scholarly journals Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers

2015 ◽  
Vol 15 (7) ◽  
pp. 3481-3492 ◽  
Author(s):  
Sonia G. Thangavelu ◽  
Ray J. Butcher ◽  
Christopher L. Cahill
Keyword(s):  
Coordination Polymers ◽  
Coordination Environment

scholarly journals Stimuli-Responsive Zinc (II) Coordination Polymers: A Novel Platform for Supramolecular Chromic Smart Tools

Polymers ◽  
2021 ◽  
Vol 13 (21) ◽  
pp. 3712
Author(s):  
Rosita Diana ◽  
Ugo Caruso ◽  
Barbara Panunzi
Keyword(s):  
Cross Section ◽  
Coordination Polymers ◽  
Imaging Technique ◽  
Stimuli Responsive ◽  
Advanced Imaging ◽  
Coordination Environment ◽  
Unique Role ◽  
Responsive Materials ◽  
The Past

The unique role of the zinc (II) cation prompted us to cut a cross-section of the large and complex topic of the stimuli-responsive coordination polymers (CPs). Due to its flexible coordination environment and geometries, easiness of coordination–decoordination equilibria, “optically innocent” ability to “clip” the ligands in emissive architectures, non-toxicity and sustainability, the zinc (II) cation is a good candidate for building supramolecular smart tools. The review summarizes the recent achievements of zinc-based CPs as stimuli-responsive materials able to provide a chromic response. An overview of the past five years has been organised, encompassing 1, 2 and 3D responsive zinc-based CPs; specifically zinc-based metallorganic frameworks and zinc-based nanosized polymeric probes. The most relevant examples were collected following a consequential and progressive approach, referring to the structure–responsiveness relationship, the sensing mechanisms, the analytes and/or parameters detected. Finally, applications of highly bioengineered Zn-CPs for advanced imaging technique have been discussed.

The influence of different coordination environments on one-dimensional Cu(ii) coordination polymers for the photo-degradation of organic dyes

2016 ◽  
Vol 45 (18) ◽  
pp. 7697-7707 ◽  
Author(s):  
Navid Hussain ◽  
Vimal K. Bhardwaj
Keyword(s):  
Coordination Polymers ◽  
Organic Dyes ◽  
Polymeric Complex ◽  
Photo Degradation ◽  
Coordination Environment ◽  
One Dimensional ◽  
Photo Catalytic Activity ◽  
Catalytic Rate Constant ◽  
Catalytic Rate

The role of coordination environment in 1D Cu(ii) coordination polymers for photo-catalytic activity has been investigated. Pyridine-2,6-dicarbohydrazide based polymeric complex 3 has the highest photo-catalytic rate constant (k = 0.72 h−1) for rhodamine B degradation.

Role of aromatic dicarboxylates in the structural diversity of cobalt(ii) and copper(ii) coordination polymers containing a flexible N,N′-di(3-pyridyl)octanediamide ligand

CrystEngComm ◽  
2013 ◽  
Vol 15 (36) ◽  
pp. 7274 ◽  
Author(s):  
Xiu-Li Wang ◽  
Fang-Fang Sui ◽  
Hong-Yan Lin ◽  
Chuang Xu ◽  
Guo-Cheng Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Diversity

Role of metal center and coordination environment in M-(Z)-N-((E)-pyridin-2-ylmethylene)isonicotinohydrazonate (M = LaIII, ZnII, CdII or HgII) catalyzed cyanosilylation of aldehydes

Polyhedron ◽  
2021 ◽  
Vol 209 ◽  
pp. 115453
Author(s):  
Fatali E. Huseynov ◽  
Ghodrat Mahmoudi ◽  
Sevinc R. Hajiyeva ◽  
Nazim T. Shamilov ◽  
Fedor I. Zubkov ◽  
...  
Keyword(s):  
Metal Center ◽  
Coordination Environment

scholarly journals Spectrally-resolved third-harmonic generation and the fundamental role of O–H⋯Cl hydrogen bonding in Oh, Td-cobalt(ii) tetraphenylmethane-based coordination polymers

2017 ◽  
Vol 46 (29) ◽  
pp. 9349-9357 ◽  
Author(s):  
J. K. Zaręba ◽  
J. Janczak ◽  
M. Samoć ◽  
M. Nyk
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymer ◽  
Harmonic Generation ◽  
Coordination Polymers ◽  
Third Harmonic Generation ◽  
Third Harmonic ◽  
Spectrally Resolved

The structural, topological and spectrally-resolved THG properties of the Oh, Td-cobalt(ii) tetraphenylmethane-based coordination polymer have been characterized.

The role of weak interactions in the crystal packing of two novel 1D Hg(II) coordination polymers and investigation for preparation of their rod and spherical structures

2020 ◽  
Vol 501 ◽  
pp. 119243 ◽  
Author(s):  
Ghodrat Mahmoudi ◽  
Payam Hayati ◽  
Khosro Mohammadi ◽  
Ardavan Masoudiasl ◽  
Joel T. Mague ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Crystal Packing ◽  
Weak Interactions ◽  
Spherical Structures

scholarly journals Boosting the Seebeck Coefficient for Organic Coordination Polymers: Role of Doping-Induced Polaron Band Formation

2019 ◽  
Vol 10 (10) ◽  
pp. 2493-2499 ◽  
Author(s):  
Yunpeng Liu ◽  
Wen Shi ◽  
Tianqi Zhao ◽  
Dong Wang ◽  
Zhigang Shuai
Keyword(s):  
Seebeck Coefficient ◽  
Coordination Polymers ◽  
Band Formation ◽  
Polaron Band
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