Dual-Channel Online Optical Detection Platform Integrated with a Visible Light Absorption Approach for Continuous and Simultaneous in Vivo Monitoring of Ascorbic Acid and Copper(II) Ions in a Living Rat Brain

2019 ◽  
Vol 91 (24) ◽  
pp. 16010-16016 ◽  
Author(s):  
Chao Wang ◽  
Xinyu Bi ◽  
Manchao Wang ◽  
Xu Zhao ◽  
Yuqing Lin
Keyword(s):  
Ascorbic Acid ◽  
Visible Light ◽  
Rat Brain ◽  
Light Absorption ◽  
Optical Detection ◽  
Visible Light Absorption ◽  
In Vivo Monitoring ◽  
Dual Channel

scholarly journals Tissue Transparency In Vivo

Molecules ◽  
2019 ◽  
Vol 24 (13) ◽  
pp. 2388 ◽  
Author(s):  
Mikhail Inyushin ◽  
Daria Meshalkina ◽  
Lidia Zueva ◽  
Astrid Zayas-Santiago
Keyword(s):  
Visible Light ◽  
Optical Imaging ◽  
Brain Tissue ◽  
Light Absorption ◽  
Optical Methods ◽  
Light Spectrum ◽  
Classical View ◽  
Visible Light Absorption ◽  
In Vivo Optical Imaging

In vivo tissue transparency in the visible light spectrum is beneficial for many research applications that use optical methods, whether it involves in vivo optical imaging of cells or their activity, or optical intervention to affect cells or their activity deep inside tissues, such as brain tissue. The classical view is that a tissue is transparent if it neither absorbs nor scatters light, and thus absorption and scattering are the key elements to be controlled to reach the necessary transparency. This review focuses on the latest genetic and chemical approaches for the decoloration of tissue pigments to reduce visible light absorption and the methods to reduce scattering in live tissues. We also discuss the possible molecules involved in transparency.

Impact of Rutile Fraction on TiO2 Visible-Light Absorption and Visible-Light-Induced Photocatalytic Activity

2018 ◽  
Author(s):  
David Maria Tobaldi ◽  
Luc Lajaunie ◽  
ana caetano ◽  
nejc rozman ◽  
Maria Paula Seabra ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Light Absorption ◽  
Solid Phase ◽  
Diffraction Method ◽  
Band Alignment ◽  
Quantitative Phase Analysis ◽  
Transmission Microscopy ◽  
Visible Light Absorption ◽  
X Ray

<div>Titanium dioxide is by far the most utilised semiconductor material for photocatalytic applications. Still, it is transparent to visible-light. Recently, it has been proved that a type-II band alignment for the rutile−anatase mixture would improve its visible-light absorption.</div><div>In this research paper we thoroughly characterised the real crystalline and amorphous phases of synthesised titanias – thermally treated at different temperatures to get distinct ratios of anatase-rutile-amorphous fraction – as well as that of three commercially available photocatalytic nano-TiO2. </div><div>The structural characterisation was done via advanced X-ray diffraction method, namely the Rietveld-RIR method, to attain a full quantitative phase analysis of the specimens. The microstructure was also investigated via an advanced X-ray method, the whole powder pattern modelling. These methods were validated combining advanced aberration-corrected scanning transmission microscopy and high-resolution electron energy-loss spectroscopy. The photocatalytic activity was assessed in the liquid- and gas-solid phase (employing rhodamine B and 4-chlorophenol, and isopropanol, respectively, as the organic substances to degrade) using a light source irradiating exclusively in the visible-range.</div><div>Optical spectroscopy showed that even a small fraction of rutile (2 wt%) is able to shift to lower energies the apparent optical band gap of an anatase-rutile mixed phase. But is this enough to attain a real photocatalytic activity promoted by merely visible-light?</div><div>We tried to give a reply to that question.</div><div>Photocatalytic activity results in the liquid-solid phase showed that a high surface hydroxylation led to specimen with superior visible light-induced catalytic activity (i.e. dye and ligand-to-metal charge transfer complexes sensitisation effects). That is: not photocatalysis <i>sensu-strictu</i>.</div><div>On the other hand, the gas-solid phase results showed that a higher amount of the rutile fraction (around 10 wt%), together with less recombination of the charge carriers, were more effective for an actual photocatalytic oxidation of isopropanol.</div>

Double Doping of NaTaO3 Photocatalysts with Lanthanum and Manganese for Strongly Enhanced Visible-Light Absorption

2019 ◽  
Vol 2 (10) ◽  
pp. 7518-7526 ◽  
Author(s):  
Hanggara Sudrajat ◽  
Mitsunori Kitta ◽  
Nobuyuki Ichikuni ◽  
Hiroshi Onishi
Keyword(s):  
Visible Light ◽  
Light Absorption ◽  
Visible Light Absorption ◽  
Double Doping

Carrier Engineering of Zr-mediated Ta3N5 Film as Efficient Photoanode for Solar Water Splitting

2021 ◽  
Author(s):  
Xin Zou ◽  
Xueyang Han ◽  
Chengxiong Wang ◽  
Yunkun Zhao ◽  
Chun Du ◽  
...  
Keyword(s):  
Band Structure ◽  
Visible Light ◽  
Water Splitting ◽  
Light Absorption ◽  
Photoelectrochemical Water Splitting ◽  
Promising Candidate ◽  
Visible Light Absorption ◽  
Solar Water ◽  
Solar Water Splitting

Ta3N5 is regarded as a promising candidate material with adequate visible light absorption and band structure for photoelectrochemical water splitting. However, the performance of Ta3N5 is severely limited by the...

scholarly journals Studies on the substrate-dependent photocatalytic properties of Cu2O heterojunctions

RSC Advances ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 4935-4941
Author(s):  
Riza Ariyani Nur Khasanah ◽  
Hui-Ching Lin ◽  
Hsiang-Yun Ho ◽  
Yen-Ping Peng ◽  
Tsong-Shin Lim ◽  
...  
Keyword(s):  
Visible Light ◽  
Light Absorption ◽  
Charge Separation ◽  
Spectral Response ◽  
Photocatalytic Properties ◽  
Visible Light Absorption ◽  
Uv Visible

Cu2O/TNA/Ti photoanode showed spectral response outperformed Cu2O/Ti and Cu2O/FTO photocathodes. Cu2O/TNA/Ti showed better spectral response than that of TNA/Ti, ascribed to UV-visible light absorption of Cu2O, not to charge separation enhancement.

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