Effect of Diffusion Coefficient Diversity on Steady-State Voltammetry When Homogeneous Equilibria and Migration Are Encountered

1996 ◽  
Vol 68 (23) ◽  
pp. 4173-4179 ◽  
Author(s):  
Keith B. Oldham
Keyword(s):  
Diffusion Coefficient ◽  
Steady State ◽  
And Migration

Temperature effects on ageing properties and diffusivity of a HDPE GM in landfill

2021 ◽  
pp. 0734242X2110570
Author(s):  
Shengwei Wang ◽  
Tao Guo ◽  
Huan Tian ◽  
Zhigang Li ◽  
Kang Fei
Keyword(s):  
Diffusion Coefficient ◽  
Tensile Properties ◽  
Ageing Time ◽  
Melt Flow Index ◽  
Engineering Properties ◽  
Flow Index ◽  
Test Results ◽  
Oxidation Induction Time ◽  
Degradation Rates ◽  
And Migration

High-density polyethylene (HDPE) geomembranes (GMs) play a crucial role in preventing the leakage and migration of pollutants. GM service life and ageing properties are the main concerns for the choice of materials. However, it is not clear how the mechanical properties and anti-fouling performance of geomembranes change with ageing time. To solve this problem, a HDPE GM was selected for testing under exposed air condition. The tests included oxidation induction time (OIT), melt flow index (MFI), tensile properties and diffusivity under four temperature conditions for 1½ years. The test results showed that the GM has higher OIT degradation rates. Stage I – depletion of antioxidants occurred at only 10 years for the GM, which was approximately 1/4 that of the GM-GSE. The GM engineering properties index showed the same changes as those of the GM-GSE. However, MI rapidly decreased with the incubation time. The molecular weight degradation of the GM was approximately 57% and far greater than that of GM-GSE after 15 months, but the tensile properties of the two GMs showed little change. The diffusion coefficient Di of GM increases gradually with the increase of temperature in methane and trichloromethane. Under the same conditions, the diffusion coefficient Di of the GM in methane is significantly higher than that in trichloromethane, indicating that the GM has better barrier to trichloromethane.

scholarly journals Potential Anticancer Activity of Crude Ethanol, Ethyl Acetate, and Water Extracts of Ephedra foeminea on Human Osteosarcoma U2OS Cell Viability and Migration

2020 ◽  
Vol 2020 ◽  
pp. 1-16
Author(s):  
Eric Zadok Mpingirika ◽  
Ahmed El Hosseiny ◽  
Sheri Magdy Saleeb Bakheit ◽  
Rami Arafeh ◽  
Asma Amleh
Keyword(s):  
Steady State ◽  
Cell Viability ◽  
Ethyl Acetate ◽  
Anticancer Activity ◽  
Ethanol Extract ◽  
U2os Cell ◽  
Mrna Levels ◽  
Water Extracts ◽  
Human Osteosarcoma ◽  
And Migration

Medicinal plants are potential sources for a wide range of complex compounds with probable anticancer activity. Ephedra foeminea Forssk. (E. foeminea), a medicinal plant found in the Eastern Mediterranean, has recently been gaining popularity as a cancer remedy; there is, however, a paucity of empirical evidence supporting this claim. In this study, the effect of E. foeminea ethyl acetate, ethanol, and water crude extracts on viability, migratory ability, and the steady-state mRNA levels of genes involved in these processes was, respectively, examined using MTT assay, wound healing assay, and reverse transcriptase PCR (RT-PCR). The study concludes that all extracts significantly reduce human osteosarcoma U2OS percentage viability in a dose- and time-dependent manner, with varying potencies. The least half-maximal inhibitory concentration (IC50) was observed in the water extract after 48 h incubation (30.761±1.4 μg/mL) followed by the ethyl acetate extract after 72 h incubation (80.35±1.233 μg/mL) and finally the ethanol extract after 48 h incubation (97.499±1.188 μg/mL). Ethanol extract significantly reduced U2OS percentage wound closure. On the other hand, both ethanol and water extracts considerably reduced the steady-state mRNA expression of beta-catenin, promoting both cell proliferation and migration in osteosarcoma by regulating target genes. Additionally, E. foeminea showed no hemolytic activity. These effects suggest that E. foeminea decreases U2OS cell viability and migratory ability by modulating the expression of critical genes involved in regulating these processes and is likely cytocompatible with human erythrocytes.

Temperature dependence of oxygen diffusion and consumption in mammalian striated muscle

1993 ◽  
Vol 264 (6) ◽  
pp. H1825-H1830 ◽  
Author(s):  
T. B. Bentley ◽  
H. Meng ◽  
R. N. Pittman
Keyword(s):  
Diffusion Coefficient ◽  
Steady State ◽  
Oxygen Diffusion ◽  
Striated Muscle ◽  
Effect Of Temperature ◽  
Retractor Muscle ◽  
Oxygen Solubility ◽  
Order Of Magnitude

This study investigated the effect of temperature on the oxygen diffusion coefficient (DO2) of hamster retractor muscle from 11 to 37 degrees C. DO2 was measured using a non-steady-state technique, whereas muscle O2 consumption (VO2) was estimated after steady state was reached. DO2 was 0.84 +/- 0.04 x 10(-5) cm2/s at 11 degrees C and rose exponentially to 2.41 +/- 0.19 x 10(-5) cm2/s at 37 degrees C, producing a temperature coefficient for DO2 of 4.60%/degrees C for this temperature range. To measure DO2 directly at 37 degrees C, it was necessary to inhibit tissue VO2 with Amytal. The DO2 measurements made at 37 degrees C were significantly higher than previously reported values, which had been based on extrapolations from lower temperatures (6). Further analysis suggests a possible transition in the diffusion pathway between 23 and 30 degrees C, resulting in a DO2 higher than that previously expected. This larger DO2, together with a recently published value of oxygen solubility (alpha) (21), results in an in vitro Krogh's diffusion coefficient (KO2) that is 2.4 times larger than that previously reported (24) and therefore significantly reduces an order of magnitude discrepancy between in vitro and estimated in vivo KO2 values (24). Muscle VO2 was 0.35 ml O2.min-1.100 g-1 at 11 degrees C and increased with temperature, resulting in an activation energy of the rate-limiting reaction from the Arrhenius equation of -10.5 kcal/mol between 11 and 30 degrees C.

Steady state solutions of a bi-stable quasi-linear equation with saturating flux

2011 ◽  
Vol 22 (4) ◽  
pp. 317-331 ◽  
Author(s):  
M. BURNS ◽  
M. GRINFELD
Keyword(s):  
Diffusion Coefficient ◽  
Steady State ◽  
Linear Equation ◽  
Stationary Solutions ◽  
Classical Solutions ◽  
Bifurcation Problem ◽  
Cahn Equation ◽  
Steady State Solutions

In this paper, we consider the bi-stable equation proposed by Rosenau to replace the Allen–Cahn equation in the case of large gradients. We discuss the bifurcation problem for stationary solutions of this equation on an interval as the diffusion coefficient and the length of the interval are varied, concentrating on classical solutions.

scholarly journals The Steady-State Transport of Oxygen through Hemoglobin Solutions

1966 ◽  
Vol 49 (4) ◽  
pp. 663-679 ◽  
Author(s):  
K. H. Keller ◽  
S. K. Friedlander
Keyword(s):  
Diffusion Coefficient ◽  
Brownian Motion ◽  
Steady State ◽  
Effective Diffusion ◽  
Close Correlation ◽  
Oxygen Electrode ◽  
Low Oxygen ◽  
Diffusion Rates ◽  
Oxygen Tensions ◽  
Diffusion Coefficient Of Oxygen

The steady-state transport of oxygen through hemoglobin solutions was studied to identify the mechanism of the diffusion augmentation observed at low oxygen tensions. A novel technique employing a platinum-silver oxygen electrode was developed to measure the effective diffusion coefficient of oxygen in steady-state transport. The measurements were made over a wider range of hemoglobin and oxygen concentrations than previously reported. Values of the Brownian motion diffusion coefficient of oxygen in hemoglobin solution were obtained as well as measurements of facilitated transport at low oxygen tensions. Transport rates up to ten times greater than ordinary diffusion rates were found. Predictions of oxygen flux were made assuming that the oxyhemoglobin transport coefficient was equal to the Brownian motion diffusivity which was measured in a separate set of experiments. The close correlation between prediction and experiment indicates that the diffusion of oxyhemoglobin is the mechanism by which steady-state oxygen transport is facilitated.

scholarly journals Combined bound water and water vapour diffusion of Norway spruce and European beech in and between the principal anatomical directions

Holzforschung ◽  
2011 ◽  
Vol 65 (6) ◽  
pp. 819-828 ◽  
Author(s):  
Walter Sonderegger ◽  
Manuele Vecellio ◽  
Pascal Zwicker ◽  
Peter Niemz
Keyword(s):  
Diffusion Coefficient ◽  
Steady State ◽  
Water Vapour ◽  
Diffusion Coefficients ◽  
Bound Water ◽  
European Beech ◽  
Unsteady State ◽  
Water Vapour Diffusion ◽  
Vapour Diffusion ◽  
Water Vapour Resistance

Abstract The combined bound water and water vapour diffusion of wood is of great interest in the field of building physics. Due to swelling stresses, the steady-state-determined diffusion coefficient clearly differs from the unsteady-state-determined diffusion coefficient. In this study, both diffusion coefficients and the water vapour resistance factor of Norway spruce (Picea abies [L.] Karst.) and European beech (Fagus sylvatica L.) were investigated for the principal anatomical directions (radial, tangential and longitudinal) and in 15° steps between these directions. The values were determined with the cup method as the basic principle. The unsteady-state-determined diffusion coefficient is, independent of the direction, about half that of the steady-state-determined diffusion coefficient. Both diffusion coefficients are about two to three times higher for spruce than for beech. They are up to 12 times higher in the longitudinal direction than perpendicular to the grain for spruce, and up to 15 times higher for beech. With increasing moisture content, the diffusion coefficients exponentially increase. The water vapour resistance factor shows converse values to the diffusion coefficients.

scholarly journals Diffusivity Measurements of Human Methemoglobin

1966 ◽  
Vol 49 (4) ◽  
pp. 681-687 ◽  
Author(s):  
K. H. Keller ◽  
S. K. Friedlander
Keyword(s):  
Diffusion Coefficient ◽  
Steady State ◽  
Experimental Measurements ◽  
Diffusion Cell ◽  
Millipore Filter ◽  
Diffusivity Measurements

Experimental measurements of the diffusion coefficient of human methemoglobin were made at 25°C with a modified Stokes diaphragm diffusion cell. A Millipore filter was used in place of the ordinary fritted disc to facilitate rapid achievement of steady state in the diaphragm. Methemoglobin concentrations varied from approximately 5 g/100 ml to 30 g/100 ml. The diffusion coefficient in this range decreased from 7.5 x 10-7 cm2/sec to 1.6 x 10-7 cm2/sec.

FORCE ON A DROPLET IN ANOTHER LIQUID WITH ARBITRARY ARRANGEMENT OF THE GRAVITY AND THERMAL GRADIENT

2005 ◽  
Vol 19 (28n29) ◽  
pp. 1671-1674
Author(s):  
REN SUN
Keyword(s):  
Gravitational Field ◽  
Steady State ◽  
General Solution ◽  
Physical Properties ◽  
Thermal Gradient ◽  
Droplet Cluster ◽  
And Migration ◽  
State Force

The steady-state force on the droplet released in another liquid subjected to the gravitational field and imposed thermal gradient in the case of vanishingly small Re and Ma is derived using the general solution given by Lamb. A solution to a transitional thermocapillary-type droplet migration is thereby obtained for the case of constant physical properties, which corresponds to the well known YGB result as t → ∞. These can be employed to investigate the interactions between droplets in a host solution under the gravitational and thermal influences, and further to explore deposition and migration of a droplet cluster in the corresponding fields.

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