using Pre-Assembled Precursors

2019 ◽  
Author(s):  
Ghada Ayoub ◽  
Bahar Karadeniz ◽  
Ashlee J. Howarth ◽  
Omar Farha ◽  
Ivica Đilović ◽  
...  
Keyword(s):  
Ball Milling ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Stoichiometric Composition ◽  
Stoichiometric Ratio ◽  
Rapid Synthesis ◽  
Mixed Metal ◽  
Main Group Metals ◽  
Metal Metal ◽  
Metal Organic

Ball milling mechanochemistry enables enables targeted, rapid synthesis of mixed-metal metal-organic frameworks (MOFs) with controllable stoichiometric composition. Specifically, the use of ball milling enabled the use of pre-assembled coordination polymers of zinc, magnesium, nickel(II) and cobalt(II) as precursors in an innovative mechanochemical strategy for the deliberate assembly of mixed-metal MOF-74 materials comprised of pairs of transition of main group metals in a pre-determinmed 1:1 stoichiometric ratio, including ZnMg-, ZnCo, ZnCu, MgZn-, MgCo-, MgCa-, NiZn-,NiMg-, NiCo-, CoZn-, CoMg- and CoCu-MOF-74. While this is the first example of target-oriented MOF synthesis using mechanochemistry, it also provides an entry to controlling the stoichiometric composition of mixed-metal frameworks.<br>

scholarly journals Overcoming Crystallinity Limitations of Aluminium Metal–Organic Frameworks by Oxalic Acid Modulated Synthesis

2019 ◽  
Author(s):  
Stefano Canossa ◽  
Adrian Gonzalez-Nelson ◽  
Leonid Shupletsov ◽  
María del Carmen Martín ◽  
Monique van der Veen
Keyword(s):  
Oxalic Acid ◽  
Hydrofluoric Acid ◽  
Metal Organic Frameworks ◽  
Structural Features ◽  
Test System ◽  
Superior Performance ◽  
Metal Organic ◽  
Potential Benefits ◽  
Synthesis Approach ◽  
Aluminium Metal

A modulated synthesis approach based on the chelating properties of oxalic acid (H<sub>2</sub>C<sub>2</sub>O<sub>4</sub>) is presented as a robust and versatile method to achieve highly crystalline Al-based metal–organic frameworks (MOFs). A comparative study on this method and the already established modulation by hydrofluoric acid was conducted using MIL-53 as test system. The superior performance of oxalic acid modulation in terms of crystallinity and absence of undesired impurities is explained by assessing the coordination modes of the two modulators and the structural features of the product. The validity of our approach was confirmed for a diverse set of Al-MOFs, namely X-MIL-53 (X = OH, CH<sub>3</sub>O, Br, NO<sub>2</sub>), CAU-10, MIL-69, and Al(OH)ndc (ndc = 1,4-naphtalenedicarboxylate), highlighting the potential benefits of extending the use of this modulator to other coordination materials.<br>

Rapid synthesis of metal-organic frameworks MIL-53(Cr)

2019 ◽  
Vol 255 ◽  
pp. 126519 ◽  
Author(s):  
Xin Li ◽  
Jin Zhang ◽  
Wanling Shen ◽  
Shutao Xu
Keyword(s):  
Metal Organic Frameworks ◽  
Rapid Synthesis ◽  
Metal Organic
Sign in / Sign up

Export Citation Format

Share Document